Grundinformationen
- Standard-SMILES
O=S(=O)([O-])O.[Na+]- InChIKey
WBHQBSYUUJJSRZ-UHFFFAOYSA-M- Summenformel
- HNaSO4
- Durchschnittliche Molmasse
- 120,06 g/mol
- Monoisotopische Masse
- 119,94932379
Überblick
Bisulfate, aqueous solution is a white crystalline solid dissolved in water. It is corrosive to metals and tissue.
Namen und Bezeichner
- Bevorzugter Name
- Sodium Bisulfate
- IUPAC
- sodium hydrogen sulfate
- Lokaler Name
- Natriumhydrogensulfat
- Englischer Name
- Sodium bisulfate
- Summenformel
- NaHSO4
- Molmasse
- 121.07
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
7681-38-1- PubChem CID
- 516919
- DTXSID
DTXSID3033983- ChEMBL
CHEMBL1200488- UNII
- BU8V88OWIQ
- EC Number
- 231-665-7
- Nikkaji
- J44.044B
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 85,8 Ų
- H-Brücken-Donoren
- 1
- H-Brücken-Akzeptoren
- 4
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 6
- Formalladung
- 0
- Komplexität
- 93,2
Experimentelle und physikochemische Eigenschaften
Physical Description
Bisulfate, aqueous solution is a white crystalline solid dissolved in water. It is corrosive to metals and tissue.
Other Solid; Dry Powder; Liquid; Other Solid; Liquid
White, odourless crystals or granules
White crystals dissolved in water; [CAMEO] Hygroscopic crystals; [CHEMINFO]
Physikochemische Eigenschaften
- Schmelzpunkt
- 315 °C · 315 °C
- Dichte
- 2.1 · 2.1
- Aggregatzustand
- Granules
- pka
- 1.99 · 1.99
- Farbe
- White to light yellow
- Wasserlöslichkeit
- 2 parts · soluble in 2 parts H2O, 1 part boiling H2O; decomposes in alcohol to sodium sulfate and H2SO4 [MER06]
- Merck
- 13 · 13,8658
- Stabilität
- Stable. Incompatible with strong bases, strong oxidizing agents, sodium carbonate, sodium hypochlorite. May decompose upon exposure to moist air or water.
- Kosmetik-Inhaltsstoffe Funktionen
- BUFFERING
- InChI
- InChI=1S/Na.H2O4S.H/c;1-5(2,3)4;/h;(H2,1,2,3,4);
- InChIKey
- TTXJTWGBBUPRBF-UHFFFAOYSA-N
- SMILES
- S(O)(O)(=O)=O.[NaH]
- CAS Datenbank
- 7681 · 7681-38-1(CAS DataBase Reference)
- EPA chemische Informationen
- Sodium bisulfate (7681-38-1)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H318: Causes serious eye damage [Danger Serious eye damage/eye irritation]
P264+P265, P280, P305+P354+P338, and P317 (click each P-code to see the statement)
This chemical does not meet GHS hazard criteria for 0.3% (2 of 794) of reports.
Danger
H318 (99.6%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
Gefahrenhinweise
Regulatory Information
Chemical: Sulfuric acid, monosodium salt
Regulation (EC) No 1333/2008 (amended)
Sulfuric acid, sodium salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfuric acid, sodium salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 24-02-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/14458
Sodium hydrogen sulphate: Does not have an individual approval but may be used under an appropriate group standard
Fire Hazards
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Health Hazards
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.
Hazards Summary
Corrosive to metals and tissues; Toxic by ingestion, inhalation, or skin contact; [CAMEO] Aqueous solutions are strong acids; [Merck Index] Harmful if swallowed; Do not inhale dust or aerosol; may cause acute lung edema if inhaled; [MSDSonline] Based on animal studies, not a skin irritant; [CHEMINFO]
Reactivity Profile
Acidic salts, such as SODIUM BISULFATE, SOLUTION, are generally soluble in water. The resulting solutions contain moderate concentrations of hydrogen ions and have pHs of less than 7.0. They react as acids to neutralize bases. These neutralizations generate heat, but less or far less than is generated by neutralization of inorganic acids, inorganic oxoacids, and carboxylic acid. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible. Many of these compounds catalyze organic reactions. The combination of calcium hypochlorite, sodium hydrogen sulfate, starch, and sodium carbonate, when compressed, caused the materials to incandescence, followed by explosion, [Ind. Eng. Chem., 1937, 15, 282].
Hazard Classes and Categories
Eye Dam. 1 (99.6%)
Eye damage - category 1
Serious eye damage/eye irritation - Category 2
Eye Dam. 1
Sicherheit und Schutzausrüstung
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
General First Aid:
Isolation and Evacuation
Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Immediate precautionary measure
Protective Action Criteria (PAC)
8.4 [mg/m3]
92 [mg/m3]
550 [mg/m3]
Toxikologische Informationen
Sicherheitsdaten
- F
- 3
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- 3260
- hs_code
- 28331900
- RTECS-Nr.
- VZ1860000
- risk_code
- 41
- hazard_code
- Xi
- safety_code
- 24-26
- hazard_class
- 8
- packing_group
- II
- Speicherklasse
- 11 - Combustible Solids
- Hazard Classifications
- Eye Dam. 1
Chemie und Industrie
Pharmakologische Informationen
Verwendung und Herstellung
Uses
Used as a bactericide and disinfectant; [ChemIDplus] Used to pickle metals, carbonize wool, bleach leather, and manufacture magnesia cements; [Merck Index]
Acid and Alkali Cleaning of Metals [Category: Clean]
Use Classification
EPA Safer Chemical Functional Use Classes -> Antimicrobial Actives;Processing Aids and Additives
Safer Chemical Classes -> Green circle - The chemical has been verified to be of low concern
Food additives
Food Additives -> ACID -> JECFA Functional Classes
Cosmetics -> Buffering
General Manufacturing Information
Miscellaneous Manufacturing
Sulfuric acid, sodium salt (1:1): ACTIVE
Anwendungen
Verwendensodium bisulfate is an inorganic salt used as an anti-septic and a pH adjuster in cosmetic creams. Concentrated solutions can produce strong irritation.
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