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Ammonium molybdate anhydrous

HCID 485454
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GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
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Grundinformationen

CAS
12027-67-7
Standard-SMILES
O.O.O.O.[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[Mo].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[NH4+].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2]
InChIKey
XCOMAVCHADVANQ-UHFFFAOYSA-O
Summenformel
H32Mo7N6O28-42
Durchschnittliche Molmasse
1.235,9 g/mol
Monoisotopische Masse
1.249,46428

Überblick

Ammonium molybdate is a white to greenish-yellow solid. Sinks and mixes with water. (USCG, 1999)

Namen und Bezeichner

Bevorzugter Name
Ammonium molybdate anhydrous
IUPAC
hexaazanium;molybdenum;(oxygen(2-));tetrahydrate
Englischer Name
Ammonium molybdate tetrahydrate
Summenformel
4MoO3.3H2MoO4.4H2O.6H3N
Molmasse
1235.85

Namen und Synonyme

Hexaammonium molybdate tetrahydrateOGI154X474RefChem:915719DTXSID5036896MOLYBDENUM (AS AMMONIUM MOLYBDATE)Molybdate (Mo7O246-), hexaammonium, tetrahydrate234-320-9234-722-4603-021-912501-45-021Y68J178EAmmonium Molybdate
Weitere Namen anzeigen
HEXAAMMONIUM HEPTAMOLYBDATE TETRAHYDRATEAMMONIUM HEPTAMOLYBDATE TETRAHYDRATEAMMONIUM PARAMOLYBDATE TETRAHYDRATEMolybdate(6-),hexaammonium,tetrahydrateSOC MEDIAAmmonium MoLAmmoniumMolybdateArAmmoniumMolybdateGrybdate TetrahydrateAmmonium molybdate t
ammonium molybdate anhydrousAmmonium molybdate(VI) tetrahydrateAmmonium paramolybdateCHEBI:91249Diammonium molybdate ((NH4)2MoO4)Hexaammonium heptamolybdateMolybdate (Mo7O246-), ammonium (1:6)Molybdic acid, diammonium salt

Datenbank-Bezeichner

CAS
12027-67-7、12054-85-2、12501-45-0、13106-76-8

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
34 Ų
H-Brücken-Donoren
10
H-Brücken-Akzeptoren
28
Frei drehbare Bindungen
0
Schwere Atome
41
Formalladung
-42
Komplexität
0

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Inorganic Compounds
Density · 3 Einträge

1.4 at 68 °F 2.398 (USCG, 1999) - Denser than water; will sink

2.27 @25 °C

2.498 @25 °C

Melting Point90 °C
Physical Description · 3 Einträge

Ammonium molybdate is a white to greenish-yellow solid. Sinks and mixes with water. (USCG, 1999)

Liquid; Dry Powder; Large Crystals

White lumps or powder; Partially soluble in water; [MSDSonline]

Physikochemische Eigenschaften

Schmelzpunkt
190 °C · 190 °C
Siedepunkt
190 °C · 190°C
Dichte
2.498 g/mL · 2.498 g/mL at 25 °C (lit.)
storage temp.
Inert atmosphere,Room Temperature
Löslichkeit
2 O: · H2O: 0.05 M at 20 °C, clear, colorless
Aggregatzustand
Solid

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 90.4% (281 of 311) of all reports.

Not Classified

Aggregated GHS information provided per 311 reports by companies from 10 notifications to the ECHA C&L Inventory.

Warning

H302: Harmful if swallowed [Warning Acute toxicity, oral]

P203, P260, P261, P264, P264+P265, P270, P271, P280, P301+P317, P304+P340, P305+P351+P338, P318, P319, P330, P337+P317, P403+P233, P405, and P501 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 4 Einträge

Molybdate (Mo7O246-), ammonium (1:6) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Molybdate (Mo7O246-), ammonium (1:6) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Hexaammonium heptamolybdate (EC: 234-722-4)

Restricted substance: Hexaammonium heptamolybdate

Ammonium molybdate: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsSpecial Hazards of Combustion Products: Toxic oxides of nitrogen may form in fire. (USCG, 1999)
Health HazardsInhalation causes irritation of nose and throat. Contact with eyes causes irritation. (USCG, 1999)
Hazards SummaryAn irritant; [MSDSonline] See Ammonium molybdate tetrahydrate. See Molybdenum.
Reactive GroupSalts, Acidic
Reactivity Profile · 1 Eintrag

Chemie und Industrie

Pharmakologische Informationen

MeSH Pharmacological ClassificationChemicals and substances that impart color including soluble dyes and insoluble pigments. They are used in INKS; PAINTS; and as INDICATORS AND REAGENTS.

Verwendung und Herstellung

UsesA metallic negative stain that is used to negative stain the Formvar backing on coated electron microscopic grids for transmission electron microscopy. [Hayes, p. 2075]
U.S. Production2023: 2,500,000 - <4,000,000 lb
Consumer UsesIntermediate
Industry UsesIntermediate
Household ProductsInformation on 2 consumer products that contain Ammonium molybdate in the following categories is provided:
General Manufacturing Information · 2 Einträge

Petroleum Lubricating Oil and Grease Manufacturing

Molybdate (Mo7O246-), ammonium (1:6): ACTIVE

Anwendungen · 1 Eintrag

VerwendenAmmonium molybdate tetrahydrate is widely utilized in cryo-negative staining which helps to visualize particles while preserving the sample. It is used as a catalyst to desulfurize thiophene and its derivatives. It serves as an analytical reagent to measure the amount of phosphates, silicates, arsenates and lead in an aqueous solution. It is also used in electroplating, in fertilizers for crops and in the production of molybdenum metal and ceramics. It is used as an analgesic in medical field.

Vor- und nachgelagerte Produkte

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
PubChem CID
485454
UNII
OGI154X474
EC Number
234-722-4、601-720-3、603-021-9
Farbe
White to yellow-green
Geruch (Odor)
Odorless
PH
4 · 4.0-5.5 (25℃, 0.05M in H2O)
Wasserlöslichkeit
400 g/L · 400 g/L (20 ºC)
Merck
14 · 14,533
Stabilität
Stable. Incompatible with strong acids, strong oxidizing agents.
Kosmetik-Inhaltsstoffe Funktionen
BUFFERING
InChI
1S/Mo.H3N.H2O.O/h;1H3;1H2;/q;;;-2/p+1
InChIKey
XCOMAVCHADVANQ-UHFFFAOYSA-O
CAS Datenbank
12054 · 12054-85-2(CAS DataBase Reference)
EPA chemische Informationen
7 O24 · Molybdate [Mo7O24(6-)], hexaammonium, tetrahydrate (12054-85-2)
Absorption
360 nm · cut-off at 360nm in H2O at 0.05M

Acidic salts, such as AMMONIUM MOLYBDATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pH's of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions.

Air and Water ReactionsWater soluble.
Hazard Classes and Categories · 2 Einträge

Not Classified

Acute toxicity (Oral) - Category 4

Sicherheit und Schutzausrüstung

First AidINHALATION: move to fresh air.
Threshold Limit Values (TLV)0.5 [mg/m3], as Mo, respirable fraction
Permissible Exposure Limit (PEL)5.0 [mg/m3], as Mo
Protective Action Criteria (PAC) · 6 Einträge

3.1 [mg/m3]

11 [mg/m3]

66 [mg/m3]

2.8 [mg/m3]

30 [mg/m3]

180 [mg/m3]

Personal Protective Equipment (PPE)Dust mask; goggles or face shield; rubber gloves (USCG, 1999)
Immediately Dangerous to Life or Health (IDLH) · 2 Einträge

1000 mg Mo/m3 (NIOSH, 2024)

1000.0 [mg/m3], as Mo

Sicherheitsdaten

wgk
1
tsca
Yes
ridadr
3288
hs_code
28417000
RTECS-Nr.
QA5076000
risk_code
36/37/38-22-20/21/22
hazard_code
Xi,Xn
safety_code
26-37/39-36/37-36
hazard_class
8
Speicherklasse
11 - Combustible Solids

Vorgelagerte Rohstoffe

Molybdenum concentrateMolybddntrioxid

Nachgelagerte Produkte

desulfurizating hydrogenation Ni-Mo catalystsother desulfurizating hydrogenation catalystssulphur resistant CO shift catalystsmedium temperature Shift catalystsMolybddntrioxida new Mo/carbonized resin catalystMolybdaendisulfid[29H,31H-Phthalocyaninato(2-)-N29,N30,N31,N32]Kupfernoncyanide zinc plating additive-TDAEBleichromatmolybdatsulfatrotDinatrium-[29H,31H-phthalocyanindisulfonato(4-)-N29,N30,N31,N32]cuprat(2-)Molybdsuremedium(high)temperature Shift catalysts