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HCID 61756Erstellt: 27. Oktober 2026

Diethylperoxydicarbonat

Diethyl peroxydiformate · Diethyl peroxydicarbonate · Bis(ethoxyformyl) peroxide · Bis(ethoxycarbonyl) peroxide · Peroxybis(formic acid ethyl) ester · Peroxydicarbonic acid diethyl ester · diethyl peroxydicarbonate, <= 27% in solution · ethoxycarbonyloxy ethyl carbonate[in solution, content ≤27%]

https://huagongshe.com/de/chemical/61756

Molekülstruktur von Diethylperoxydicarbonat

Identifikatoren & physikalische Daten

CAS No.14666-78-5
SummenformelC6H10O6
Durchschnittliche Molmasse178,14 g/mol
Monoisotopische Masse178,04773804 g/mol
SMILESCCOC(=O)OOC(=O)OCC
InChIKeyCWINGZLCRSDKCL-UHFFFAOYSA-N
PubChem CID61756
EC No.238-707-3
DTXSIDDTXSID0075310
Lokaler NameDiethylperoxydicarbonat

Chemische & physikalische Eigenschaften

XLogP1,7
Polarare Oberfläche (TPSA)71,1
H-Brücken-Donoren0
H-Brücken-Akzeptoren6
Frei drehbare Bindungen7
Schwere Atome12
Formalladung0
Komplexität136
Physical DescriptionThis liquid peroxide is particularly sensitive to temperature rises and contamination. Above a given "Control Temperature" they decompose violently. It is generally stored or transported in a solvent slurry, water, alcohol, etc.
Siedepunkt230.35°C (rough estimate)
Dichte1.3253 (rough estimate)
Brechungsindex1.5860 (estimate)
EPA chemische InformationenPeroxydicarbonic acid, diethyl ester (14666-78-5)

Sicherheit & Vorschriften

GHS-EinstufungDangerH226 (100%): Flammable liquid and vapor [Warning Flammable liquids]P210, P233, P234, P235, P240, P241, P242, P243, P264, P264+P265, P280, P302+P352, P303+P361+P353, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403, P403+P235, P410, P411, P420, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 8 reports by companies from 1 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Regulatorische InformationenChemical: Peroxydicarbonic acid, diethyl esterStatus: Active Update: 27-05-2013 https://echa.europa.eu/registration-dossier/-/registered-dossier/13297
DOT-KennzeichnungOrganic Peroxide
BrandgefahrenExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
GesundheitsgefahrenExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Reaktive GruppePeroxides, Organic
Reactivity AlertsExplosive
Reactivity ProfileDIETHYL PEROXYDICARBONATE decomposes violently or explosively at temperatures 0-10 °C owing to self-accelerating exothermic decomposition. Several explosions were due to shock, heat or friction. Amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156]. Danger of explosion when dry.
DOT Hazard ClassificationDiethyl peroxydicarbonate, with more than 27 percent in solutionForbidden explosives/materials (49 eCFR § 173.54/§ 173.21)
Air and Water ReactionsNo rapid reaction with air. No rapid reaction with water.
Hazard Classes and CategoriesFlam. Liq. 3 (100%)
BrandbekämpfungExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Erste HilfeExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Freisetung ohne BrandExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Isolation and EvacuationExcerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
Personal Protective Equipment (PPE)Excerpt from ERG Guide 148 [Organic Peroxides (Heat and Contamination Sensitive / Temperature Controlled)]:
UN-Transportnummer3115
Gefahrenklasse5.2
VerpackungsgruppeII