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1,4,4a,5a,6,9,9a,9b-Octahydrodibenzofuran-4a-carbaldehyd

2,3:4,5-Di(2-butenyl)tetrahydrofurfural

HCID 31341
NotizenReaktionen
GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
TeilstruktursucheÄhnliche Strukturen suchen

Grundinformationen

CAS
126-15-8
Standard-SMILES
O=CC12CC=CCC1C1CC=CCC1O2
InChIKey
XNYGOEGATLFFOX-UHFFFAOYSA-N
Summenformel
C13H16O2
Durchschnittliche Molmasse
204,26 g/mol
Monoisotopische Masse
204,11502975

Überblick

topical repellent against Phlebotomus perniciosus

Namen und Bezeichner

Bevorzugter Name
2,3:4,5-Di(2-butenyl)tetrahydrofurfural
IUPAC
4,5a,6,9,9a,9b-hexahydro-1H-dibenzofuran-4a-carbaldehyde
Lokaler Name
1,4,4a,5a,6,9,9a,9b-Octahydrodibenzofuran-4a-carbaldehyd
Englischer Name
MGK 11
Summenformel
C13H16O2
Molmasse
204.26

Namen und Synonyme

126-15-8Mgk repellent 11Dibutylene tetrafurfural1,5a,6,9,9a,9b-Hexahydro-4a(4H)-dibenzofurancarboxaldehydeCaswell No. 0894a(4H)-Dibenzofurancarboxaldehyde, 1,5a,6,9,9a,9b-hexahydro-2,3,4,5-Bis(2-butylene)tetrahydro-2-furaldehydeMGK R-11HSDB 5609UNII-C62PHK07EV2,3,4,5-Bisbutylene tetrafurfuralEINECS 204-773-7
Weitere Namen anzeigen
r-11MGK 11MGK IIMKG 11ac-r-11MGK-R 11ent17,596NSC 52965Repel 111MGK 11 0.1g
BRN 00116852,3:4,5-DI(2-BUTENYL)TETRAHYDROFURFURALAI3-17596Bis-delta(sup 2)-butylenetetrahydrofurfuralNSC-529652,3,4,5-Bis(delta-2-butylene)tetrahydrofurfural2,3,4,5-Bis(delta(sup 2)-butylene)tetrahydrofurfural2,3,4,5-Bis(delta(sup 2)-butenylene)tetrahydrofurfural

Datenbank-Bezeichner

CAS

Eigenschaften

Berechnete Struktureigenschaften

XLogP
2,1
Polarare Oberfläche (TPSA)
26,3 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
1
Schwere Atome
15
Formalladung
0
Komplexität
331

Experimentelle und physikochemische Eigenschaften

CosmeticsViscosity controlling; Antioxidant
PesticidesPesticides -> Insect Repellents
OdorFRUITY ODOR
Density · 3 Einträge

1.10 @ 20 °C/4 °C

DENSITY: 1.120 @ 20 °C/20 °C /TECHNICAL GRADE/

1.10 @ 20°C

Color/FormPALE YELLOW LIQUID
SolubilityPRACTICALLY INSOL IN WATER & IN DILUTE ALKALI; MISCIBLE WITH PETROLEUM OILS, TOLUENE, XYLENE, ETHANOL
Boiling Point · 2 Einträge

307 °C

307 °C @760 [mm Hg]

Melting Point · 2 Einträge

-80 °C

-80 °C

Physical DescriptionPale yellow liquid with a fruity odor; [HSDB]
Stability/Shelf LifeSTABLE FOR LONG PERIODS IN DRUMS

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 3 Einträge

H411 (100%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]

P273, P391, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

Gefahrenhinweise

Regulatory InformationChemical: 4a(4H)-Dibenzofurancarboxaldehyde, 1,5a,6,9,9a,9b-hexahydro-
Hazards SummaryMay cause irritation; [MSDSonline]
TSCA Requirements · 2 Einträge

Section 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble in 51 FR 41329.

Pursuant to section 8(d) of TSCA, EPA promulgated a model Health and Safety Data Reporting Rule. The section 8(d) model rule requires manufacturers, importers, and processors of listed chemical substances and mixtures to submit to EPA copies and lists of unpublished health and safety studies. /4a(4H)-Dibenzofurancarboxaldehyde,1,5a,6,9,9a,9b-hexahydro/ is included on this list.

FIFRA Requirements · 1 Eintrag

As the federal pesticide law FIFRA directs, EPA is conducting a comprehensive review of older pesticides to consider their health and environmental effects and make decisions about their future use. Under this pesticide reregistration program, EPA examines health and safety data for pesticide active ingredients initially registered before November 1, 1984, and determines whether they are eligible for reregistration. In addition, all pesticides must meet the new safety standard of the Food Quality Protection Act of 1996. Pesticides for which EPA had not issued Registration Standards prior to the effective date of FIFRA, as amended in 1988, were divided into three lists based upon their potential for human exposure and other factors, with List B containing pesticides of greater concern and List D pesticides of less concern. Bis(2-butylene)tetrahydro-2-furaldehyde is found on List C. Case No: 3127; Pesticide type: insecticide; Case Status: No products containing the pesticide are actively registered ... The case /is characterized/ as "cancelled." Under FIFRA, pesticide producers may voluntarily cancel their registered products. EPA also may cancel pesticide registrations if registrants fail to pay required fees or make/meet certain reregistration commitments, or if EPA reaches findings of unreasonable adverse effects.; Active ingredient (AI): Bis(2-butylene)tetrahydro-2-furaldehyde; AI Status: The active ingredient is no longer contained in any registered pesticide products ... "cancelled."

Chemie und Industrie

Verwendung und Herstellung

Uses · 3 Einträge

Used as insect repellent; No longer registered with the EPA for use in the US, cancelled; [HSDB]

The active ingredient is no longer contained in any registered pesticide products ... "cancelled."

INSECT REPELLENT

Methods of ManufacturingPRODUCED BY THE CONDENSATION OF BUTA-1,3-DIENE WITH 2-FURALDEHYDE (US PATENTS 2683511; 2934471)...
Formulations/Preparations · 4 Einträge

USED IN COMBINATION WITH OTHER REPELLENTS SUCH AS DEET & MGK REPELLENT 326 OR TOXICANTS IN LIQUID & PRESSURIZED SPRAYS.

USED AT 0.5% TO 1.25% BY WT WITH DIETHYLTOLUAMIDE & OTHER COMPOUNDS IN REPELLENTS FOR PERSONAL USE. USED AT 0.2% TO 0.25% WITH PYRETHRINS IN SPRAYS FOR PETS & SHOW ANIMALS & HORSES.

ACTIVE INGREDIENT IN WATER EMULSION OR OIL SPRAYS USED IN INSECT REPELLENTS (FINAL RECOMMENDED CONCN 0.2-0.4%).

A typical formulation contains 0.075% pyrethins, 0.15% piperonyl butoxide, and 1% 2,3:4,5-di(2-butenyl)tetrahydrofurfural.

Household ProductsInformation on 2 consumer products that contain 2,3,4,5 Bis(2-butylene) tetrahydro 2-furaldehyde in the following categories is provided:
Use ClassificationCosmetics -> Viscosity controlling; Antioxidant
General Manufacturing Information · 3 Einträge

4a(4H)-Dibenzofurancarboxaldehyde, 1,5a,6,9,9a,9b-hexahydro-: ACTIVE

IT IS AN INSECT REPELLENT EFFECTIVE AGAINST COCKROACHES, STABLE & HORN FLIES, MOSQUITOES & GNATS. ITS MAIN USES NOW ARE IN PET SPRAYS & IN REPELLENTS FOR PERSONAL USE IN COMBINATION WITH OTHER MATERIALS. IT IS NO LONGER RECOMMENDED FOR USE ON MILK- OR MEAT-PRODUCING ANIMALS.

The pesticide is no longer an active ingredient in any registered pesticide products. Therefore, EPA is characterizing it as cancelled.

Anwendungen

MGK 11 is an insect repellent most commonly used commercially as a mosquito repellent.

Zugehörige Reaktionen

2
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 73724
HRID 73724als Produktuspto-grants-2014_09
Reaktionsgleichung von HRID 1399474
HRID 1399474als Produktuspto-grants-2014_12

Notizen zur Verbindung

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
126-15-8
PubChem CID
31341
DTXSID
DTXSID3041320
UNII
C62PHK07EV
EC Number
204-773-7
Nikkaji
J5.380E

Physikochemische Eigenschaften

Schmelzpunkt
-80 ℃ · -80℃
Siedepunkt
307 ° · bp 307°
Dichte
420 · d420 1.10
Brechungsindex
20 · n20/D 1.520-1.530
Flammpunkt
154 °C · 154 °C
storage temp.
-20 °C · Amber Vial, -20°C Freezer, Under inert atmosphere
Löslichkeit
Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand
Oil
Farbe
Pale-yellow liquid
Stabilität
Air Sensitive
Kosmetik-Inhaltsstoffe Funktionen
ANTIOXIDANTVISCOSITY CONTROLLING
LogP
2.29 · 2.290 (est)
EPA chemische Informationen
2 · 2,3:4,5-Bis(2-butylene)tetrahydro-2-furaldehyde (126-15-8)
Hazard Classes and CategoriesAquatic Chronic 2 (100%)

Sicherheit und Schutzausrüstung

Disposal Methods · 1 Eintrag

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

Protective Action Criteria (PAC) · 3 Einträge

7.5 [mg/m3]

83 [mg/m3]

500 [mg/m3]

Toxikologische Informationen

Non-Human Toxicity ExcerptsIN 90-DAY FEEDING TRIALS RATS RECEIVING 20000 MG/KG DIET SUFFERED NO GROSS ILL-EFFECT.
Non-Human Toxicity ValuesLD50 Rat oral 2 g/kg

Regulatorische Informationen

TSCA Requirements · 2 Einträge

Section 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble in 51 FR 41329.

Pursuant to section 8(d) of TSCA, EPA promulgated a model Health and Safety Data Reporting Rule. The section 8(d) model rule requires manufacturers, importers, and processors of listed chemical substances and mixtures to submit to EPA copies and lists of unpublished health and safety studies. /4a(4H)-Dibenzofurancarboxaldehyde,1,5a,6,9,9a,9b-hexahydro/ is included on this list.

FIFRA Requirements · 1 Eintrag

As the federal pesticide law FIFRA directs, EPA is conducting a comprehensive review of older pesticides to consider their health and environmental effects and make decisions about their future use. Under this pesticide reregistration program, EPA examines health and safety data for pesticide active ingredients initially registered before November 1, 1984, and determines whether they are eligible for reregistration. In addition, all pesticides must meet the new safety standard of the Food Quality Protection Act of 1996. Pesticides for which EPA had not issued Registration Standards prior to the effective date of FIFRA, as amended in 1988, were divided into three lists based upon their potential for human exposure and other factors, with List B containing pesticides of greater concern and List D pesticides of less concern. Bis(2-butylene)tetrahydro-2-furaldehyde is found on List C. Case No: 3127; Pesticide type: insecticide; Case Status: No products containing the pesticide are actively registered ... The case /is characterized/ as "cancelled." Under FIFRA, pesticide producers may voluntarily cancel their registered products. EPA also may cancel pesticide registrations if registrants fail to pay required fees or make/meet certain reregistration commitments, or if EPA reaches findings of unreasonable adverse effects.; Active ingredient (AI): Bis(2-butylene)tetrahydro-2-furaldehyde; AI Status: The active ingredient is no longer contained in any registered pesticide products ... "cancelled."

Sicherheitsdaten

tsca
TSCA listed
RTECS-Nr.
HP5075000
Toxizität
LD50 orl-rat: 2500 mg/kg MEIEDD 10,1170,83
Giftige Stoffe Daten
126-15-8(Hazardous Substances Data)
Verwenden

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

2-Furyl-methanalButa-1,3-dien

Anbieter21 Anbieter

Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
梯希爱(上海)化工贸易有限公司021-61109150 · [email protected]
四川库利南科技有限公司400-1166-196 18981987031 · [email protected]
艾科试剂4008-755-333 18080918076 · [email protected]
上海贺康生物技术有限公司17721021104 18939837085 · [email protected]
上海将来实业股份有限公司400-0066400 13621662912 · [email protected]
天津阿尔塔科技有限公司022-65378550-8551 · [email protected]
陕西缔都医药化工有限公司029-81024372 17792795018 · [email protected]
深圳振强药物研发有限公司+86-0755-66853366 +86-13670046396 · [email protected]
天津阿尔塔科技有限公司022-6537-8550 15522853686 · [email protected]
上海博尔森生物科技有限公司021-67681877 13166061152 · [email protected]
安耐吉化学&3A(安徽泽升科技股份有限公司)400-0056266 · [email protected]
湖北万业众诚化学试剂有限责任公司18671296875 · [email protected]
河北贞佳新材料有限公司0319-5925599 13315915972
Shaanxi Dideu New Materials Co. Ltd18192503167 · [email protected]
杭州洁汉化工有限公司+86-571-86217390; +8618058761490 · [email protected]
career henan chemical co+86-0371-86658258 · [email protected]
深圳聚合生化科技有限公司+86-400-002-6226 13028896684 · [email protected]
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