Chloromethyl chloroformate (HCID 62754)

Überblick

Chloromethyl chloroformate appears as a colorless liquid with a penetrating, irritating odor. Denser than water. Contact may irritate skin, eyes and mucous membranes. Toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.

Namen und Bezeichner

Bevorzugter Name: Chloromethyl chloroformate
IUPAC: chloromethyl carbonochloridate
Lokaler Name: Chlormethylchlorformiat
Englischer Name: Chloromethyl chloroformate
Summenformel: C2H2Cl2O2
Molmasse: 128.94

Namen und Synonyme

Chloromethyl chloroformatechloromethyl carbonochloridatechloromethylchloroformateCarbonochloridic acid, chloromethyl esterPaliteEINECS 244-793-3DTXSID9074567UN 2745Formic acid, chloro-, chloromethyl esterRefChem:125439DTXCID2036613CHLOROMETHOXYCARBONYL CHLORIDE

Weitere Namen anzeigen

JMCCMCFTenofovir Impurity 42Tenofovir Impurity 65Tenofovir Impurity 241Tenofovir Impurity 42 CRSChloromethylchloroformate,97%Chloromethyl chloromethanoate

244-793-3JYWJULGYGOLCGW-UHFFFAOYSA-N22128-62-7Chloroformic Acid Chloromethyl EsterChlorocarbonic acid chloromethyl esterMFCD00077688Chloro-formic acid Chloromethyl Ester; Chloromethoxycarbonyl Chloride; Chloromethyl Carbonochloridate; Chloromethyl Chlorocarbonate; Chloromethyl ChloroformateUN2745

Datenbank-Bezeichner

CAS: 22128-62-7
PubChem CID: 62754
DTXSID: DTXSID9074567
UNII: V6LT723843
EC Number: 244-793-3
Nikkaji: J26.283H

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 1,9
Polarare Oberfläche (TPSA): 26,3 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 2
Frei drehbare Bindungen: 2
Schwere Atome: 6
Formalladung: 0
Komplexität: 53,5

Experimentelle und physikochemische Eigenschaften

Chemical ClassesCorrosives

SpringerMaterials PropertiesSchoenflies notation

Physical Description · 1 Eintrag

Chloromethyl chloroformate appears as a colorless liquid with a penetrating, irritating odor. Denser than water. Contact may irritate skin, eyes and mucous membranes. Toxic by ingestion, inhalation and skin absorption. Used to make other chemicals.

Physikochemische Eigenschaften

Schmelzpunkt: -20 °C · <-20°C
Siedepunkt: 107 · 107-108 °C(lit.)
Dichte: 1.449 g/mL · 1.449 g/mL at 20 °C
Brechungsindex: 20 · n20/D 1.428
Flammpunkt: 95 °C · 95°C
storage temp.: 2 · 2-8°C
Löslichkeit: Chloroform (Soluble), Methanol (Slightly)
Aggregatzustand: clear liquid
Farbe: Colorless to Light yellow to Light orange
Wasserlöslichkeit: Slightly miscible with water.
BRN: 506426 · 506426
Stabilität: Extremely Moisture Sensitive, Hygroscopic
InChI: 1S/C2H2Cl2O2/c3-1-6-2(4)5/h1H2
InChIKey: JYWJULGYGOLCGW-UHFFFAOYSA-N
SMILES: ClCOC(Cl)=O
CAS Datenbank: 22128 · 22128-62-7(CAS DataBase Reference)
EPA chemische Informationen: Carbonochloridic acid, chloromethyl ester (22128-62-7)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H302 (11.8%): Harmful if swallowed [Warning Acute toxicity, oral]

P260, P261, P264, P270, P271, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 51 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory InformationThe New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

DOT LabelPoison Corrosive

Fire Hazards · 2 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.

DOT ID and Guide2745 157

Reactive GroupHalogenated Organic Compounds

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 2 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).

Nonfire Spill ResponseExcerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:

Immediate precautionary measure

Sicherheitsdaten

F: 10-19-21
wgk: 3
ridadr: UN 2745
hs_code: 2915.90.5050
risk_code: 23-34
hazard_code: T
safety_code: 26-36/37/39-45
hazard_class: 6.1
packing_group: II
Speicherklasse: 6.1A - Combustible acute toxic Cat. 1 and 2very toxic hazardous materials
Hazard Classifications: Acute Tox. 3 InhalationSkin Corr. 1B