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Diammoniumhexachloropalladat
hexachloropalladium(2-) · 99.9%(metalsbasis),Pd30% · PALLADIC AMMONIUM CHLORIDE · Ammonium palladic chloride · Ammoniumchloropalladate(IV) · ammoniumhexachloropalladate · Diazanium hexachloropalladium · Diammonium hexachloropalladate

Identifikatoren & physikalische Daten
| CAS No. | 19168-23-1 |
|---|---|
| Summenformel | Cl6Pd.2H4N |
| Durchschnittliche Molmasse | 355,2 g/mol |
| SMILES | [Cl][Pd-2]([Cl])([Cl])([Cl])([Cl])[Cl].[NH4+].[NH4+] |
| InChIKey | LOLIPEAFAJNGJM-UHFFFAOYSA-J |
| PubChem CID | 62732 |
| ChEBI | CHEBI:60124 |
| EC No. | 242-854-9 |
| Lokaler Name | Diammoniumhexachloropalladat |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 2 |
|---|---|
| H-Brücken-Donoren | 2 |
| H-Brücken-Akzeptoren | 1 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 9 |
| Formalladung | 0 |
| Komplexität | 62,7 |
| Physical Description | Wet Solid |
| Schmelzpunkt | °Cd ec.) |
| Dichte | 2,418 g/cm3 |
| Dampfdruck | 0Pa at 20℃ |
| Lagerbedingungen | under inert gas (nitrogen or Argon) at 2-8°C |
| Aggregatzustand | Crystalline |
| Farbe | Red-orange |
| Wichte | 2.418 |
| Löslichkeit | slightly soluble |
| Stabilität | hygroscopic |
| InChI | 1S/6ClH.2H3N.Pd/h6*1H2*1H3/q+4/p-4 |
| InChIKey | LOLIPEAFAJNGJM-UHFFFAOYSA-J |
| SMILES | [NH4+].[NH4+].Cl[Pd--](Cl)(Cl)(Cl)(Cl)Cl |
| CAS Datenbank | 19168-23-1(CAS DataBase Reference) |
| EPA chemische Informationen | Palladate(2-), hexachloro-, diammonium, (OC-6-11)- (19168-23-1) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH301 (68.9%): Toxic if swallowed [Danger Acute toxicity, oral]P261, P264, P264+P265, P270, P272, P273, P280, P301+P316, P301+P317, P302+P352, P305+P351+P338, P305+P354+P338, P317, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 151 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Palladate(2-), hexachloro-, diammonium, (OC-6-11)-Palladate(2-), hexachloro-, ammonium (1:2), (OC-6-11)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Palladate(2-), hexachloro-, ammonium (1:2), (OC-6-11)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Cease Manufacture Update: 13-11-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/19003Restricted substance: Diammonium hexachloropalladate |
| Weitere Sicherheitsinformationen | IMAP assessments - Palladate(2-), hexachloro-, diammonium, (OC-6-11)-: Human health tier I assessment |
| Hazard Classes and Categories | Acute Tox. 3 (68.9%) |
| Treatment | EYES: irrigate opened eyes for several minutes under running water. INGESTION: do not induce vomiting. Rinse mouth with water (never give anything by mouth to an unconscious person). Seek immediate medical advice. SKIN: should be treated immediately by rinsing the affected parts in cold running water for at least 15 minutes, followed by thorough washing with soap and water. If necessary, the person should shower and change contaminated clothing and shoes, and then must seek medical attention. INHALATION: supply fresh air. If required provide artificial respiration. |
| Gesundheitliche Auswirkungen | Contact with palladium may cause palladium sensitivity and allergy. Animal studies have shown that palladium may damage the liver and kidney. (L798) |
| Toxizitätsübersicht | Due to their ability to form strong complexes with both inorganic and organic ligands, palladium ions can disturb cellular equilibria, replace other essential ions, and interact with functional groups of macromolecules, such as proteins or DNA. Palladium complexes binding to DNA and RNA leads to strand breakage. Palladium ions are able to inhibit most major cellular functions, including DNA and RNA synthesis. Palladium compounds have been shown to bind to and inhibit various enzymes, including creatine kinase and prolyl hydroxylase. (L798) |
Anwendungen & Verwendung
Verwenden
Ammonium hexachloropalladate(IV) is used as analytical reagent and as a catalyst in the chemical synthesis. It is also used as raw material and intermediates in organic synthesis and pharmaceutical field. Further, it is used in emission spectrographic analysis.