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Bariumoxid, bei der Kalzinierung von Witherit gewonnen

Barium oxide

HCID 62392
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Grundinformationen

CAS
1304-28-5
Standard-SMILES
[O]=[Ba]
InChIKey
QVQLCTNNEUAWMS-UHFFFAOYSA-N
Summenformel
BaO
Durchschnittliche Molmasse
153,33 g/mol
Monoisotopische Masse
153,90016182

Überblick

Barium oxide appears as a white to yellow powder. May be toxic by ingestion. Irritates skin, eyes and mucous membranes. Used as a drying agent for gasoline and solvents.

Namen und Bezeichner

Bevorzugter Name
Barium oxide
IUPAC
oxobarium
Lokaler Name
Bariumoxid, bei der Kalzinierung von Witherit gewonnen
Englischer Name
Barium oxide
Summenformel
BaO
Molmasse
153.33

Namen und Synonyme

BARIUM OXIDE1304-28-5oxobariumBarytaBarium monoxideCalcined barytaBarium protoxideBarium oxide (BaO)Oxyde de baryumDTXSID2089323477603K202BRefChem:116544
Weitere Namen anzeigen
BARIUM (II) OXIDEBarsitooxydedebaryumcalcinedbarytabariumprotoxide
DTXCID501323167215-127-9Barium oxide, obtained by calcining witheriteMFCD00003453Oxyde de baryum [French]EINECS 215-127-9UN1884Baria

Datenbank-Bezeichner

CAS
1304-28-5
PubChem CID
62392
DTXSID
DTXSID20893234
EC Number
215-127-9
Nikkaji
J43.682H

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
17,1 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
0
Schwere Atome
2
Formalladung
0
Komplexität
2

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Metals -> Metals, Inorganic Compounds

Reactive agents - 2nd degree

SpringerMaterials Propertiesphonon wavenumber
Density · 2 Einträge

5.7 g/cm³

5.72 @25 °C

SolubilitySolubility in water, g/100ml at 20 °C: 3.8
Boiling Point~2000 °C
Melting Point · 2 Einträge

1923 °C

1973 °C

Physical Description · 4 Einträge

Barium oxide appears as a white to yellow powder. May be toxic by ingestion. Irritates skin, eyes and mucous membranes. Used as a drying agent for gasoline and solvents.

Large Crystals; CBI; Other Solid

White to yellowish-white solid; Soluble in water; [Merck Index] Beige powder; [Aldrich MSDS]

YELLOWISH-WHITE SOLID IN VARIOUS FORMS.

Physikochemische Eigenschaften

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

This chemical does not meet GHS hazard criteria for 1.4% (5 of 359) of reports.

Danger

H271 (36.8%): May cause fire or explosion; strong Oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P260, P261, P264, P264+P265, P270, P271, P280, P283, P301+P316, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P306+P360, P316, P317, P321, P330, P332+P317, P337+P317, P362+P364, P363, P370+P378, P371+P380+P375, P405, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 359 reports by companies from 18 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

Gefahrenhinweise

Regulatory Information · 5 Einträge

Chemical: Barium oxide (BaO)

Barium oxide (BaO) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Barium oxide (BaO) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 06-04-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/13409

Barium oxide, anhydrous: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelPoison
Fire Hazards · 3 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Chemie und Industrie

Pharmakologische Informationen

Metabolism/Metabolites · 1 Eintrag

Barium compounds are absorbed via ingestion and inhalation, the extent of which depends on the individual compound. In the body, the majority of the barium is found in the bone, while small amounts exists in the muscle, adipose, skin, and connective tissue. Barium is not metabolized in the body, but it may be transported or incorporated into complexes or tissues. Barium is excreted in the urine and faeces. (L214)

Verwendung und Herstellung

Uses · 3 Einträge

Used to dry gases and solvents and to make lubricating oil detergents and barium methoxide; [Merck Index] Used as a drying agent for gasoline and solvents; [CAMEO]

Petroleum Production and Refining [Category: Industry]

Barium oxide is used as a coating for hot cathodes, in cathode ray tubes, and in the production of certain kinds of glass, such as optical crown glass. (L208)

U.S. Production2023: 1,000,000 - <5,000,000 lb
Consumer UsesOther
Industry UsesOther
General Manufacturing Information · 2 Einträge

All Other Basic Inorganic Chemical Manufacturing

Barium oxide (BaO): ACTIVE

Anwendungen · 1 Eintrag

VerwendenBarium oxide is used as a coating for “hot cathodes” in a variety of electronic devices such as TV’s and lamps. It replaced lead oxide in the production of certain kinds of glass. While lead oxide raised the refractive index of the glass, it also raised the dispersion, i.e refraction of various colors of light resulting in distortion of images which barium oxide does not alter. Barium oxide also has use as an ethoxylation catalyst in the reaction of ethylene oxide and alcohols which takes place between 150 and 200°C. The thermionic emission from thin evaporated films of barium oxide has been studied extensively. Thin barium oxide films have a good emission following evaporation. The emission improves a little during heat treatment, and is then similar to that from a sprayed cathode coating of barium oxide.

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Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
Schmelzpunkt
1920 °C · 1920 °C
Siedepunkt
2000 °C · 2000 °C
Dichte
5.72 g/mL · 5.72 g/mL at 25 °C(lit.)
Brechungsindex
1.98 · 1.98
Löslichkeit
soluble in dilute acid solutions, ethanol; insoluble in acetone
Aggregatzustand
Powder
Wichte
5.72 · 5.72
Farbe
Light yellow-greenish to grayish
Wasserlöslichkeit
Sparingly soluble in water. Soluble in ethanol, dilute mineral acids and alkali.
Spezifische Wärmekapazität
0.31 J/ · Cp(crystal): 0.31 J/(g·K), at 25℃
Merck
14 · 14,986
Stabilität
Stable. Incompatible with strong acids, water. Protect from moisture.
InChI
1S/Ba.O
InChIKey
QVQLCTNNEUAWMS-UHFFFAOYSA-N
SMILES
O=[Ba]
CAS Datenbank
1304 · 1304-28-5(CAS DataBase Reference)
EPA chemische Informationen
Barium oxide (1304-28-5)

Not combustible.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards Summary · 1 Eintrag

Highly alkaline; Absorbs moisture and carbon dioxide from air; Produces barium hydroxide and much heat on contact with water; [Merck Index] Reacts violently with water posing fire and explosion hazard; A skin, eye, and respiratory tract irritant; Short-term exposure may affect the nervous system and cause hypokalemia (leading to cardiovascular and muscular disorders); [ICSC] Reacts with water evolving energy and forming barium hydroxide (corrosive); A skin, eye, and respiratory tract irritant; [CAMEO] Causes somnolence and tetany in intraperitoneal lethal-dose studies of mice; [RTECS] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; Toxic by ingestion; Targets heart, nerves, kidney, GI tract, bone marrow, spleen, and liver; [Aldrich MSDS] See Barium.

DOT ID and Guide1884 157
Reactive GroupBases, Strong
EC ClassificationSymbol: Xn; R: 20/22; S: (2)-28; Note: A
UN ClassificationUN Hazard Class: 6.1; UN Pack Group: III
Reactivity AlertsWater-Reactive
Reactivity Profile · 1 Eintrag

BARIUM OXIDE reacts as a strong base. Combines exothermically with all categories of acids. Reacts with carbon dioxide to form barium carbonate [Merck 11th ed. 1989]. Ignites hydroxylamine on contact [Mellor 8:291 1946-47]. Mixtures with mercurous or nickel oxide react vigorously with hydrogen sulfide in air. Explosions may result [Mellor 10:140 1946-47]. Can react, particularly in the presence of moisture, with aluminum and zinc)to form oxides or hydroxides of the metal and generate gaseous hydrogen. May initiate polymerization reactions in polymerizable organic compounds, especially epoxides. May generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, peroxides, and hydroperoxides.

Chemical DangersThe solution in water is a medium strong base. Reacts violently with water, dinitrogen tetraoxide, hydroxylamine, sulfur trioxide and hydrogen sulfide. This generates fire and explosion hazard.

Sicherheit und Schutzausrüstung

Fire Fighting · 2 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

In case of fire in the surroundings, use appropriate extinguishing media.

First Aid Measures · 4 Einträge

Fresh air, rest. Refer for medical attention.

Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Induce vomiting (ONLY IN CONSCIOUS PERSONS!). Give one or two glasses of water to drink. Refer for medical attention .

Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

General First Aid:

Safe StorageSeparated from food and feedstuffs. Dry. Well closed.
Exposure Control and Personal Protection · 2 Einträge

· Wear positive pressure self-contained breathing apparatus (SCBA).

0.5 [mg/m3], as Ba, inhalable fraction(soluble compds)[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Spillage Disposal · 1 Eintrag

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into covered containers. Carefully collect remainder. Then store and dispose of according to local regulations.

Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

Immediate precautionary measure

Eye PreventionWear safety spectacles or eye protection in combination with breathing protection if powder.
Inhalation RiskEvaporation at 20 °C is negligible; a harmful concentration of airborne particles can, however, be reached quickly when dispersed.
Skin PreventionProtective gloves.

Toxikologische Informationen

TreatmentIntravenous infusion of potassium often relieves many of the symptoms of barium toxicity. (L214)
Health Effects · 1 Eintrag

The health effects of the different barium compounds depend on how well the compound dissolves in water or the stomach contents. At low doses, barium acts as a muscle stimulant, while higher doses affect the nervous system, causing cardiac irregularities, tremors, weakness, anxiety, dyspnea, paralysisand possibly death. Barium may also cause gastrointestinal disturbances, damage the kidneys and cause decreases in body weight. (L214)

Adverse EffectsNephrotoxin - The chemical is potentially toxic to the kidneys in the occupational setting.
Exposure Routes · 2 Einträge

The substance can be absorbed into the body by inhalation of its aerosol and by ingestion.

Oral (L214) ; inhalation (L214)

Toxicity Summary · 1 Eintrag

Barium is a competitive potassium channel antagonist that blocks the passive efflux of intracellular potassium, resulting in a shift of potassium from extracellular to intracellular compartments. The intracellular translocation of potassium results in a decreased resting membrane potential, making the muscle fibers electrically unexcitable and causing paralysis. Some of these barium's effects may also be due to barium induced neuromuscular blockade and membrane depolarization. (L214)

Signs and Symptoms · 5 Einträge

Cough. Sore throat.

Redness. Pain.

Redness. Pain.

Abdominal pain. Diarrhoea. Nausea. Vomiting. Muscle paralysis. Irregular heartbeat. Elevated blood pressure.

Ingesting excess barium may cause vomiting, abdominal cramps, diarrhea, difficulties in breathing, increased or decreased blood pressure, numbness around the face, and muscle weakness. High levels may result in changes in heart rhythm or paralysis and possibly death. (L214)

ICSC Environmental DataThe substance is harmful to aquatic organisms.
Carcinogen ClassificationNo indication of carcinogenicity to humans (not listed by IARC).
Toxicity DataLD50: 50 mg/kg (Oral, Rat) (L274)

Sicherheitsdaten

F
3-9-34
wgk
1
tsca
TSCA listed
ridadr
UN 1884
hs_code
28164000
RTECS-Nr.
CQ9800000
risk_code
20-25-34
Toxizität
mouse,LD50,intraperitoneal,146mg/kg (146mg/kg),Current Toxicology. Vol. 1, Pg. 39, 1993.
hazard_code
T
safety_code
26-36/37/39-45
hazard_class
6.1
packing_group
III
Speicherklasse
6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects
Hazard Classifications
Acute Tox. 3 OralAcute Tox. 4 InhalationEye Dam. 1Skin Corr. 1B

Darstellung

synthetischeBarium oxide is made by heating barium carbonate with coke, carbon black or tar: BaCO3 + C→ BaO + 2CO It may be also prepared by thermal decomposition of barium nitrate.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

BariumcarbonatHigh purity lanthanum nitrateKoks (Kohle)

Nachgelagerte Produkte

myo-InositBariumbis[2-chlor-5-[(2-hydroxy-1-naphthyl)azo]toluol-4-sulfonat]Bariumpotassium ω-hydroperfluroheptylateN10-(Trifluoroacetyl)pteroic acidBariumsulfat

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Ergänzende Hinweise · 1 Eintrag

Definitionbarium oxide: A white or yellowishsolid, BaO, obtained by heating bariumin oxygen or by the thermal decompositionof barium carbonate ornitrate; cubic; r.d. 5.72; m.p. 1923°C;b.p. 2000°C. When barium oxide isheated in oxygen the peroxide, BaO2,is formed in a reversible reactionthat was once used as a method forobtaining oxygen (the Brin process).Barium oxide is now used in themanufacture of lubricating-oil additives.