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Molybdenum pentachloride

HCID 61497
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Grundinformationen

CAS
10241-05-1
Standard-SMILES
[Cl][Mo]([Cl])([Cl])([Cl])[Cl]
InChIKey
GICWIDZXWJGTCI-UHFFFAOYSA-I
Summenformel
Cl5Mo
Durchschnittliche Molmasse
273,2 g/mol
Monoisotopische Masse
272,7496716

Überblick

Molybdenum pentachloride is a green-black odorless solid. It is toxic by ingestion and an irritant to skin. It may react with water to produce corrosive hydrochloric acid and toxic fumes.

Namen und Bezeichner

Bevorzugter Name
Molybdenum pentachloride
IUPAC
pentachloromolybdenum

Namen und Synonyme

Molybdenum(V) chlorideMolybdenum pentachloride10241-05-1PentachloromolybdenumMoCl5BB0UFP2VO5CHEBI:30635RefChem:159384DTXCID1032721233-575-3DTXSID0065012MOLYBDENUM CHLORIDE (MoCl5)
Weitere Namen anzeigen
MFCD00003467EINECS 233-575-3UNII-BB0UFP2VO5UN2508pentachloridomolybdenum[MoCl5]SCHEMBL454117Molybdenum(V) chloride, 95%

Datenbank-Bezeichner

CAS
10241-05-1
PubChem CID
61497
DTXSID
DTXSID0065012
ChEBI
CHEBI:30635
EC Number
233-575-3

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
0
Schwere Atome
6
Formalladung
0
Komplexität
37,1

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Metals -> Metals, Inorganic Compounds

Corrosives

Density2.93 @25 °C
Boiling Point268 °C @760 [mm Hg]
Physical Description · 2 Einträge

Molybdenum pentachloride is a green-black odorless solid. It is toxic by ingestion and an irritant to skin. It may react with water to produce corrosive hydrochloric acid and toxic fumes.

Green-black solid; Dark-red as liquid or vapor; Hygroscopic; Reacts with water and air; [Hawley] Black crystalline solid with a pungent odor; Reacts with water; [MSDSonline]

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 71 reports by companies from 6 notifications to the ECHA C&L Inventory.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Molybdenum chloride (MoCl5)

Molybdenum (V) chloride: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelCorrosive
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

· Combustible material: may burn but does not ignite readily.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards Summary · 1 Eintrag

An irritant; [Hawley] May react with water evolving hydrochloric acid; A skin irritant; [CAMEO] Corrosive to skin and eyes; [eChemPortal: ERMA] A corrosive substance that can cause injury to the skin, eyes, and respiratory tract; Inhalation may cause chemical pneumonitis; [MSDSonline] See Molybdenum.

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used as a chlorination catalyst and intermediate; Also used in molybdenum coatings, fire-retardant resins, and brazing/soldering fluxes; [Hawley]

Brazing [Category: Heat or Machine]

General Manufacturing InformationMolybdenum chloride (MoCl5): ACTIVE

Anbieter100 Anbieter

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DOT ID and Guide2508 156
Reactive GroupHalogenating Agents
Reactivity AlertsWater-Reactive
Reactivity Profile · 1 Eintrag

MOLYBDENUM PENTACHLORIDE is a corrosive, hygroscopic solid, on contact with water or steam it decomposes to form hydrochloric acid. When heated to decomposition it emits toxic fumes of molybdenum chlorides and metallic molybdenum [Lewis, 3rd ed., 1993, p. 892]. Explodes on contact with finely divided sodium [Berry D. H., Chem. Eng. News, 1989, 67(47), p. 2]. Reaction with finely divided sodium sulfide is violent, may lead to autoignition [Kaner, R. B., Nature, 1991, 349, p. 510].

DOT Hazard Classification · 4 Einträge

Molybdenum pentachloride

UN2508

Class 8 Corrosive material (49 eCFR § 173.136)

PG III: the degree of danger presented by the material is minor

Air and Water ReactionsMolybdenum pentachloride may react with water to produce corrosive hydrochloric acid and toxic fumes.
Hazard Classes and Categories · 2 Einträge

Skin Corr. 1B (100%)

Corrosives, Reactive agents - 2nd degree

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 Einträge

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:

Immediate precautionary measure

Threshold Limit Values (TLV)0.5 [mg/m3], as Mo, respirable fraction
Permissible Exposure Limit (PEL)5.0 [mg/m3], as Mo
Protective Action Criteria (PAC) · 3 Einträge

1.8 [ppm]

22 [ppm]

100 [ppm]

Personal Protective Equipment (PPE)Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:
Emergency Response Planning Guidelines· Note: Most foams will react with the material and release corrosive/toxic gases.
Immediately Dangerous to Life or Health (IDLH) · 2 Einträge

1000 mg Mo/m3 (NIOSH, 2024)

1000.0 [mg/m3], as Mo

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.
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