HRID 1299688als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
1,2-Bis(diphenylphosphino)benzene
Grundinformationen
- CAS
13991-08-7- Standard-SMILES
c1ccc(P(c2ccccc2)c2ccccc2P(c2ccccc2)c2ccccc2)cc1- InChIKey
NFRYVRNCDXULEX-UHFFFAOYSA-N- Summenformel
- C30H24P2
- Durchschnittliche Molmasse
- 446,5 g/mol
- Monoisotopische Masse
- 446,13532403
Überblick
structure in first source
Namen und Bezeichner
- Bevorzugter Name
- 1,2-Bis(diphenylphosphino)benzene
- IUPAC
- (2-diphenylphosphanylphenyl)-diphenylphosphane
- Englischer Name
- 1,2-Bis(diphenylphosphino)benzene
- Summenformel
- C30H24P2
- Molmasse
- 446.47
Namen und Synonyme
1,2-Bis(diphenylphosphino)benzene13991-08-7DTXSID60333306RefChem:71736DTXCID30284396681-134-2dppBzMFCD00014081o-Bis(diphenylphosphino)benzeneo-Phenylenebis(diphenylphosphine)Phosphine, 1,1'-(1,2-phenylene)bis[1,1-diphenyl-(2-diphenylphosphanylphenyl)-diphenylphosphane
Weitere Namen anzeigen
dppbedppbendppbenzJACS-13991-08-71,2-Diphenylphosphine-benzene
[2-(diphenylphosphanyl)phenyl]diphenylphosphaneSCHEMBL150139o-Phenylenebis[diphenylphosphine]SY038943EN300-7396611[2-(Diphenylphosphino)phenyl](diphenyl)phosphine #Phosphine, phenylenebis[diphenyl-1,2-Bis(diphenylphosphanyl)benzene
Datenbank-Bezeichner
- CAS
13991-08-7- PubChem CID
- 498379
- DTXSID
DTXSID60333306- EC Number
- 681-134-2
- Nikkaji
- J726.283C
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 7,3
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 0
- Frei drehbare Bindungen
- 6
- Schwere Atome
- 32
- Formalladung
- 0
- Komplexität
- 439
Physikochemische Eigenschaften
- Schmelzpunkt
- 183 · 183-188 °C (lit.)
- Siedepunkt
- 546.9 · 546.9±33.0 °C(Predicted)
- storage temp.
- Inert atmosphere,Room Temperature
- Aggregatzustand
- Fine Crystalline Powder
- Farbe
- White
- Wasserlöslichkeit
- Insoluble in water.
- InChI
- InChI=1S/C30H24P2/c1-5-15-25(16-6-1)31(26-17-7-2-8-18-26)29-23-13-14-24-30(29)32(27-19-9-3-10-20-27)28-21-11-4-12-22-28/h1-24H
- InChIKey
- NFRYVRNCDXULEX-UHFFFAOYSA-N
- SMILES
- P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1
- CAS Datenbank
- 13991 · 13991-08-7(CAS DataBase Reference)
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 16.7% (1 of 6) of reports.
Warning
H315 (83.3%): Causes skin irritation [Warning Skin corrosion/irritation]
P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 6 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Hazard Classes and CategoriesSkin Irrit. 2 (83.3%)
Sicherheitsdaten
- wgk
- 3
- tsca
- No
- hs_code
- 29319090
- risk_code
- 36/37/38
- safety_code
- 24/25
- Speicherklasse
- 11 - Combustible Solids
Chemie und Industrie
Anwendungen
Verwenden1,2-Bis(diphenylphosphino)benzene (DPPB) can be used:As a chelating ligand in the synthesis of luminescent copper(I) halide complexes.In the synthesis of copper-1,2-bis(diphenylphosphino)benzene catalyst which is used for the β-boration of α, β-unsaturated amide.As an alternative to TMEDA for the selective cleavage of sp3 C-X bond in fluoroaromatic coupling reactions catalyzed by iron.As a ligand in the synthesis of alkenylboronates from acetylenic esters.To synthesize copper-diphosphine complexes which are used as homogeneous catalysts for N-formylation of a wide range of amines.
Anbieter100 Anbieter
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖南韵邦生物科技股份有限公司0731-88532326 13319508186 · [email protected]
山东春雨精细化工有限责任公司13561220159 · [email protected]
上海炎泽化工有限公司15345144255 19975051755 · [email protected]
INTATRADE GmbH+49 3493/605464 · [email protected]
上海遐瑞医药科技有限公司+86-021-61551413 · [email protected]
T&W GROUP021-61551611 13296011611 · [email protected]
Dayang Chem (Hangzhou) Co.,Ltd.+86-0571-88938639 17705817739 · [email protected]
韶远科技（上海）有限公司
Zugehörige Reaktionen
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HRID 1299689als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1299690als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1299691als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1299692als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1299693als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1299694als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
HRID 1299695als KatalysatorHigh-throughput exploration of 50,688 Pd-, Ni- and Cu-catalysed C–N coupling reactions
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