Grundinformationen
- Standard-SMILES
F[Si-2](F)(F)(F)(F)F.[Mg+2]- InChIKey
INWUJAAIUAAHJA-UHFFFAOYSA-N- Summenformel
- F6Si.Mg
- Durchschnittliche Molmasse
- 166,38 g/mol
- Monoisotopische Masse
- 165,95238755
Überblick
Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.
Namen und Bezeichner
- Bevorzugter Name
- Magnesium hexafluorosilicate
- IUPAC
- magnesium hexafluorosilicon(2-)
- Lokaler Name
- Magnesiumhexafluorosilicat
- Englischer Name
- Magnesium fluosilicate
- Summenformel
- F6MgSi
- Molmasse
- 166.38
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
16949-65-8、18972-56-0- PubChem CID
- 61861
- DTXSID
DTXSID70884950- UNII
- H37V80D2JS
- EC Number
- 241-022-2、606-187-0
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 7
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 8
- Formalladung
- 0
- Komplexität
- 62,7
Experimentelle und physikochemische Eigenschaften
Physical Description
Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.
Dry Powder
Solid; [CAMEO] White powder; [Gelest MSDS]
Physikochemische Eigenschaften
- Schmelzpunkt
- 120 °C · 120°C
- Siedepunkt
- 120 °C · >120°C
- Dichte
- 1.788 · 1.788
- Dampfdruck
- 0.001 Pa · 0.001Pa at 25℃
- Aggregatzustand
- Powder
- Wichte
- 1.788 · 1.788
- Wasserlöslichkeit
- 498.4 g/L · 498.4g/L at 18.3℃
- Kosmetik-Inhaltsstoffe Funktionen
- ANTIPLAQUEORAL CARE
- InChI
- InChI=1S/F6Si.Mg.6H2O/c1-7(2,3,4,5)6;;;;;;;/h;;6*1H2/q-2;+2;;;;;;
- InChIKey
- ZYDDCPHMRLLEEV-UHFFFAOYSA-N
- SMILES
- [Si-2](F)(F)(F)(F)(F)F.O.O.O.O.O.O.[Mg+2]
- LogP
- 0 at · 0 at 25℃
- CAS Datenbank
- 16949 · 16949-65-8(CAS DataBase Reference)
- EPA chemische Informationen
- Magnesium fluosilicate (16949-65-8)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H301: Toxic if swallowed [Danger Acute toxicity, oral]
P264, P270, P301+P316, P321, P330, P405, and P501 (click each P-code to see the statement)
Danger
H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]
P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P354+P338, P317, P321, P330, P405, and P501 (click each P-code to see the statement)
Gefahrenhinweise
Regulatory Information
Chemical: Silicate(2-), hexafluoro-, magnesium (1:1)
Silicate(2-), hexafluoro-, magnesium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicate(2-), hexafluoro-, magnesium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Magnesium hexafluorosilicate (EC: 241-022-2)
Magnesium hexafluorosilicate: Does not have an individual approval but may be used under an appropriate group standard
Magnesium fluorosilicate: Does not have an individual approval but may be used under an appropriate group standard
Fire Hazards
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Health Hazards
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
Hazards Summary
Toxic by ingestion; May cause serious eye injury [Classifications by the EC] Not a skin irritant in rabbits (80% aqueous solution); Hematological and clinical chemistry changes, adverse dental effects, mineralization in bone tissue, interstitial nephritis, hyperkeratosis of the stomach, increased relative liver and kidney weights, and increased relative testes and adrenal weights in males observed in 4-week oral study of rats at 3,000 ppm dietary (approximately 300 mg/kg/day); [IUCLID] An eye irritant; Corrosive to mucous membranes; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause osteofluorosis; [Gelest MSDS] See Magnesium. See Fluorosilicic acid. See Calcium hexafluorosilicate.
Reactivity Profile
MAGNESIUM FLUOROSILICATE gives basic aqueous solutions. Reacts with acids. Does not usually react as either oxidizing agents or reducing agents. It can react slowly with water to generate hydrofluoric acid, which can cause severe chemical burns and is one of the few materials that can etch glass.
DOT Hazard Classification
Magnesium fluorosilicate
UN2853
Div 6.1 Poisonous materials (49 eCFR § 173.132)
PG III: the degree of danger presented by the material is minor
Hazard Classes and Categories
Acute Tox. 3 (100%)
Acute toxicity (ingestion) - category 3
Acute toxicity (Oral) - Category 3
Acute toxicity (Oral) - Category 3
Acute Tox. 3 *
Sicherheit und Schutzausrüstung
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
First Aid
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
General First Aid:
Exposure Control and Personal Protection
· Wear positive pressure self-contained breathing apparatus (SCBA).
Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)
1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]
Isolation and Evacuation
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Immediate precautionary measure
Toxikologische Informationen
Sicherheitsdaten
- tsca
- TSCA listed
- ridadr
- UN 2853
- risk_code
- 25
- Toxizität
- LD in guinea pigs (mg/kg): 200 orally, 400 s.c. (Waldbott)
- hazard_code
- T
- safety_code
- 24/25-45
- hazard_class
- 6.1
- packing_group
- III
Chemie und Industrie
Verwendung und Herstellung
Uses
Used for mothproofing textiles; [Merck Index] Used to make other chemicals; [CAMEO]
Textiles (Printing, Dyeing, or Finishing) [Category: Industry]
General Manufacturing Information
Non-metallic Mineral Product Manufacturing (includes clay, glass, cement, concrete, lime, gypsum, and other non-metallic mineral product manufacturing)
Silicate(2-), hexafluoro-, magnesium (1:1): ACTIVE
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