Grundinformationen
- CAS
119-26-6- Standard-SMILES
NNc1ccc([N+](=O)[O-])cc1[N+](=O)[O-]- InChIKey
HORQAOAYAYGIBM-UHFFFAOYSA-N- Summenformel
- C6H6N4O4
- Durchschnittliche Molmasse
- 198,14 g/mol
- Monoisotopische Masse
- 198,03890467
Überblick
2,4-dinitrophenylhydrazine is a C-nitro compound that is phenylhydrazine substituted at the 2- and 4-positions by nitro groups. It has a role as a reagent. It is a member of phenylhydrazines and a C-nitro compound.
Namen und Bezeichner
- Bevorzugter Name
- (2,4-Dinitrophenyl)hydrazine
- IUPAC
- (2,4-dinitrophenyl)hydrazine
- Lokaler Name
- 2,4-Dinitrophenylhydrazin
- Englischer Name
- 2,4-Dinitrophenylhydrazine
- Summenformel
- C6H6N4O4
- Molmasse
- 198.14
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
119-26-6- PubChem CID
- 3772977
- DTXSID
DTXSID2059485- ChEMBL
CHEMBL352799- ChEBI
CHEBI:66932- UNII
- 1N39KD7QPJ
- EC Number
- 204-309-3
- Nikkaji
- J2.913K
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 1,5
- Polarare Oberfläche (TPSA)
- 130 Ų
- H-Brücken-Donoren
- 2
- H-Brücken-Akzeptoren
- 6
- Frei drehbare Bindungen
- 1
- Schwere Atome
- 14
- Formalladung
- 0
- Komplexität
- 235
Experimentelle und physikochemische Eigenschaften
Physikochemische Eigenschaften
- Schmelzpunkt
- 197 · 197-200 °C (lit.)
- Siedepunkt
- 335.43 °C · 335.43°C (rough estimate)
- Dichte
- 0.843 g/mL · 0.843 g/mL at 20 °C
- Brechungsindex
- 20 · n20/D 1.374
- Flammpunkt
- 14 °C · 14 °C
- storage temp.
- 2 · 2-8°C
- Löslichkeit
- 50 % · 50% sulfuric acid: 10 mg/mL, clear, colorless
- pka
- 12.1 · 12.1(at 25℃)
- Aggregatzustand
- crystals
- Farbe
- Red
- Wasserlöslichkeit
- slightly soluble
- Merck
- 14 · 14,3283
- BRN
- 615586 · 615586
- Stabilität
- Stable when wet, but explosive when dry. May be shock sensitive when dry. Highly flammable. Incompatible with strong oxidizing agents.
- Major Application
- Fuel cells, detecting microorganisms, antibacterial agent, treatment of acuteand chronic hepatitis, gynecopathy, cardiovascular diseases, cerebrovascular diseases
- InChI
- 1S/C6H6N4O4/c7-8-5-2-1-4(9(11)12)3-6(5)10(13)14/h1-3,8H,7H2
- InChIKey
- HORQAOAYAYGIBM-UHFFFAOYSA-N
- SMILES
- NNc1ccc(cc1[N+]([O-])=O)[N+]([O-])=O
- CAS Datenbank
- 119 · 119-26-6(CAS DataBase Reference)
- NIST chemische Informationen
- Hydrazine, (2,4-dinitrophenyl)-(119-26-6)
- EPA chemische Informationen
- 2 · 2,4-Dinitrophenylhydrazine (119-26-6)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H228 (93.4%): Flammable solid [Danger Flammable solids]
P210, P240, P241, P264, P264+P265, P270, P280, P301+P317, P305+P351+P338, P330, P337+P317, P370+P378, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 61 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory Information
Chemical: Hydrazine, (2,4-dinitrophenyl)-
2,4-Dinitropenylhydrazine: Does not have an individual approval but may be used under an appropriate group standard
Sicherheitsdaten
- F
- 8
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 3380 4.1/PG 1
- hs_code
- 29280000
- RTECS-Nr.
- MV3325000
- risk_code
- 1-11-22-40-2001/11/22
- hazard_code
- F,Xn
- safety_code
- 35-48A-45-36/37-16
- hazard_class
- 4.1
- packing_group
- II
- Speicherklasse
- 4.1A - Other explosive hazardous materials
- Hazard Classifications
- Acute Tox. 4 OralDesen. Expl. 1
Chemie und Industrie
Verwendung und Herstellung
Anwendungen
BeschreibungDas 2,4-Dinitrophenylhydrazin bildet rotbraune, wasserunlösliche, thermisch instabile Kristalle. Das trockene Produkt kann bei Schlag, Stoß oder Erhitzen heftig explodieren. Die Substanz ist ein häufig verwendetes Reagens in der organisch-chemischen Analyse. Es dient zum Nachweis und zur Identifizierung von Carbonylverbindungen. Insbesondere die Aldehyd- und Keton-2,4-dinitrophenylhydrazone kristallisieren gut und lassen sich leicht dünnschichtchromatographisch nachweisen.
Beschreibung2,4-Dinitrophenylhydrazine (abbreviated 2,4-DNP for short) is the chemical compound C6H3 (NO2) 2NHNH2, and it is often used to qualitatively test for carbonyl groups associated with aldehydes and ketones. The hydrazone derivatives can also be used as evidence toward the identity of the original compound. It is relatively sensitive to shock and friction; it is a shock explosive, so care must be taken with its use. To reduce its explosive hazard, it is usually supplied wet. 2,4-Dinitrophenylhydrazine is a compound with a benzene ring, two Nitro groups, and a hydrazine (two nitrogen atoms bonded directly to each other) functional group. It is used as a Brady's reagent to test the existing of a ketone or aldehyde.
Verwenden2,4-Dinitrophenylhydrazine is known was Brady's reagent, a substituted hydrazine that is often used for qualitative testing of carbonyl groups associated with aldehydes and ketones.
Vor- und nachgelagerte Produkte
Vorgelagerte Rohstoffe
Nachgelagerte Produkte
Ergänzende Hinweise
DefinitionChEBI: 2,4-dinitrophenylhydrazine is a C-nitro compound that is phenylhydrazine substituted at the 2- and 4-positions by nitro groups. It has a role as a reagent. It is a member of phenylhydrazines and a C-nitro compound.
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