Dikaliumhexachloroplatinat

POTASSIUM HEXACHLOROPLATINATE · POTASSIUM HEXACHLOROPLATINATE(IV) · POTASSIUM CHLOROPLATINATE (IV) · atinate · Potassium hexachL · HexachloroplatinuM · Potassium chloroplat · Potassium chloroplatite

https://huagongshe.com/de/chemical/61856

Molekülstruktur von Dikaliumhexachloroplatinat

Identifikatoren & physikalische Daten

CAS No.	16921-30-5
Summenformel	Cl6Pt.2K
Durchschnittliche Molmasse	486 g/mol
Monoisotopische Masse	482,70532054 g/mol
SMILES	[Cl][Pt-2]([Cl])([Cl])([Cl])([Cl])[Cl].[K+].[K+]
InChIKey	DPAIVKJGTXERIM-UHFFFAOYSA-H
PubChem CID	61856
EC No.	240-979-3
DTXSID	DTXSID90926861
Lokaler Name	Dikaliumhexachloroplatinat

Chemische & physikalische Eigenschaften

Polarare Oberfläche (TPSA)	0
H-Brücken-Donoren	0
H-Brücken-Akzeptoren	1
Frei drehbare Bindungen	0
Schwere Atome	9
Formalladung	0
Komplexität	62,7
Stoffklassen	Metals -> Metals, Inorganic Compounds
Physical Description	Orange-yellow or yellow solidSlightly soluble in cold waterSoluble in hot water[Merck Index] Yellow powder[Sigma-Aldrich MSDS]
Schmelzpunkt	250 °C (dec.)(lit.)
Dichte	3.499
Dampfdruck	0Pa at 20℃
Brechungsindex	^=1.825
Lagerbedingungen	Inert atmosphere,Room Temperature
Löslichkeit	50g/l50 g/L (95 ºC)
Aggregatzustand	Powder/Solid
Wichte	3.5
Farbe	Yellow-Orange
Merck	14,7636
Stabilität	Stable. Incompatible with acids, interhalogen compounds, strong oxidizing agents.
InChI	1S/6ClH.2K.Pt/h61H/q2+1+4/p-6
InChIKey	DPAIVKJGTXERIM-UHFFFAOYSA-H
SMILES	[K+].[K+].Cl[Pt--](Cl)(Cl)(Cl)(Cl)Cl
CAS Datenbank	16921-30-5(CAS DataBase Reference)
EPA chemische Informationen	Platinate(2-), hexachloro-, dipotassium, (OC-6-11)- (16921-30-5)

Sicherheit & Vorschriften

GHS-Einstufung	DangerH301: Toxic if swallowed [Danger Acute toxicity, oral]P233, P260, P261, P264, P264+P265, P270, P271, P272, P280, P284, P301+P316, P302+P352, P304+P340, P305+P354+P338, P317, P321, P330, P333+P317, P342+P316, P362+P364, P403, P405, and P501 (click each P-code to see the statement)This chemical does not meet GHS hazard criteria for 0.5% (1 of 190) of reports.H290 (71.1%): May be corrosive to metals [Warning Corrosive to Metals]
Regulatorische Informationen	Chemical: Platinate(2-), hexachloro-, dipotassium, (OC-6-11)-Hazard Traits - Respiratory ToxicityStatus: Active Update: 23-06-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/21529Potassium hexachloroplatinate (IV): Does not have an individual approval but may be used under an appropriate group standard
Weitere Sicherheitsinformationen	IMAP assessments - Platinate(2-), hexachloro-, dipotassium, (OC-6-11)-: Environment tier I assessment
Gefahrenübersicht	Toxic and corrosive[Merck Index] Chloroplatinates are skin and respiratory sensitizers[MAK] All salts of sodium, potassium, and ammonium are soluble, except sodium antimonite, potassium hexachlorplatinate, and potassium cobalinitrite. [Nordberg, p. 19] Causes burnsInhalation may cause corrosive injuries to upper respiratory tract and lungsMay cause skin and respiratory sensitizationToxic by ingestion[Sigma-Aldrich MSDS]
Hazard Classes and Categories	Met. Corr. 1 (71.1%)Acute toxicity - category 3Acute Tox. 3 *
Threshold Limit Values (TLV)	0.002 [mg/m3], as Pt (soluble salts)
Permissible Exposure Limit (PEL)	0.002 [mg/m3], as Pt (soluble salts)
Immediately Dangerous to Life or Health (IDLH)	4.0 [mg/m3], as Pt (soluble salts)

Anwendungen & Verwendung

Verwenden

Potassium chloroplatinate is a red colored crystal that is soluble in water but less soluble in alcohol. Potassium chloroplatinate is produced by a complicated treatment of the reducing of platinum chloride with sulfurous gas and adding potassium chloride. It was used primarily in the platinum printing process, but also for toning silver prints.

Herstellung & Synthese

synthetische

It is formed by reaction of soluble potassium salt solution and chloroplatinic acid.