HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
tert-Butylamin-Boran
TERT-BUTYLAMINE BORANE · BORANE-TERT-BUTYLAMINE COMPLEX · Borane tert-butyL · BORANE-TERT-BUTYLAMINE · DDK314 · NSC 114045 · amine compL · butylamineborane
Identifikatoren & physikalische Daten
| CAS No. | 7337-45-3 |
|---|---|
| Summenformel | C4H14BN |
| Durchschnittliche Molmasse | 86,97 g/mol |
| Monoisotopische Masse | 87,1219296 g/mol |
| SMILES | [BH3-][NH2+]C(C)(C)C |
| InChIKey | HJUZMIDACSQXPA-UHFFFAOYSA-N |
| PubChem CID | 419331 |
| DTXSID | DTXSID50994086 |
| Lokaler Name | tert-Butylamin-Boran |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 16,6 |
|---|---|
| H-Brücken-Donoren | 1 |
| H-Brücken-Akzeptoren | 1 |
| Frei drehbare Bindungen | 1 |
| Schwere Atome | 6 |
| Formalladung | 0 |
| Komplexität | 37,3 |
| Schmelzpunkt | 98-100 °C (dec.)(lit.) |
| Dichte | 0,87 g/cm3 |
| Lagerbedingungen | Refrigerator |
| Löslichkeit | 27g/lSoluble in water (27 g/L at 20°C) and methanol. |
| Aggregatzustand | powder |
| Farbe | White to off-white |
| BRN | 4134905 |
| InChI | InChI=1S/C4H11N.BH3/c1-4(2,3)5/h5H2,1-3H31H3 |
| InChIKey | GKFJEDWZQZKYHV-UHFFFAOYSA-N |
| SMILES | N([H])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H].B |
| EPA chemische Informationen | Boron, trihydro(2-methyl-2-propanamine)-, (T-4)- (7337-45-3) |
Sicherheit & Vorschriften
| F | 9 |
|---|---|
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 2811 6.1/PG 3 |
| Zollcode | 29299090 |
| RTECS-Nr. | EO3900000 |
| R-Sätze (R) | 21-25-36/37/38 |
| Gefahrensymbole | T |
| Sicherheitshinweise (S) | 26-36/37-45 |
| Gefahrenklasse | 4.1Acute Tox. 3 DermalAcute Tox. 3 OralAquatic Chronic 2Eye Irrit. 2Skin Irrit. 2 |
| Verpackungsgruppe | III |
| Lagerklasse | 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects |
Anwendungen & Verwendung
Verwenden
Borane-tert-butylamine complex is used in stereoselective reduction of a steroidal ketone and for a review of amine boranes as selective reducing and hydroborating agents. It is also used as strong co-reducing agent in the syntheses of copper (I) oxide nanoparticles, diphosphine-protected gold nanocluster and 4-acetoxycinnamyl alcohols.