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3-Ethylaminophenol

HCID 578991
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GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
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Grundinformationen

CAS
621-31-8
Standard-SMILES
CCNc1cccc(O)c1
InChIKey
TVKZDKSHNITMRZ-UHFFFAOYSA-N
Summenformel
C8H11NO
Durchschnittliche Molmasse
137,18 g/mol
Monoisotopische Masse
137,08406397

Überblick

3-ethylaminophenol is a very viscous deep orange liquid. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name
3-Ethylaminophenol
IUPAC
3-(ethylamino)phenol
Lokaler Name
3-Ethylaminophenol
Englischer Name
3-Ethylaminophenol
Summenformel
C8H11NO
Molmasse
137.18

Namen und Synonyme

3-(Ethylamino)phenol3-ETHYLAMINOPHENOLn-ethyl-m-aminophenolCCRIS 4640EINECS 210-678-1UNII-L26AT05W85BRN 2637735L26AT05W85Phenol, 3-ethylamino-N-ETHYL-3-AMINOPHENOLDTXSID60252700-13-00-00408 (Beilstein Handbook Reference)
Weitere Namen anzeigen
m-(ethylamino)-pheno3-(ethylamino)-pheno3-Hydroxyphenylethylamine
RefChem:93846META-ETHYLAMINOPHENOLDTXCID005270TVKZDKSHNITMRZ-UHFFFAOYSA-N621-31-8Phenol, 3-(ethylamino)-Phenol, m-(ethylamino)-m-(Ethylamino)phenol

Datenbank-Bezeichner

CAS
621-31-8
PubChem CID
578991
DTXSID
DTXSID6025270
UNII
L26AT05W85
EC Number
210-678-1
Nikkaji
J31.081F

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,9
Polarare Oberfläche (TPSA)
32,3 Ų
H-Brücken-Donoren
2
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
2
Schwere Atome
10
Formalladung
0
Komplexität
95,3

Experimentelle und physikochemische Eigenschaften

Solubility0.1 to 1 mg/mL at 64 °F (NTP, 1992)
Boiling Point349 °F at 12 mmHg (NTP, 1992)
Melting Point144 °F (NTP, 1992)
Physical Description3-ethylaminophenol is a very viscous deep orange liquid. (NTP, 1992)

Physikochemische Eigenschaften

Schmelzpunkt
62 °C · 62°C
Siedepunkt
252.03 °C · 252.03°C (rough estimate)
Dichte
1.063 · 1.0630 (rough estimate)
Brechungsindex
1.556 · 1.5560 (estimate)
storage temp.
2 · 2-8°C
Löslichkeit
Chloroform (Slightly), Methanol (Slightly)
Aggregatzustand
Solid
pka
10.36 · 10.36±0.10(Predicted)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Warning

H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P264, P270, P273, P301+P317, P330, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 40 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

DOT LabelCorrosive
Fire HazardsFlash point data for this compound are not available, however, it is probably combustible. (NTP, 1992)
Health HazardsExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Reactive GroupAmines, Phosphines, and Pyridines
Reactivity Profile · 1 Eintrag

An amine and phenol. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. Phenols do not behave as organic alcohols, as one might guess from the presence of a hydroxyl (-OH) group in their structure. Instead, they react as weak organic acids. Phenols and cresols are much weaker as acids than common carboxylic acids (phenol has pKa = 9.88). These materials are incompatible with strong reducing substances such as hydrides, nitrides, alkali metals, and sulfides. Flammable gas (H2) is often generated, and the heat of the reaction may ignite the gas. Heat is also generated by the acid-base reaction between phenols and bases. Such heating may initiate polymerization of the organic compound. Phenols are sulfonated very readily (for example, by concentrated sulfuric acid at room temperature). The reactions generate heat. Phenols are also nitrated very rapidly, even by dilute nitric acid.

Chemie und Industrie

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

3-(ethylamino)cyclohex-2-en-1-one3-Aminocyclohex-2-en-1-onAcetonitril3-Aminophenol

Anbieter

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Öffentliche Anfragen

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Zugehörige Reaktionen

7
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 329354
HRID 329354als Produktuspto-grants-1990_01
Reaktionsgleichung von HRID 733031
HRID 733031als Eduktuspto-grants-2009_09
Reaktionsgleichung von HRID 733032
HRID 733032als Eduktuspto-grants-2009_09
Reaktionsgleichung von HRID 1382182
HRID 1382182als Produktuspto-grants-1989_02
Reaktionsgleichung von HRID 1382183
HRID 1382183als Eduktuspto-grants-1989_02
Reaktionsgleichung von HRID 1674509
HRID 1674509als Eduktuspto-grants-2011_08
Reaktionsgleichung von HRID 1674510
HRID 1674510als Eduktuspto-grants-2011_08

Notizen zur Verbindung

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
Farbe
Light Brown to Very Dark Red
EPA chemische Informationen
3 · 3-(Ethylamino)phenol (621-31-8)
Air and Water ReactionsThis chemical may be sensitive to prolonged exposure to air. (NTP, 1992). Slightly soluble in water.
Hazard Classes and CategoriesAcute Tox. 4 (100%)

Sicherheit und Schutzausrüstung

Fire FightingFires involving this compound can be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:
Personal Protective Equipment (PPE) · 1 Eintrag

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Sicherheitsdaten

ridadr
1759
hs_code
2922290090
risk_code
34
safety_code
26-36/37/39