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Aluminiumtri-sec-butanolat
ASB · ALUMINUM S-BUTOXIDE · ALUMINUM SEC-BUTOXIDE · ALUMINIUM SEC-BUTOXIDE · ANH1 · XLSA · XLDPP · XLEPP
Identifikatoren & physikalische Daten
| CAS No. | 2269-22-9 |
|---|---|
| Summenformel | C12H27AlO3 |
| Durchschnittliche Molmasse | 246,32 g/mol |
| Monoisotopische Masse | 246,17755835 g/mol |
| SMILES | CCC(C)[O-].CCC(C)[O-].CCC(C)[O-].[Al+3] |
| InChIKey | WOZZOSDBXABUFO-UHFFFAOYSA-N |
| PubChem CID | 61289 |
| DTXSID | DTXSID3044386 |
| Lokaler Name | Aluminiumtri-sec-butanolat |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 69,2 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 3 |
| Frei drehbare Bindungen | 3 |
| Schwere Atome | 16 |
| Formalladung | 0 |
| Komplexität | 19,6 |
| Siedepunkt | 40 °C |
| Dichte | 0.967 g/mL at 25 °C(lit.) |
| Dampfdruck | 23 hPa (195 °C) |
| Brechungsindex | 1.4390 |
| Flammpunkt | 82 °F |
| Lagerbedingungen | Store below +30°C. |
| Löslichkeit | Miscible with alcohol, isopropyl alcohol and toluene.decomposes |
| Aggregatzustand | Oily Liquid |
| Farbe | Light yellow |
| Wichte | 0.9671 |
| Explosionsgrenze | 1.7-9.8%(V) |
| BRN | 3910908 |
| Stabilität | Stability Stable, but may decompose upon exposure to air and moisture. Flammable. Incompatible with strong oxidizing agents, strong acids, water. |
| Kosmetik-Inhaltsstoffe Funktionen | LIGHT STABILIZER |
| InChI | 1S/3C4H9O.Al/c3*1-3-4(2)5/h3*4H,3H2,1-2H3/q3*-1+3 |
| InChIKey | WOZZOSDBXABUFO-UHFFFAOYSA-N |
| SMILES | CCC(C)O[Al](OC(C)CC)OC(C)CC |
| CAS Datenbank | 2269-22-9(CAS DataBase Reference) |
| NIST chemische Informationen | Aluminum tri-sec-butoxide(2269-22-9) |
| EPA chemische Informationen | 2-Butanol, aluminum salt (2269-22-9) |
Sicherheit & Vorschriften
| Minimum Risk Level | Intermediate Oral: 1.0 mg/kg/day (L134) Chronic Oral: 1.0 mg/kg/day (L134) |
|---|---|
| Gesundheitliche Auswirkungen | Aluminum targets the nervous system and causes decreased nervous system performance and is associated with altered function of the blood-brain barrier. The accumulation of aluminum in the body may cause bone or brain diseases. High levels of aluminum have been linked to Alzheimer's disease. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740) |
| Expositionspfade | Oral (L739)inhalation (L739) |
| Toxizitätsübersicht | The main target organs of aluminum are the central nervous system and bone. Aluminum binds with dietary phosphorus and impairs gastrointestinal absorption of phosphorus. The decreased phosphate body burden results in osteomalacia (softening of the bones due to defective bone mineralization) and rickets. Aluminum's neurotoxicity is believed to involve several mechanisms. Changes in cytoskeletal protein functions as a results of altered phosphorylation, proteolysis, transport, and synthesis are believed to be one cause. Aluminum may induce neurobehavioral effects by affecting permeability of the blood-brain barrier, cholinergic activity, signal transduction pathways, lipid peroxidation, and impair neuronal glutamate nitric oxide-cyclic GMP pathway, as well as interfere with metabolism of essential trace elements because of similar coordination chemistries and consequent competitive interactions. It has been suggested that aluminum's interaction with estrogen receptors increases the expression of estrogen-related genes and thereby contributes to the progression of breast cancer (A235), but studies have not been able to establish a clear link between aluminum and increased risk of breast cancer (A15468). Certain aluminum salts induce immune responses by activating inflammasomes. (L739, A235, A236) |
| Signs and Symptoms | Inhalating aluminum dust causes coughing and abnormal chest X-rays. A small percentage of people are allergic to aluminium and experience contact dermatitis, digestive disorders, vomiting or other symptoms upon contact or ingestion of products containing aluminium. (L739, L740) |
| Carcinogen Classification | Not listed by IARC. IARC classified aluminum production as carcinogenic to humans (Group 1), but did not implicate aluminum itself as a human carcinogen. (L135) A link between use of aluminum-containing antiperspirants and increased risk of breast cancer has been proposed (A235), but studies have not been able to establish a clear link (A15468). |
| F | 3-10-23 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 1992 3/PG 3 |
| Zollcode | 29051900 |
| R-Sätze (R) | 40-21/22-10 |
| Toxizität | LD50 orally in Rabbit: 401 mg/kg LD50 dermal Rabbit 402 mg/kg |
| Gefahrensymbole | Xn,Xi |
| Sicherheitshinweise (S) | 36/37-45-43-36/37/39-26-16 |
| Gefahrenklasse | 3Acute Tox. 3 DermalAcute Tox. 4 OralFlam. Liq. 3 |
| Verpackungsgruppe | III |
| Lagerklasse | 3 - Flammable liquids |
| Selbstentzündungstemperatur | 763 °F |
Anwendungen & Verwendung
Verwenden
It is used for active catalyst and support, inorganic membrane, redrcing agent of aldehyde-ketone, oxidant of aldehyde-ketone, gel forming agent of printing ink and paint, dehydrant, water proofing agent and aluminum base grease.