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Trisilberarsenit

Silver arsenite

HCID 44144454
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Grundinformationen

CAS
7784-08-9
Standard-SMILES
O[As](O)O.[Ag].[Ag].[Ag]
InChIKey
FQUOIMHWJGIXSS-UHFFFAOYSA-N
Summenformel
Ag3AsH3O3
Durchschnittliche Molmasse
449,548 g/mol
Monoisotopische Masse
446,64509

Überblick

Silver arsenite appears as a fine yellow powder. Sensitive to light. Irritating to skin, eyes, and mucous membranes. Highly toxic by ingestion and inhalation. Used to make dyes and insecticides.

Namen und Bezeichner

Bevorzugter Name
Silver arsenite
IUPAC
arsorous acid;silver
Lokaler Name
Trisilberarsenit
Englischer Name
SILVER ARSENITE
Summenformel
AgAsH3O3
Molmasse
233.81

Namen und Synonyme

Trisilver arseniteSilver orthoarseniteArsenous acid, trisilver(1+) saltArsenious acid, trisilver(1+) saltEINECS 232-048-5UN1683RefChem:183023232-048-57784-08-9ARSENIOUS ACID (H3ASO3), TRISILVER(1+) SALTSILVER ARSENITEArsorous acid--silver (1/3)
Weitere Namen anzeigen
Silver arseenitetrisilverarseniteSilver arsenate(III)silver,trioxidoarsaneSilver ortho-arsenitearsenousacid,trisilver(1+)saltArsenous acid trisilver(I) saltarseniousacid,trisilver(1+)salt
DTXSID60999047FQUOIMHWJGIXSS-UHFFFAOYSA-NSilver arsenite [UN1683] [Poison]

Datenbank-Bezeichner

CAS
7784-08-9
PubChem CID
44144454
DTXSID

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
60,7 Ų
H-Brücken-Donoren
3
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
0
Schwere Atome
7
Formalladung
0
Komplexität
8

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Metals -> Arsenic Compounds, Inorganic

Carcinogens

Physical Description · 2 Einträge

Silver arsenite appears as a fine yellow powder. Sensitive to light. Irritating to skin, eyes, and mucous membranes. Highly toxic by ingestion and inhalation. Used to make dyes and insecticides.

Yellow solid; [CAMEO]

Physikochemische Eigenschaften

CAS Datenbank
7784 · 7784-08-9
EPA chemische Informationen
Arsenous acid, trisilver(1+) salt (7784-08-9)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P270, P271, P273, P301+P316, P304+P340, P316, P321, P330, P391, P403+P233, P405, and P501 (click each P-code to see the statement)

The GHS information provided by 1 company from 1 notification to the ECHA C&L Inventory.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Restricted substance: Trisilver arsenite

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelPoison
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.

Hazards SummaryLight sensitive; A skin, eye, and mucous membrane irritant; Very toxic by ingestion and inhalation; [CAMEO] See Arsenic and the linked occupational diseases.
DOT ID and Guide1683 151
Reactive GroupSalts, Basic

Chemie und Industrie

Verwendung und Herstellung

UsesUsed to make dyes and insecticides; [CAMEO]

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DTXSID60999047
EC Number
232-048-5
Reactivity Profile
SILVER ARSENITE has weak oxidizing or reducing powers. Redox reactions can however still occur.
DOT Hazard Classification · 6 Einträge

Silver arsenite

Marine pollutant

Silver orthoarsenite

Marine pollutant

Silver arsenite

UN1683

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 2 Einträge

Acute Tox. 3 (100%)

Carcinogens

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

First Aid · 2 Einträge

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

General First Aid:

Exposure Control and Personal Protection · 3 Einträge

· Wear positive pressure self-contained breathing apparatus (SCBA).

Biological Exposure Indices (BEI) [ACGIH] - Inorganic arsenic plus methylated metabolites in urine = 35 ug As/L; end of workweek;

0.1 [mg/m3], inhalable fraction, as Ag (salts)[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

Immediate precautionary measure

Threshold Limit Values (TLV)0.01 [mg/m3], as As (0.01 mg/m3, as Ag [sol. compds.])
Permissible Exposure Limit (PEL)0.01 [mg/m3], as As (0.01 mg/m3, as Ag [sol. compds.])
Personal Protective Equipment (PPE)Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Emergency Response Planning GuidelinesSmall Fire
Immediately Dangerous to Life or Health (IDLH)5.0 [mg/m3], as As

Toxikologische Informationen

Adverse EffectsNeurotoxin - Sensorimotor

Sicherheitsdaten

ridadr
UN 1683
hazard_class
6.1
packing_group
II