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Kieselsure, Zirkon(4+)-salz

Silicic acid, zirconium(4+) salt

HCID 61775
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Grundinformationen

CAS
10101-52-7
Standard-SMILES
[O-][Si]([O-])([O-])[O-].[Zr+4]
InChIKey
GFQYVLUOOAAOGM-UHFFFAOYSA-N
Summenformel
O4SiZr
Durchschnittliche Molmasse
183,3 g/mol
Monoisotopische Masse
181,861284

Überblick

The Expert Panel for Cosmetic Ingredient Safety concluded that the following 24 silicate ingredients are safe in cosmetics in the present practices of use and concentration described in this safety assessment when formulated to be non-irritating, with the exception that the available data are insufficient to make a determination of safety for the use of naturally-sourced (i.e., mined) silicate ingredients in products that may be incidentally inhaled: Zirconium Silicate.

Namen und Bezeichner

Bevorzugter Name
Silicic acid, zirconium(4+) salt
IUPAC
zirconium(4+) silicate
Lokaler Name
Kieselsure, Zirkon(4+)-salz
Englischer Name
Silicic acid, zirconium(4+) salt
Summenformel
O6Si2Zr
Molmasse
243.3914

Namen und Synonyme

1344-21-4Silicic acid, zirconium(4+) saltRefChem:1098530DTXSID501032382215-690-0Zirconium silicate10101-52-7ZirconZircon (Zr(SiO4))Zirconite14940-68-2Zircosil
Weitere Namen anzeigen
Micro-Paxzirconium(4+);silicateZirconium orthosilicateZirconium(IV) silicate (1:1)Silicon zirconium oxide (SiZrO4)MFCD00085353Silicic acid (H4SiO4), zirconium(4+) salt (1:1)ZIRCONIUM SILICON OXIDE

Datenbank-Bezeichner

CAS
10101-52-7、1344-21-4、14940-68-2
PubChem CID
61775
DTXSID
DTXSID60892246
UNII
4SY8H89134
EC Number
215-690-0、233-252-7、239-019-6

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
92,2 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
0
Schwere Atome
6
Formalladung
0
Komplexität
19,1

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Metals -> Metals, Inorganic Compounds

Mineral Dusts -> Other Mineral Dusts

CosmeticsCosmetic ingredients (Zirconium Silicate) -> CIR (Cosmetic Ingredient Review)
Physical Description · 4 Einträge

Large Crystals; CBI; Dry Powder

Dry Powder; Other Solid

Colorless solid; [Merck Index] Grey powder; [MSDSonline]

Colorless to greyish-white to red to brown fine powder; Odorless; [Continental Mineral Processing MSDS]

Physikochemische Eigenschaften

Kosmetik-Inhaltsstoffe Funktionen
ABRASIVEOPACIFYING

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 75.9% (189 of 249) of all reports.

Warning

H315 (24.1%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 249 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

This chemical does not meet GHS hazard criteria for 97.8% (176 of 180) of all reports.

Gefahrenhinweise

Regulatory Information · 6 Einträge

Chemical: Silicic acid (H4SiO4), zirconium(4+) salt (1:1)

Chemical: Zircon (Zr(SiO4))

Zircon (Zr(SiO4)) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Zircon (Zr(SiO4)) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Silicic acid (H4SiO4), zirconium(4+) salt (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicic acid (H4SiO4), zirconium(4+) salt (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Silicic acid (H4SiO4), zirconium(4+) salt (1:1): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Zircon (Zr(SiO4)): Does not have an individual approval but may be used under an appropriate group standard

Other Safety Information · 2 Einträge

IMAP assessments - Silicic acid (H4SiO4), zirconium(4+) salt (1:1): Environment tier I assessment

Chemie und Industrie

Verwendung und Herstellung

Uses · 6 Einträge

CIR ingredient: Zirconium Silicate

Used in refractories, ceramics, glazes, cements, coatings for casting molds, polishing materials, gemstones, and cosmetics; Also used as a catalyst and silicone rubber stabilizer; [Merck Index] Occurs in nature as the mineral zircon; Used as a refractory, abrasive, and to make ceramic glazes and enamels; Also used in the steel and glass industries and in foundries to make molds; [Ullmann]

Steel Producing [Category: Industry]

Ceramics making [Category: Hobbies]

Naturally occurring zirconium silicate found in many different rocks and beach sand from South Carolina and Northeast Florida; [Merck Index] Used as a source of zirconium oxide, metallic zirconium, and hafnium, in abrasives, refractories, enamels, refractory porcelain, silicon rubbers, foundry cores, and as a catalyst; [Continental Mineral Processing MSDS]

Abrasive Blasting [Category: Clean]

U.S. Production · 2 Einträge

2023: 500,000,000 - <1,000,000,000 lb

2023: 75,000 - <500,000 lb

Consumer Uses · 2 Einträge

Corrosion inhibitor

Other

Industry Uses · 2 Einträge

Binder

Other

Household ProductsInformation on 1 consumer products that contain Zirconium silicate in the following categories is provided:
General Manufacturing Information · 4 Einträge

Primary Metal Manufacturing

Miscellaneous Manufacturing

Silicic acid (H4SiO4), zirconium(4+) salt (1:1): ACTIVE

Zircon (Zr(SiO4)): ACTIVE

Zugehörige Reaktionen

0
Reaktionsaufzeichnung erstellen

Keine Reaktionsaufzeichnungen unter den aktuellen Filterkriterien.

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IMAP assessments - Zircon (Zr(SiO4)): Human health tier I assessment

Hazards Summary · 2 Einträge

An irritant; Prolonged inhalation may cause pulmonary fibrosis known as silicosis. [MSDSonline] Silicosis is caused by inhalation of dust containing particles of crystalline silica in the respirable size range. Some non-crystalline forms of silica are relatively nontoxic. [APHA, p. 446] See Zirconium.

Contains small amounts of uranium and thorium; Causes moderate skin and eye irritation by abrasive action; [IUCLID] Contains 0.1-2% aluminum oxide and aluminum silicate and trace amounts of crystalline silica, titanium dioxide, uranium, and thorium; Abrasive action may cause skin and eye irritation; Non-toxic by ingestion; [Continental Mineral Processing MSDS] See Zirconium silicate. See Zirconium.

Hazard Classes and Categories · 2 Einträge

Not Classified

Skin Irrit. 2 (24.1%)

Sicherheit und Schutzausrüstung

Exposure Control and Personal Protection · 2 Einträge

1.0 [mg/m3], inhalable fraction (metal and insol. cmpds.)[German Research Foundation (DFG)]

1.0 [mg/m3], inhalable fraction (metal and insol. cmpds.)[German Research Foundation (DFG)]

Threshold Limit Values (TLV) · 4 Einträge

5.0 [mg/m3], as Zr

10.0 [mg/m3], as Zr

5.0 [mg/m3], as Zr

10.0 [mg/m3], as Zr

Permissible Exposure Limit (PEL) · 2 Einträge

5.0 [mg/m3], as Zr (compounds)

5.0 [mg/m3], as Zr (compounds)

Protective Action Criteria (PAC) · 3 Einträge

20 [mg/m3]

170 [mg/m3]

1000 [mg/m3]

Immediately Dangerous to Life or Health (IDLH) · 2 Einträge

25.0 [mg/m3], as Zr

25.0 [mg/m3], as Zr

Toxikologische Informationen

Toxicity Summary · 2 Einträge

The Expert Panel for Cosmetic Ingredient Safety concluded that the following 24 silicate ingredients are safe in cosmetics in the present practices of use and concentration described in this safety assessment when formulated to be non-irritating, with the exception that the available data are insufficient to make a determination of safety for the use of naturally-sourced (i.e., mined) silicate ingredients in products that may be incidentally inhaled: Zirconium Silicate.

Safe for use in cosmetics, with qualifications