Platindioxid

Adams' catalyst

HCID 345198CAS 1314-15-4
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Grundinformationen

Standard-SMILES
[O]=[Pt]=[O]
InChIKey
YKIOKAURTKXMSB-UHFFFAOYSA-N
Summenformel
O2Pt
Durchschnittliche Molmasse
227,08 g/mol
Monoisotopische Masse
226,95462034

Namen und Bezeichner

Bevorzugter Name
Adams' catalyst
IUPAC
dioxoplatinum
Lokaler Name
Platindioxid
Englischer Name
Platinum dioxide
Summenformel
O2Pt
Molmasse
227.08

Namen und Synonyme

Platinum(IV) oxide1314-15-4dioxoplatinumAdams' catalystAdams CatalystPlatinic oxideplatinum (iv) oxidePlatinium oxideMFCD00011184platinum(iv) dioxidePlatinium oxide, PtO2Platinum(iv)oxide
Weitere Namen anzeigen
PtO2PLATINUM OXIDE1341-15-4ADAM'S CATALYSTplatinum(iv) oxide monohydrate, adams catalyst
Bis(oxido)platinumplatinum (IV)oxideplatinum(IV)-oxidePlatinum-(IV)-oxidePlatinum (1V) oxideplatinum (IV) dioxidePlatinum( cento) oxideSCHEMBL72223

Datenbank-Bezeichner

CAS
1314-15-4
PubChem CID
345198
DTXSID
DTXSID40904275
EC Number
215-223-0
Nikkaji
J96.441G

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
34,1 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
0
Schwere Atome
3

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Inorganic Compounds
Food Contact SubstancesFCS -> FDA Inventory of Effective Food Contact Substance (FCS) Notifications
Physical DescriptionMonohydrate: Black solid; [Merck Index] Black odorless powder; Insoluble in water; [MSDSonline]

Physikochemische Eigenschaften

Schmelzpunkt
450 °C · 450 °C (lit.)
Dichte
10.2 · 10.2
storage temp.
2 · under inert gas (nitrogen or Argon) at 2-8°C
Aggregatzustand
crystalline
Farbe
Dark brown
Wasserlöslichkeit
Soluble in caustic potash solution. Insoluble in water, acid, aquaregia.

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 3% (8 of 269) of reports.

Danger

H271 (75.5%): May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P264+P265, P280, P283, P305+P351+P338, P306+P360, P337+P317, P370+P378, P371+P380+P375, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 269 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Platinum oxide (PtO2)

Status: Active Update: 27-01-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/18998

Platinum (IV) oxide: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Platinum oxide (PtO2): Environment tier I assessment
Hazards SummaryA skin irritant; Corrosive to eyes; [eChemPortal: ERMA] An oxidizing agent; May cause fire on contact with combustible material; An irritant; May cause skin sensitization; [MSDSonline]
Hazard Classes and CategoriesOx. Sol. 1 (75.5%)

Toxikologische Informationen

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.

Sicherheitsdaten

wgk
2
tsca
TSCA listed
ridadr
UN 1479 5.1/PG 2
hs_code
28439000
risk_code
8-36-41-38-36/37/38
hazard_code
O,Xi

Chemie und Industrie

Verwendung und Herstellung

Uses · 1 Eintrag

Used as a hydrogenation catalyst; [Merck Index] Platinum(IV) oxide hydrate (PtO2.H2O) is a hydrogenation catalyst. Other platinum oxides have little commercial use: Platinum(II) oxide (PtO) and platinum(II) oxide hydrate (PtO.H2O). [Ullmann]

General Manufacturing InformationPlatinum oxide (PtO2): ACTIVE
Anwendungen · 1 Eintrag

VerwendenAs catalyst in hydrogenations. The actual catalyst is platinum black which is formed in situ by reduction of the PtO2 by the hydrogen used for the hydrogenation. Especially useful for reduction at room tempereture and hydrogen pressures up to 4 atmospheres. Suitable for the reduction of double and triple bonds, aromatic nuclei, carbonyl groups, nitro groups, and nitriles.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Anbieter50 Anbieter

国药集团化学试剂有限公司86-21-63210123 · [email protected]
北京华美互利生物化工010-56205725 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]

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