HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Thiram
TMTD · THIRAM · 1,1’-dithiobis(n,n-dimethylthio-formamid · THIURAM · TETRAMETHYLTHIURAM DISULPHIDE · Tetramethylthiuram · TNTD · tmtc
Identifikatoren & physikalische Daten
| CAS No. | 137-26-8 |
|---|---|
| Summenformel | C6H12N2S4 |
| Durchschnittliche Molmasse | 240,4 g/mol |
| Monoisotopische Masse | 239,98833309 g/mol |
| SMILES | CN(C)C(=S)SSC(=S)N(C)C |
| InChIKey | KUAZQDVKQLNFPE-UHFFFAOYSA-N |
| PubChem CID | 5455 |
| ChEMBL | CHEMBL120563 |
| ChEBI | CHEBI:9495 |
| EC No. | 205-286-2 |
| DTXSID | DTXSID5021332 |
| Lokaler Name | Thiram |
Chemische & physikalische Eigenschaften
| XLogP | 1,7 |
|---|---|
| Polarare Oberfläche (TPSA) | 121 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 4 |
| Frei drehbare Bindungen | 3 |
| Schwere Atome | 12 |
| Formalladung | 0 |
| Komplexität | 158 |
| LogP (Verteilungskoeffizient) | log Kow = 1.731.82 |
| Geruch | Characteristic odor |
| Dichte | 1.43 at 68 °F (USCG, 1999) - Denser than waterwill sink1.3 g/cu cm1.3 g/cm³1.3 @25 °C1.29 |
| Color/Form | White crystalline powderColorless to yellow, crystalline solid. (Note: commercial pesticide product may be dyed blue.) |
| Löslichkeit | less than 1 mg/mL at 72 °F (NTP, 1992)Solubility in alcohol and in ether less than 0.2%solubility in acetone 1.2%in benzene 2.5%.Sol in carbon disulfideSolubility in ethanol <10 g/L at 25 °C, acetone 80 g/L at 25 °C, chloroform 230 g/L at 25 °C, hexane 0.04 g/L at 20 °Cdichloromethane 170 g/L at 20 °C, toluene 18 g/L at 20 °C, isopropanol 0.7 g/L at 20 °C.In water, 30 mg/L at 25 °CSolubility in water: none0.0184g/l16.5 mg/L (20 ºC) |
| Corrosivity | Non-corrosive in the dry state. |
| Flammpunkt | 280 °F (NTP, 1992)89 °C (192 °F) (closed cup)89 °C c.c.89°C |
| Siedepunkt | 264 °F at 20 mmHg (NTP, 1992)129 °C at 20 mm Hgat 2.6kPa: 129 °C264 °F at 20 mmHgDecomposes129 °C (20 mmHg) |
| Schmelzpunkt | 311 to 313 °F (NTP, 1992)155-156 °CMP: 146 °C /Commercial grade/312 °F156-158 °C(lit.) |
| Geruchsschwelle | 5 mg/cu m |
| Dampfdruck | 0 mmHg at 68 °F approximately (NTP, 1992)0.0000172 [mmHg]1.72X10-5 mm Hg at 25 °CVapor pressure at 20 °C: negligible0.000008 mmHg0.000017 [mm Hg] @25 °C8 x 10-6 mmHg at 20 °C (NIOSH, 1997) |
| Henry-Konstante | Henry's Law constant = 3.26X10-7 atm-cu m/mol at 25 °C9.3×101 mol/(m3Pa) at 25℃, Mackay et al. (2006) |
| Brechungsindex | 1.5500 (estimate) |
| Lagerbedingungen | under inert gas (argon) |
| Aggregatzustand | solid |
| pKa (Säurekonstante) | 0.87±0.50(Predicted) |
| Spezifische Wärmekapazität | Cp(crystal): 1.25 J/(g·K), at 25℃ |
| Merck | 14,9371 |
| BRN | 1725821 |
| Kosmetik-Inhaltsstoffe Funktionen | ANTIMICROBIAL |
| InChI | 1S/C6H12N2S4/c1-7(2)5(9)11-12-6(10)8(3)4/h1-4H3 |
| InChIKey | KUAZQDVKQLNFPE-UHFFFAOYSA-N |
| SMILES | CN(C)C(=S)SSC(=S)N(C)C |
| LogP (Verteilungskoeffizient) | 1.730 |
| CAS Datenbank | 137-26-8(CAS DataBase Reference) |
| NIST chemische Informationen | Thiram(137-26-8) |
| EPA chemische Informationen | Thiram (137-26-8) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH302: Harmful if swallowed [Warning Acute toxicity, oral]H315: Causes skin irritation [Warning Skin corrosion/irritation]H317: May cause an allergic skin reaction [Warning Sensitization, Skin]H319: Causes serious eye irritation [Warning Serious eye damage/eye irritation]H332: Harmful if inhaled [Warning Acute toxicity, inhalation]H373 **: May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]H400: Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]H410: Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P391, and P501 (click each P-code to see the statement) |
|---|---|
| Regulatorische Informationen | Chemical: Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), N,N,Nâ²,Nâ²-tetramethyl-Hazard Traits - NeurotoxicityAuthoritative List - IRIS NeurotoxicantsReport - if used as a fragrance or flavor ingredientRegulation (EC) No 396/2005 (amended)Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), N,N,N',N'-tetramethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), N,N,N',N'-tetramethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Thiram is listed in the dataset of EPA Human Health Benchmarks for Pesticides under the Safe Drinking Water Act (40 eCFR 141)03/81/EC, Reg. (EU) 2016/2016, Reg. (EU) No 540/2011, Reg. (Eu) 2018/1500, Reg.(EU)2018/524 |
| Weitere Sicherheitsinformationen | IMAP assessments - Thioperoxydicarbonic diamide ([(H2N)C(S)]2S2), tetramethyl-: Human health tier II assessment |
| DOT-Kennzeichnung | Poison |
| Brandgefahren | Special Hazards of Combustion Products: Toxic and irritating oxides of sulfur are formed. Carbon disulfide may be formed from unburned material. (USCG, 1999) |
Anwendungen & Verwendung
Beschreibung
Tetramethylthiuram disulfide is a rubber chemieal, an accelerator of vulcanization. It represents the most commonly positive allergen contained in the "thiuram mix". The most frequent occupational categories are the metal industry, homemakers, health services and laboratories, building industries, and shoemakers.
Verwenden
Tetramethylthiuram disulfide is used as fungicide; bacteriostat; pesticide; rubber vulcanization accelerator; scabicide; seed disinfectant; animal repellent; insecticide; lube-oil additive; wood preservative; in antiseptic sprays; in the blending of lubrieant oils; used against Botrytis, rusts and downy mildews; seed dressing against "damping off' and verticillium wilt; ethanol antagonist and deterrent in mixtures of the methyl, ethyl, propyl, and butyl derivatives; antioxidant in polyolefin plastics; peptizing agent in polysulphide elastomers; in soaps and rodent repellents; nut, fruit, and mushroom disinfectant.