Ammoniumglycyrrhizinat
MONOAMMONIUM GLYCYRRHIZINATE · Magnasweet · Monoammonium Glycyrrhizinate S · glycyrram · monoammoniumglycyrrhizate · glycyrrhizin monoammonium salt · GLYCYRRHIZINATE MONOAMMONIUM SALT · GLYCYRRHIZIC ACID MONOAMMONIUM SALT
Identifikatoren & physikalische Daten
| CAS No. | 53956-04-0 |
|---|---|
| Summenformel | C42H62O16.H3N |
| Durchschnittliche Molmasse | 840 g/mol |
| Monoisotopische Masse | 839,43033499 g/mol |
| SMILES | CC1(C)[C@@H](O[C@H]2O[C@H](C(=O)O)[C@@H](O)[C@H](O)[C@H]2O[C@@H]2O[C@H](C(=O)O)[C@@H](O)[C@H](O)[C@H]2O)CC[C@]2(C)[C@H]3C(=O)C=C4[C@@H]5C[C@@](C)(C(=O)O)CC[C@]5(C)CC[C@@]4(C)[C@]3(C)CC[C@@H]12.N |
| InChIKey | ILRKKHJEINIICQ-OOFFSTKBSA-N |
| PubChem CID | 62074 |
| ChEBI | CHEBI:81864 |
| EC No. | 258-887-7 |
| Lokaler Name | Ammoniumglycyrrhizinat |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 268 |
|---|---|
| H-Brücken-Donoren | 9 |
| H-Brücken-Akzeptoren | 17 |
| Frei drehbare Bindungen | 7 |
| Schwere Atome | 59 |
| Formalladung | 0 |
| Komplexität | 1.730 |
| Kosmetika | Cosmetic ingredients (Ammonium Glycyrrhizate) -> CIR (Cosmetic Ingredient Review)Skin conditioning |
| Duftstoffe | Fragrance Ingredient (Glycyrrhizin, ammoniated (Glycyrrhiza spp.)) -> IFRA transparency List |
| Lebensmittelzusatzstoffe | FLAVORING AGENT OR ADJUVANT -> FDA Substance added to food |
| Aromastoffe | EU Flavoring substances |
| Animal Drugs | Pharmaceuticals -> UK Veterinary Medicines Directorate List |
| Collision Cross Section | 284.9 Ų [M+H]+ [CCS Type: TWMethod: calibrated with polyalanine and drug standards] |
| Schmelzpunkt | >200°C (dec.) |
| Siedepunkt | 768.56°C (rough estimate) |
| Dichte | 1.1846 (rough estimate) |
| FEMA | 2528 | GLYCYRRHIZIN, AMMONIATED (GLYCYRRHIZA SPP.) |
| Brechungsindex | 49 ° (C=1.5, EtOH) |
| Lagerbedingungen | 2-8°C |
| Löslichkeit | Slightly soluble in water, very slightly soluble in anhydrous ethanol, practically insoluble in acetone. It dissolves in dilute solutions of acids and of alkali hydroxides. |
| Aggregatzustand | Powder or Crystals |
| Farbe | Yellow to yellow-green |
| Geruch | bland |
| BRN | 3897076 |
| Stabilität | Hygroscopic |
| Kosmetik-Inhaltsstoffe Funktionen | SKIN CONDITIONING - MISCELLANEOUSFLAVOURINGFRAGRANCE |
| InChIKey | ILRKKHJEINIICQ-YDYGGSECSA-N |
| LogP (Verteilungskoeffizient) | -0.9 |
| CAS Datenbank | 53956-04-0 |
| EPA chemische Informationen | .alpha.-D-Glucopyranosiduronic acid, (3.beta.,20.beta.)-20-carboxy-11-oxo-30-norolean-12-en-3-yl 2-O-.beta.-D-glucopyranuronosyl-, monoammonium salt (53956-04-0) |
Sicherheit & Vorschriften
| GHS-Einstufung | This chemical does not meet GHS hazard criteria for 36.4% (98 of 269) of reports.WarningH319 (62.8%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]P264+P265, P280, P305+P351+P338, and P337+P317 (click each P-code to see the statement)Aggregated GHS information provided per 269 reports by companies from 4 notifications to the ECHA C&L Inventory. |
|---|---|
| Regulatorische Informationen | Chemical: .alpha.-D-Glucopyranosiduronic acid, (3.beta.,20.beta.)-20-carboxy-11-oxo-30-norolean-12-en-3-yl 2-O-.beta.-D-glucopyranuronosyl-, monoammonium saltRegulation (EC) No 1831/2003 (amended)REACH registered substance: Ammonium glycyrrhizate (EC: 258-887-7).alpha.-D-Glucopyranosiduronic acid, (3.beta.,20.beta.)-20-carboxy-11-oxo-30-norolean-12-en-3-yl 2-O-.beta.-D-glucopyranuronosyl-, monoammonium salt: Does not have an individual approval but may be used under an appropriate group standard |
| Hazard Classes and Categories | Eye Irrit. 2 (62.8%) |
| Toxizitätsübersicht | Safe in the present practices of use and concentration. Ingredient, concentration, and use information are available in documents discoverable at https://cir-reports.cir-safety.org |
| F | 3-10 |
| Wassergefährdungsklasse (WGK) | 2 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 3077 9 / PGIII |
| Zollcode | 29389090 |
| RTECS-Nr. | LZ6500000 |
| Lagerklasse | 11 - Combustible Solids |
| Gefahrenklasse | Eye Irrit. 2 |
Anwendungen & Verwendung
Beschreibung
§ 184.1408(a)(1) Licorice (glycyrrhiza) root is the dried and ground rhizome and root portions of Glycyrrhiza glabra or other species of glycyrrhiza. Licorice extract is that portion of the licorice root that is, after maceration, extracted by boiling water. The extract can be further purified by filtration and by treatment with acids and ethyl alcohol. Licorice extract is sold as a liquid paste ("block"), or spraydried powder. (2) Ammoniated glycyrrhizin is prepared from the water extract of licorice root by acid precipitation followed by neutralization with dilute ammonia. Monoammonium glycyrrhizinate (C42H61016NH45H2O ) is prepared from ammoniated glycyrrhizin by solvent extraction and separation techniques.
Verwenden
Glycyrrhizic acid ammonium salt is a flavoring and sweetening agent obtained from licorice flavonoids. It has a slight licorice flavor and an intense and rounded sweetness. It is soluble in water, glycerin, and propylene glycol and has good thermal stability but can degrade under prolonged heating. It is stable over a ph of 3.5–9 but could precipitate below ph of 3.5. It can be used in beverages, desserts, confectionary products, soups, and dressings.