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1-Iodpropan
PROPYL IODIDE · N-PROPYL IODIDE · n-C3H7I · 1-Jodpropan · Propyljodid · 1-Iodpropane · 1-IODOPROPANE · n-Propyliodid
Identifikatoren & physikalische Daten
| CAS No. | 107-08-4 |
|---|---|
| Summenformel | C3H7I |
| Durchschnittliche Molmasse | 169,99 g/mol |
| Monoisotopische Masse | 169,95924822 g/mol |
| SMILES | CCCI |
| InChIKey | PVWOIHVRPOBWPI-UHFFFAOYSA-N |
| PubChem CID | 33643 |
| EC No. | 203-460-2 |
| DTXSID | DTXSID501015653 |
| Lokaler Name | 1-Iodpropan |
Chemische & physikalische Eigenschaften
| XLogP | 2,6 |
|---|---|
| Polarare Oberfläche (TPSA) | 0 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 1 |
| Schwere Atome | 4 |
| Formalladung | 0 |
| Komplexität | 7,2 |
| Stoffklassen | Other Classes -> Halogenated Aliphatics, SaturatedFlammable agents - 2nd degree |
| SpringerMaterials Properties | Coriolis coupling |
| LogP (Verteilungskoeffizient) | 2.54 |
| Dampfdruck | 43.1 [mmHg]43 mm Hg ( 25 °C) |
| Physical Description | Iodopropanes appears as a colorless liquid that discolors in air. Denser than water. The vapors are heavier than air. May be mildly toxic by inhalation. Used as a solvent and to make pharmaceuticals.Colorless or yellowish liquid[Merck Index] |
| Schmelzpunkt | -101 °C |
| Siedepunkt | 101-102 °C(lit.) |
| Dichte | 1.743 g/mL at 25 °C(lit.) |
| Brechungsindex | n20/D 1.504(lit.) |
| Flammpunkt | 112 °F |
| Lagerbedingungen | Store below +30°C. |
| Löslichkeit | 1.1g/lFully miscible in water. |
| Aggregatzustand | Liquid |
| Farbe | Clear colorless to yellow |
| Merck | 14,7862 |
| BRN | 505937 |
| Henry-Konstante | (x 10-3 atmm3/mol): 9.09 at 25 °C (Hine and Mookerjee, 1975) |
| Dielektrizitätskonstante | 7.0899999999999999 |
| Stabilität | Stable, but may discolour on exposure to light. Incompatible with strong oxidizing agents, strong bases. Flammable. |
| InChI | 1S/C3H7I/c1-2-3-4/h2-3H2,1H3 |
| InChIKey | PVWOIHVRPOBWPI-UHFFFAOYSA-N |
| SMILES | CCCI |
| CAS Datenbank | 107-08-4(CAS DataBase Reference) |
| NIST chemische Informationen | Propane, 1-iodo-(107-08-4) |
| EPA chemische Informationen | Propane, 1-iodo- (107-08-4) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH226 (100%): Flammable liquid and vapor [Warning Flammable liquids]P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 50 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Propane, 1-iodo-Status: Active Update: 01-02-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/220931-Iodopropane: Does not have an individual approval but may be used under an appropriate group standardThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| DOT-Kennzeichnung | Flammable Liquid |
| Brandgefahren | Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: |
| Gesundheitsgefahren | Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: |
| Gefahrenübersicht | An irritantHarmful by inhalation[Alfa Aesar MSDS] |
| Reaktive Gruppe | Halogenated Organic Compounds |
| Reactivity Alerts | Highly Flammable |
| Reactivity Profile | Halogenated aliphatic compounds, such as IODOPROPANE, are moderately or very reactive. Halogenated organics generally become less reactive as more of their hydrogen atoms are replaced with halogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. |
| Air and Water Reactions | Highly flammable. Slightly soluble in water. |
| Hazard Classes and Categories | Flam. Liq. 3 (100%)Flammable agents - 2nd degree |
| Brandbekämpfung | Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: |
| Erste Hilfe | Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: |
| Freisetung ohne Brand | Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: |
| Isolation and Evacuation | Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: |
| Personal Protective Equipment (PPE) | Excerpt from ERG Guide 129 [Flammable Liquids (Water-Miscible / Noxious)]: |
| Toxicity Data | LC50 (rat) = 73,000 mg/m3/30min |
| F | 8 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 2392 (IODOPROPANES) |
| Zollcode | 29033080 |
| RTECS-Nr. | TZ4100000 |
| R-Sätze (R) | 10-20-36/37/38-52/53-2017/10/20 |
| Toxizität | LD50 (inhalation) for rats 73,000 mg/m3/30-min (quoted, RTECS, 1985). |
| Gefahrensymbole | Xn,Xi,N |
| hazard_note | Irritant |
| Sicherheitshinweise (S) | 16-26-36/37-61 |
| Gefahrenklasse | 3Acute Tox. 4 InhalationAquatic Chronic 1Carc. 2Eye Irrit. 2Flam. Liq. 3Muta. 2Skin Irrit. 2STOT SE 3 |
| Verpackungsgruppe | III |
| Lagerklasse | 3 - Flammable liquids |
Anwendungen & Verwendung
Verwenden
1-Iodopropane is used in wide range of medicals industrial applications as well as in human and animal nutrition products, pharmaceutical intermediates, polarizing films for Liquid Crystal Display (LCD) chemicals. Iodine derivatives are also used as organic building blocks, analytical reagents etc. It is also used as a solvent and intermediate of organic synthesis.