HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Binap, (A+-)-
RAC-BINAP · (R)-BINAP · (R)-(+)-BINAP · (+)-BINAP · RAC-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL · RACEMIC-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL · (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthalene · (+/-)-BINAP
Identifikatoren & physikalische Daten
| CAS No. | 76189-55-4 |
|---|---|
| Summenformel | C44H32P2 |
| Durchschnittliche Molmasse | 622,7 g/mol |
| Monoisotopische Masse | 622,19792428 g/mol |
| SMILES | c1ccc(P(c2ccccc2)c2ccc3ccccc3c2-c2c(P(c3ccccc3)c3ccccc3)ccc3ccccc23)cc1 |
| InChIKey | MUALRAIOVNYAIW-UHFFFAOYSA-N |
| PubChem CID | 634876 |
| ChEMBL | CHEMBL1275990 |
| EC No. | 616-304-7 |
| DTXSID | DTXSID40913327 |
Chemische & physikalische Eigenschaften
| XLogP | 11,4 |
|---|---|
| Polarare Oberfläche (TPSA) | 0 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 7 |
| Schwere Atome | 46 |
| Formalladung | 0 |
| Komplexität | 797 |
| Schmelzpunkt | 283-286 °C(lit.) |
| Siedepunkt | 724.3±55.0 °C(Predicted) |
| Brechungsindex | 235 ° (C=0.3, Toluene) |
| Lagerbedingungen | Inert atmosphere,Room Temperature |
| Löslichkeit | Benzene (Slightly), Chloroform (Slightly)insoluble |
| Aggregatzustand | Powder |
| Farbe | White to cream-white |
| Merck | 14,1223 |
| BRN | 4914063 |
| InChIKey | MUALRAIOVNYAIW-UHFFFAOYSA-N |
| SMILES | P(C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC2=CC=CC=C2C=1C1C2=CC=CC=C2C=CC=1P(C1C=CC=CC=1)C1C=CC=CC=1 |
| CAS Datenbank | 76189-55-4(CAS DataBase Reference) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH315 (96%): Causes skin irritation [Warning Skin corrosion/irritation]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 25 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.This chemical does not meet GHS hazard criteria for 11.1% (1 of 9) of reports. |
|---|---|
| Hazard Classes and Categories | Skin Irrit. 2 (77.8%)Skin Irrit. 2 (96%) |
| F | 8-10-23 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | No |
| Zollcode | 29319090 |
| R-Sätze (R) | 36/37/38-20/21/22 |
| Gefahrensymbole | Xi,Xn |
| Sicherheitshinweise (S) | 22-24/25-37/39-26-36 |
| Lagerklasse | 11 - Combustible Solids |
Anwendungen & Verwendung
Verwenden
Chiral ligand for metal mediated asymmetric catalysis.