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Rubidium hydroxide

HCID 62393
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Grundinformationen

CAS
1310-82-3
Standard-SMILES
[OH-].[Rb+]
InChIKey
CPRMKOQKXYSDML-UHFFFAOYSA-M
Summenformel
HORb
Durchschnittliche Molmasse
102,475 g/mol
Monoisotopische Masse
101,91452939

Überblick

Rubidium hydroxide appears as a grayish-white solid. It is very irritating to skin and eyes. Denser than water. It is used in electric storage batteries.

Namen und Bezeichner

Bevorzugter Name
Rubidium hydroxide
IUPAC
rubidium(1+) hydroxide
Englischer Name
Rubidium hydroxide
Summenformel
HORb
Molmasse
102.47514

Namen und Synonyme

RUBIDIUM HYDROXIDE1310-82-3Rubidium hydroxide (Rb(OH))Rubidium monohydroxideUNII-2692362HBM2692362HBMRUBIDIUM HYDROXIDE [MI]DTXSID1061655CHEBI:32108Rubidium hydroxide ((sup 81)Rb) Injection [JAN]RUBIDIUM HYDROXIDE, (SOLID)RUBIDIUM HYDROXIDE, [SOLID]
Weitere Namen anzeigen
Hydroxyde de rubidiumHidroxido de rubidioUN2677 (solution)RefChem:180182UN2678 (solid)Hidroxido de rubidio, solidoHydroxyde de rubidium, solideDTXCID0034017

Datenbank-Bezeichner

CAS
1310-82-3
PubChem CID
62393
DTXSID
DTXSID1061655
ChEBI
CHEBI:32108
UNII
2692362HBM
EC Number
215-186-0
Nikkaji
J43.981I

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
1 Ų
H-Brücken-Donoren
1
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
0
Schwere Atome
2
Formalladung
0
Komplexität
2

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Metals -> Metals, Inorganic Compounds

Corrosives

Density3 .203 @ 11°C
Melting Point382 °C
Physical Description · 4 Einträge

Rubidium hydroxide appears as a grayish-white solid. It is very irritating to skin and eyes. Denser than water. It is used in electric storage batteries.

Rubidium hydroxide, solution appears as a clear aqueous solution. Very caustic. Very irritating to skin and eyes. Used in electric storage batteries.

Greyish-white deliquescent solid; [Merck Index] 50% aqueous solution: Clear colorless liquid; [Acros Organics MSDS]

V (@25 °C)

Physikochemische Eigenschaften

Schmelzpunkt
301 °C · 301 °C
Dichte
1.05934 g/cm3 · 1.05934 g/cm3(Temp: 25 °C)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H302 (98.6%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P270, P271, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P362+P364, P363, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 74 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Rubidium hydroxide (Rb(OH))

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to human health
DOT Label · 2 Einträge

Corrosive

Corrosive

Fire Hazards · 4 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 4 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

· TOXIC and/or CORROSIVE; inhalation, ingestion or skin contact with material may cause severe injury or death.

Hazards Summary · 1 Eintrag

A stronger base than sodium hydroxide; Corrosive; [Merck Index] Causes respiratory stimulation, GI changes, somnolence, flaccid paralysis, and diffuse hepatitis in oral lethal-dose studies of rats; [RTECS] Reacts with water; Absorbs carbon dioxide from air; A severe skin and eye irritant; [CAMEO] 50% aqueous solution: Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause CNS depression and cardiac disturbances; [Acros Organics MSDS] See Rubidium.

DOT ID and Guide · 2 Einträge

2677 154

2678 154

Reactive Group · 2 Einträge

Bases, Strong

Bases, Strong

Reactivity AlertsWater-Reactive
Reactivity Profile · 2 Einträge

A strong base. Forms caustic solution in water with heat generation [Merck 11th ed. 1989]. May generate sufficient heat when dissolved in water to cause the solution to boil.

A strong base. Forms caustic solution in water [Merck 11th ed. 1989].

DOT Hazard Classification · 4 Einträge

Rubidium hydroxide

UN2678

Class 8 Corrosive material (49 eCFR § 173.136)

PG II: the degree of danger presented by the material is medium

Air and Water Reactions · 2 Einträge

Extremely hygroscopic. Absorbs carbon dioxide from the air. May generate sufficient heat when dissolved in water to cause the solution to boil.

Absorbs carbon dioxide from the air. May generate large amounts of heat when diluted with water.

Sicherheit und Schutzausrüstung

Fire Fighting · 2 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Accidental Release Measures · 4 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 4 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

General First Aid:

General First Aid:

Exposure Control and Personal Protection · 2 Einträge

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear positive pressure self-contained breathing apparatus (SCBA).

Nonfire Spill Response · 2 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Isolation and Evacuation · 4 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Immediate precautionary measure

Immediate precautionary measure

Protective Action Criteria (PAC) · 3 Einträge

1.8 [mg/m3]

19 [mg/m3]

120 [mg/m3]

Personal Protective Equipment (PPE) · 2 Einträge

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Excerpt from ERG Guide 154 [Substances - Toxic and/or Corrosive (Non-Combustible)]:

Emergency Response Planning Guidelines · 2 Einträge

Small Fire

Small Fire

Toxikologische Informationen

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.
RAIS Toxicity Values · 2 Einträge

0.004

PPRTV Current

EPA Provisional Peer-Reviewed Toxicity Values · 4 Einträge

Rubidium Hydroxide

PDF Document

Inadequate information to assess carcinogenic potential

2016

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used as a catalyst in oxidative chlorination; [Merck Index] Used in electric storage batteries; [CAMEO] Used in photography; [NJ-HSFS]

Battery Manufacturing [Category: Industry]

General Manufacturing InformationRubidium hydroxide (Rb(OH)): ACTIVE

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