2,5-Dioxopyrrolidin-1-yl 2-(trimethylsilyl)ethyl carbonate

HCID 5018386

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Grundinformationen

CAS: 78269-85-9
Standard-SMILES: C[Si](C)(C)CCOC(=O)ON1C(=O)CCC1=O
InChIKey: FLDNDAMSCINJDX-UHFFFAOYSA-N
Summenformel: C10H17NO5Si
Durchschnittliche Molmasse: 259,33 g/mol
Monoisotopische Masse: 259,08759918

Namen und Bezeichner

Bevorzugter Name: 2,5-Dioxopyrrolidin-1-yl 2-(trimethylsilyl)ethyl carbonate
IUPAC: (2,5-dioxopyrrolidin-1-yl) 2-trimethylsilylethyl carbonate
Englischer Name: 1-(2-(Trimethylsilyl)ethoxycarbonyloxy)&
Summenformel: C10H17NO5Si
Molmasse: 259.33

Namen und Synonyme

2,5-dioxopyrrolidin-1-yl 2-(trimethylsilyl)ethyl carbonateRefChem:444650628-606-678269-85-92,5-Dioxopyrrolidin-1-yl (2-(trimethylsilyl)ethyl) carbonateN-[2-(Trimethylsilyl)ethoxycarbonyloxy]succinimideTeoc-OSu1-[2-(Trimethylsilyl)ethoxycarbonyloxy]pyrrolidin-2,5-dione(2,5-dioxopyrrolidin-1-yl) 2-trimethylsilylethyl CarbonateMFCD02683467C10H17NO5Si2,5-Dioxopyrrolidin-1-yl (2-(trimethylsilyl)-ethyl) carbonate

Weitere Namen anzeigen

1-(2-(Trimethylsilyl)ethoxycarbonyloxy)&1-(2-(TRIMETHYLSILYL)ETHOXYCARBONYLOXY)&(TriMethylsilyl)ethoxycarbonyloxy]succiniMide1-[[[2-(Trimethylsilyl)ethoxy]carbonyl]oxy]-2(triMethylsilyl)ethoxy]carbonyl}oxy)pyrrolidine-2,5-dioneN-[2-(Trimethylsilyl)ethoxycarbonyloxy]succinimide≥ 98%(N)TEOC-OSU N-[2-(trimethylsilyl)ethoxycarbonyloxy]succinimideN-[2-(trimethylsilyl)ethoxycarbonyloxy]succinimide(Teoc-Osu)

1-({[2-(trimethylsilyl)ethoxy]carbonyl}oxy)pyrrolidine-2,5-dioneTeocOSu2,5-Pyrrolidinedione, 1-[[[2-(trimethylsilyl)ethoxy]carbonyl]oxy]-SCHEMBL2081842,5-Dioxopyrrolidin-1-yl(2-(trimethylsilyl)ethyl)carbonateDTXSID10407561FLDNDAMSCINJDX-UHFFFAOYSA-NAKOS015840149

Datenbank-Bezeichner

CAS: 78269-85-9
PubChem CID: 5018386
DTXSID: DTXSID10407561
EC Number: 628-606-6

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 72,9 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 5
Frei drehbare Bindungen: 6
Schwere Atome: 17
Formalladung: 0
Komplexität: 320

Physikochemische Eigenschaften

Schmelzpunkt: 83 · 83-88 °C(lit.)
Siedepunkt: 308.6 · 308.6±44.0 °C(Predicted)
Dichte: 1.17 · 1.17±0.1 g/cm3(Predicted)
storage temp.: 2 · 2-8°C
Löslichkeit: soluble in Methanol
Aggregatzustand: powder to crystal
Farbe: White to Almost white
InChI: InChI=1S/C10H17NO5Si/c1-17(2,3)7-6-15-10(14)16-11-8(12)4-5-9(11)13/h4-7H2,1-3H3
InChIKey: FLDNDAMSCINJDX-UHFFFAOYSA-N
SMILES: C(OCC[Si](C)(C)C)(=O)ON1C(=O)CCC1=O

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.6%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.6%)

Sicherheitsdaten

wgk: 3
hs_code: 2931.90.9010
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
Speicherklasse: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Anwendungen

Verwenden1-[2-(Trimethylsilyl)ethoxycarbonyloxy]pyrrolidin-2,5-dione (Teoc-OSu) may be used as an acylating reagent to produce Teoc-amino acid derivatives.