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Tris(pentan-2,4-dionato)eisen(II)
Fe(acac)3 · IRON(III) ACETYLACETONATE · IRON ACETYLACETONATE · Iron triacetylacetonate · TRIS(2,4-PENTANEDIONATO)IRON(III) · acetonate · Iron (Ⅲ) acetylacetonate · Tris(acetylacetonato)iron
Identifikatoren & physikalische Daten
| CAS No. | 14024-18-1 |
|---|---|
| Summenformel | C15H21FeO6 |
| Durchschnittliche Molmasse | 353,17 g/mol |
| Monoisotopische Masse | 353,068749 g/mol |
| SMILES | CC(=O)/C=C(/C)[O-].CC(=O)/C=C(/C)[O-].CC(=O)/C=C(/C)[O-].[Fe+3] |
| InChIKey | AQBLLJNPHDIAPN-LNTINUHCSA-K |
| PubChem CID | 5483663 |
| Lokaler Name | Tris(pentan-2,4-dionato)eisen(II) |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 120 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 6 |
| Frei drehbare Bindungen | 3 |
| Schwere Atome | 22 |
| Formalladung | 0 |
| Komplexität | 90 |
| Physical Description | Dry PowderDark red powderInsoluble in water[Alfa Aesar MSDS] |
| Schmelzpunkt | 180-182 °C (dec.)(lit.) |
| Siedepunkt | 110°C 2mm |
| Dichte | 5.24 g/mL at 25 °C(lit.) |
| Dampfdruck | 2.6 hPa (110 °C) |
| Lagerbedingungen | Store below +30°C. |
| Löslichkeit | Soluble in toluene.2 g/L (20 ºC) |
| Aggregatzustand | Powder |
| Farbe | Red |
| Wichte | 5.24 |
| BRN | 4157960 |
| Stabilität | Stable. Incompatible with strong bases, strong oxidizing agents. |
| InChI | 1S/3C5H8O2.Fe/c3*1-4(6)3-5(2)7/h3*3,6H,1-2H3/q+3/p-3/b3*4-3- |
| InChIKey | AQBLLJNPHDIAPN-LNTINUHCSA-K |
| SMILES | CC(=O)\C=C(\C)O[Fe](O\C(C)=C/C(C)=O)O\C(C)=C/C(C)=O |
| LogP (Verteilungskoeffizient) | 0.4 at 20℃ |
| NIST chemische Informationen | Iron tris(acetylacetonate)(14024-18-1) |
| EPA chemische Informationen | Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)- (14024-18-1) |
Sicherheit & Vorschriften
| Regulatorische Informationen | Iron, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Iron, tris(2,4-pentanedionato-.kappa.O2,.kappa.O4)-, (OC-6-11)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711) |
|---|---|
| Gefahrenübersicht | Intraperitoneal LD50 (mouse) = 76 mg/kg[RTECS] An eye irritantHarmful by ingestion[Alfa Aesar MSDS] See Iron oxide (Fe2O3). |
| F | 21 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| Zollcode | 29420000 |
| RTECS-Nr. | NO8960000 |
| R-Sätze (R) | 22-36 |
| Toxizität | LD50 orally in Rabbit: 1872 mg/kg |
| Gefahrensymbole | Xn |
| Sicherheitshinweise (S) | 26-37/39 |
| Lagerklasse | 11 - Combustible Solids |
| Gefahrenklasse | Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralEye Dam. 1 |
Anwendungen & Verwendung
Verwenden
Moderating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate.
Herstellung & Synthese
synthetische
Ferric acetylacetonate is prepared by shaking ferric hydroxide with an alcoholic solution of the reagent. It is an excellent quencher of triplet states.