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Rutheniumtrichlorid
RUCl3 · RUTHENIUM TRICHLORIDE · RUTHENIUM CHLORIDE · RUTHENIUM(III) CHLORIDE ANHYDROUS · Ruthenic chloride · Ruthenium(III) chL · Ruthenium(III) chlor · Ruthenium triehloride
Identifikatoren & physikalische Daten
| CAS No. | 10049-08-8 |
|---|---|
| Summenformel | Cl3Ru |
| Durchschnittliche Molmasse | 207,4 g/mol |
| Monoisotopische Masse | 206,81090734 g/mol |
| SMILES | [Cl][Ru]([Cl])[Cl] |
| InChIKey | YBCAZPLXEGKKFM-UHFFFAOYSA-K |
| PubChem CID | 61850 |
| EC No. | 233-167-5 |
| DTXSID | DTXSID101014308 |
| Lokaler Name | Rutheniumtrichlorid |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 4 |
| Formalladung | 0 |
| Komplexität | 8 |
| Stoffklassen | Metals -> Metals, Inorganic Compounds |
| SpringerMaterials Properties | crystal structure |
| Dichte | 3.11 @25 °C3.11 g/mL at 25 °C (lit.) |
| Physical Description | alpha form: Black lustrous solidbeta form: Dark brown solid[Merck Index] Black hygroscopic crystals with a pungent odor[Alfa Aesar MSDS] |
| Schmelzpunkt | 500 °C |
| Lagerbedingungen | Keep in dark place,Inert atmosphere,Room temperature |
| Löslichkeit | insoluble in H2Oslightly soluble in ethanol |
| Aggregatzustand | Powder or Crystals |
| Farbe | Black |
| pH | 1-2 |
| Merck | 14,8302 |
| Stabilität | Stable. Incompatible with zinc. Protect from moisture. |
| Hauptanwendungen | PEM fuel cellshomogeneous catalystmaterial synthesis precursor |
| InChI | InChI=1S/3ClH.Ru/h3*1H/q+3/p-3 |
| InChIKey | YBCAZPLXEGKKFM-UHFFFAOYSA-K |
| SMILES | [Ru](Cl)(Cl)Cl |
| CAS Datenbank | 10049-08-8(CAS DataBase Reference) |
| EPA chemische Informationen | Ruthenium chloride (RuCl3) (10049-08-8) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH290 (18.5%): May be corrosive to metals [Warning Corrosive to Metals]P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P391, P405, P406, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 205 reports by companies from 18 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Ruthenium chloride (RuCl3)Ruthenium chloride (RuCl3): Does not have an individual approval but may be used under an appropriate group standardRuthenium (III) chloride: Does not have an individual approval but may be used under an appropriate group standard |
| Weitere Sicherheitsinformationen | IMAP assessments - Ruthenium chloride (RuCl3): Human health tier I assessment |
| Gefahrenübersicht | Intraperitoneal LD50 (rat) = 360 mg/kg[RTECS] Causes burnsInhalation may cause corrosive injuries to upper respiratory tract and lungs[Alfa Aesar MSDS] |
| Hazard Classes and Categories | Met. Corr. 1 (18.5%) |
| Protective Action Criteria (PAC) | 2.2 [mg/m3]24 [mg/m3]140 [mg/m3] |
| Unerwünschte Wirkungen | Dermatotoxin - Skin burns. |
| Wassergefährdungsklasse (WGK) | 2 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 3260 8/PG 2 |
| Zollcode | 28439000 |
| RTECS-Nr. | VM2650000 |
| R-Sätze (R) | 34-52/53-22 |
| Gefahrensymbole | C |
| Sicherheitshinweise (S) | 26-36/37/39-45-61 |
| Gefahrenklasse | 8Acute Tox. 4 OralAquatic Chronic 2Eye Dam. 1Skin Corr. 1B |
| Verpackungsgruppe | III |
| Lagerklasse | 8A - Combustible corrosive hazardous materials |
Anwendungen & Verwendung
Verwenden
Ruthenium(III) chloride is widely used as a starting material of ruthenium complexes. It acts as a catalyst used in the oxidative cyclization of 1,7-dienes to oxepane diols. It is used in the hydroxylation of tertiary hydrocarbons in combination of periodate or bromate. It is involved as a catalyst in the synthesis of 2,3-pyridinedicarboxylic acid-13C3, 15N, where the unlabelled analog is an inhibitor of glucose synthesis.