2,4-Dinitrophenylhydrazin

(2,4-Dinitrophenyl)hydrazine

HCID 3772977

Grundinformationen

CAS
119-26-6
Standard-SMILES
NNc1ccc([N+](=O)[O-])cc1[N+](=O)[O-]
InChIKey
HORQAOAYAYGIBM-UHFFFAOYSA-N
Summenformel
C6H6N4O4
Durchschnittliche Molmasse
198,14 g/mol
Monoisotopische Masse
198,03890467

Überblick

2,4-dinitrophenylhydrazine is a C-nitro compound that is phenylhydrazine substituted at the 2- and 4-positions by nitro groups. It has a role as a reagent. It is a member of phenylhydrazines and a C-nitro compound.

Namen und Bezeichner

Bevorzugter Name
(2,4-Dinitrophenyl)hydrazine
IUPAC
(2,4-dinitrophenyl)hydrazine
Lokaler Name
2,4-Dinitrophenylhydrazin
Englischer Name
2,4-Dinitrophenylhydrazine
Summenformel
C6H6N4O4
Molmasse
198.14

Namen und Synonyme

2,4-Dinitrophenylhydrazine119-26-6(2,4-Dinitrophenyl)hydrazine2,4-DnphHydrazine, (2,4-dinitrophenyl)-1-Hydrazino-2,4-dinitrobenzene1N39KD7QPJNSC-5709DTXSID2059485CHEBI:66932RefChem:443841DTXCID5033462
Weitere Namen anzeigen
DNP(2,4-dinitrophenyl)-hydrazinDINITROPHENYL HYDRAZINE2,4-dinitrophenyl-hydrazin2,4-Dinitrophenylhydrazine, 97%, moist with 30-35% water2,4-Dinitrophenylhydrazine, reagent grade, with 30 - 35% of H2O
204-309-3DNPHBrady's reagent2,4-DinitrofenylhydrazinNSC 57092,4-DNP hydrazineCCRIS 31402,4-Dinitrofenylhydrazin [Czech]

Datenbank-Bezeichner

CAS
119-26-6
PubChem CID
3772977
DTXSID
DTXSID2059485
ChEMBL
CHEMBL352799
ChEBI
CHEBI:66932
UNII
1N39KD7QPJ
EC Number
204-309-3
Nikkaji
J2.913K

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,5
Polarare Oberfläche (TPSA)
130 Ų
H-Brücken-Donoren
2
H-Brücken-Akzeptoren
6
Frei drehbare Bindungen
1
Schwere Atome
14

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Uses -> Explosives
SpringerMaterials PropertiesChemical shift
Vapor Pressure0.0000125 [mmHg]
Physical DescriptionBlue-red flourescent crystals; [Sax] Red powder; [MSDSonline]

Physikochemische Eigenschaften

Schmelzpunkt
197 · 197-200 °C (lit.)
Siedepunkt
335.43 °C · 335.43°C (rough estimate)
Dichte
0.843 g/mL · 0.843 g/mL at 20 °C
Brechungsindex
20 · n20/D 1.374
Flammpunkt
14 °C · 14 °C
storage temp.
2 · 2-8°C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H228 (93.4%): Flammable solid [Danger Flammable solids]

P210, P240, P241, P264, P264+P265, P270, P280, P301+P317, P305+P351+P338, P330, P337+P317, P370+P378, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 61 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Hydrazine, (2,4-dinitrophenyl)-

2,4-Dinitropenylhydrazine: Does not have an individual approval but may be used under an appropriate group standard

Hazards SummaryEmits nitrogen oxides when heated to decomposition; Toxic by ingestion; An eye irritant; [Sax] Highly flammable; Explosive when dry; [MSDSonline]
Hazard Classes and CategoriesFlam. Sol. 1 (93.4%)

Sicherheitsdaten

F
8
wgk
3
tsca
TSCA listed
ridadr
UN 3380 4.1/PG 1
hs_code
29280000
RTECS-Nr.
MV3325000

Chemie und Industrie

Verwendung und Herstellung

UsesA dangerous explosive; [Sax] Used as a reagent for aldehydes and ketones; [Merck Index, 3283]
General Manufacturing InformationHydrazine, (2,4-dinitrophenyl)-: ACTIVE
Anwendungen · 3 Einträge

BeschreibungDas 2,4-Dinitrophenylhydrazin bildet rotbraune, wasserunlösliche, thermisch instabile Kristalle. Das trockene Produkt kann bei Schlag, Stoß oder Erhitzen heftig explodieren. Die Substanz ist ein häufig verwendetes Reagens in der organisch-chemischen Analyse. Es dient zum Nachweis und zur Identifizierung von Carbonylverbindungen. Insbesondere die Aldehyd- und Keton-2,4-dinitrophenylhydrazone kristallisieren gut und lassen sich leicht dünnschichtchromatographisch nachweisen.

Beschreibung2,4-Dinitrophenylhydrazine (abbreviated 2,4-DNP for short) is the chemical compound C6H3 (NO2) 2NHNH2, and it is often used to qualitatively test for carbonyl groups associated with aldehydes and ketones. The hydrazone derivatives can also be used as evidence toward the identity of the original compound. It is relatively sensitive to shock and friction; it is a shock explosive, so care must be taken with its use. To reduce its explosive hazard, it is usually supplied wet. 2,4-Dinitrophenylhydrazine is a compound with a benzene ring, two Nitro groups, and a hydrazine (two nitrogen atoms bonded directly to each other) functional group. It is used as a Brady's reagent to test the existing of a ketone or aldehyde.

Verwenden2,4-Dinitrophenylhydrazine is known was Brady's reagent, a substituted hydrazine that is often used for qualitative testing of carbonyl groups associated with aldehydes and ketones.

Ergänzende Hinweise

DefinitionChEBI: 2,4-dinitrophenylhydrazine is a C-nitro compound that is phenylhydrazine substituted at the 2- and 4-positions by nitro groups. It has a role as a reagent. It is a member of phenylhydrazines and a C-nitro compound.

Zugehörige Reaktionen

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