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Mangantrifluorid
MnF3 · Manganic fluoride · MANGANESE TRIFLUORIDE · Manganese(Ⅲ) Fluoride · manganesefluoride(mnf3) · Manganese(III) fluoride · Manganese fluoride (III) · Manganese fluoride (MnF3)
Identifikatoren & physikalische Daten
| CAS No. | 7783-53-1 |
|---|---|
| Summenformel | F3Mn |
| Durchschnittliche Molmasse | 111,9333 g/mol |
| Monoisotopische Masse | 111,933253 g/mol |
| SMILES | [F][Mn]([F])[F] |
| InChIKey | SRVINXWCFNHIQZ-UHFFFAOYSA-K |
| PubChem CID | 522682 |
| EC No. | 232-006-6 |
| DTXSID | DTXSID50893904 |
| Lokaler Name | Mangantrifluorid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 3 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 4 |
| Formalladung | 0 |
| Komplexität | 8 |
| Stoffklassen | Metals -> Manganese Compounds, Inorganic |
| Physical Description | Red solid[Merck Index] |
| Schmelzpunkt | decomposes at >600℃ [KIR81] |
| Dichte | 3.54 g/mL at 25 °C(lit.) |
| Löslichkeit | reacts with H2OInsoluble in organic solvents. Hydrolyzed by water. |
| Aggregatzustand | Powder |
| Farbe | red |
| Wichte | 3.54 |
| Merck | 14,5741 |
| Stabilität | Stable. Incompatible with strong oxidizing agents. Protect from moisture. Contact with combustible material may lead to fire. |
| Hauptanwendungen | battery precursorscatalystsmaterial synthesis precursor |
| InChI | 1S/3FH.Mn/h3*1H/q+3/p-3 |
| InChIKey | SRVINXWCFNHIQZ-UHFFFAOYSA-K |
| SMILES | F[Mn](F)F |
| CAS Datenbank | 7783-53-1(CAS DataBase Reference) |
| EPA chemische Informationen | Manganese fluoride (MnF3) (7783-53-1) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH272 (88.6%): May intensify fireoxidizer [Danger Oxidizing liquidsOxidizing solids]P210, P220, P261, P264, P264+P265, P270, P271, P280, P301+P316, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 44 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Gefahrenübersicht | Toxic material[Hawley] See Manganese and linked occupational diseases. |
| Hazard Classes and Categories | Ox. Sol. 2 (88.6%) |
| Expositionsschutz und Persönliche Schutzausrüstung | Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift(Repeated measurements recommended.)0.2 [mg/m3], as Mn (inhalable fraction), 0.02 mg/m3, as Mn (respirable fraction) [1 mg/m3, as F, inhalable fraction][German Research Foundation (DFG)] |
| Minimum Risk Level | Chronic Inhalation: 0.0003 mg/m3 (L134) |
| Threshold Limit Values (TLV) | 0.02 [mg/m3], as Mn (respirable fraction), 0.1 mg/m3, as Mn (inhalable fraction) (2.5 mg/m3, as F) |
| Permissible Exposure Limit (PEL) | 2.5 [mg/m3]Ceiling(OSHA)=5 mg/m3, as Mn |
| Treatment | EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration. |
| Gesundheitliche Auswirkungen | Manganese mainly affects the nervous system and may cause behavioral changes and other nervous system effects, which include movements that may become slow and clumsy. This combination of symptoms when sufficiently severe is referred to as “manganism”. (L228) |
Anwendungen & Verwendung
Verwenden
Fluorinating agent in organic chemistry.