TITANIUM CHLORIDE (TiCl3) (HCID 62646)

Namen und Bezeichner

Bevorzugter Name: TITANIUM CHLORIDE (TiCl3)
IUPAC: trichlorotitanium
Lokaler Name: Titantrichlorid
Englischer Name: Titanous chloride
Summenformel: TiCl3
Molmasse: 154.22

Namen und Synonyme

TITANIUM TRICHLORIDETrichlorotitanium7705-07-9Titanium chloride (TiCl3)TiCl3TAC 121TAC 131Lynx 900GVD566MM7KTEN 12TGY 24TOS 17

Weitere Namen anzeigen

TITANIUM(III) CHLORIDETitanium (III) chloride (solid)Titanium(iii) chloride, 20% w/w solution in 2n hydrochloric acidtac121tac131

RefChem:190167TAC 140TAC 144TAS 101231-728-9LYNX-900TAC-121TAS-101

Datenbank-Bezeichner

CAS: 7705-07-9
PubChem CID: 62646
DTXSID: DTXSID1052870
EC Number: 231-728-9

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 0
Frei drehbare Bindungen: 0
Schwere Atome: 4
Formalladung: 0
Komplexität: 8

Experimentelle und physikochemische Eigenschaften

Chemical Classes · 2 Einträge

Metals -> Metals, Inorganic Compounds

Flammable agents - 3rd degree

SpringerMaterials Propertiescrystal structure

Density1.772 @25 °C

Boiling Point136.4 °C @760 [mm Hg]

Melting Point-30 °C

Vapor Pressure10 [mm Hg] @21.3 °C

Physikochemische Eigenschaften

Schmelzpunkt: 440 °C · 440 °C (dec.)(lit.)
Siedepunkt: 100 °C · 100 °C
Dichte: 1.192 g/mL · 1.192 g/mL at 25 °C
Löslichkeit: 2 O · reacts with H2O
Aggregatzustand: powder
Farbe: Purple
Wasserlöslichkeit: Soluble
Spezifische Wärmekapazität: 0.63 J/ · Cp(crystal): 0.63 J/(g·K), at 25℃
Merck: 14 · 14,9481
Stabilität: Stable, but reacts violently with water and is spontaneously flammable in air.
InChI: InChI=1S/2ClH.Ti/h2*1H;/q;;+2/p-2
InChIKey: ZWYDDDAMNQQZHD-UHFFFAOYSA-L
SMILES: Cl[Ti](Cl)Cl
CAS Datenbank: 7705 · 7705-07-9(CAS DataBase Reference)
NIST chemische Informationen: Titanium(iii) chloride(7705-07-9)
EPA chemische Informationen: Titanium chloride (TiCl3) (7705-07-9)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H250 (96.6%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

P210, P222, P231, P233, P260, P261, P264, P264+P265, P271, P272, P280, P284, P301+P330+P331, P302+P335+P334, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P319, P320, P321, P333+P317, P362+P364, P363, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 236 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H250: Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Titanium chloride (TiCl3)

REACH registered substance: Titanium trichloride (EC: 231-728-9)

Titanium (III) chloride: Does not have an individual approval but may be used under an appropriate group standard

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Fire Hazards· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

Hazards Summary · 1 Eintrag

Unstable and highly reactive; Powder is pyrophoric; Dissociates rapidly from moisture in air; A powerful reducing agent; [Merck Index] A strong reducing agent; Decomposed by moisture evolving hydrochloric acid; Dry powder is pyrophoric; Corrosive to skin and mucous membranes; [CAMEO] Pyrophoric; Reacts violently with water evolving hydrogen chloride gas; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract; [Sigma-Aldrich MSDS]

DOT ID and Guide2869 157

DOT Hazard Classification · 5 Einträge

Titanium trichloride, pyrophoric or Titanium trichloride mixtures, pyrophoric

UN2441

Div 4.2 Spontaneously combustible material (49 eCFR § 173.124)

PG I: the degree of danger presented by the material is great

Sicherheit und Schutzausrüstung

Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First AidGeneral First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

Isolation and EvacuationImmediate precautionary measure

Protective Action Criteria (PAC) · 3 Einträge

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

Emergency Response Planning Guidelines· Note: Some foams will react with the material and release corrosive/toxic gases.

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.

Sicherheitsdaten

F: 10-23
wgk: 3
tsca: TSCA listed
ridadr: UN 2441
hs_code: 28273990
RTECS-Nr.: XR1924000
risk_code: 34-37-35-17-14
hazard_code: C,F
safety_code: 6-26-30-36/37/39-43-45
hazard_class: 4.2
packing_group: I
Speicherklasse: 8B - Non-combustible corrosive hazardous materials
Hazard Classifications: Eye Dam. 1Met. Corr. 1Skin Corr. 1BSTOT SE 3

Chemie und Industrie

Verwendung und Herstellung

UsesUsed as a reducing agent (nitrate to ammonia), laundry stain remover, and analytical reagent; [Merck Index]

General Manufacturing InformationTitanium chloride (TiCl3): ACTIVE

Anwendungen · 1 Eintrag

VerwendenAs powerful reducing agent, Titanous chlorideb can reduces nitrate to ammonia; when boiled with aqueous SO2, sulfur is separated; hence is used as an aqueous solution for estimation of nitro groups, ferric ions, per-salts, etc. Removes stains, etc. (stripper) in laundering.

Darstellung

synthetischeTitanium trichloride may be prepared by reducing titanium tetrachloride with hydrogen at 600°C. The tetrachloride may alternatively be reduced with aluminum, zinc, magnesium, tin, or by electrolysis.