Cyclohexanon, Peroxid

Cyclohexanone peroxi · CYCLOHEXANONE PEROXIDE · Cyclohexanone peroxide solution · 1,1'-Peroxybis(1-hydroperoxycyclohexane) · 1-HYDROPEROXYCYCLOHEXYL-1-HYDROXY CYCLOHEXYL PEROXIDE · CYCLOHEXANONE PEROXIDE, TECH., 50% IN DI OCTYL PHTHALATE · 1-Hydroperoxycyclohexyl-1-hydroxycyclohexyl peroxide 12262-58-7

https://huagongshe.com/de/chemical/6521

Molekülstruktur von Cyclohexanon, Peroxid

Identifikatoren & physikalische Daten

CAS No.	12262-58-7
Summenformel	C12H22O5
Durchschnittliche Molmasse	246,3 g/mol
Monoisotopische Masse	246,1467238 g/mol
SMILES	OOC1(OOC2(O)CCCCC2)CCCCC1
InChIKey	UICXTANXZJJIBC-UHFFFAOYSA-N
PubChem CID	6521
EC No.	201-091-1
DTXSID	DTXSID9058812
Lokaler Name	Cyclohexanon, Peroxid

Chemische & physikalische Eigenschaften

XLogP	2,3
Polarare Oberfläche (TPSA)	68,2
H-Brücken-Donoren	2
H-Brücken-Akzeptoren	5
Frei drehbare Bindungen	4
Schwere Atome	17
Formalladung	0
Komplexität	231
Stoffklassen	Other Classes -> Peroxides, Organic
Dichte	1.05 at 68 °F (USCG, 1999) - Denser than waterwill sink1.15[at 20℃]
Color/Form	Grayish paste
Löslichkeit	OFF-WHITE THICK PASTEINSOL IN WATERSOL IN COMMON ORG SOLVENTS /PASTE WITH DIBUTYL PHTHALATE/Insoluble in watersoluble in most organic solvents9.3g/L at 25℃
Flammpunkt	315 °F Combustible solution) (dibutyl phthalate) (USCG, 1999)
Schmelzpunkt	76-77 °C65-70 °C
Dampfdruck	0.00000071 [mmHg]2.16Pa at 25℃
Physical Description	Cyclohexanone peroxide, not more than 72% in solution is a white solid dissolved in some unkown organic solvent. Responders should try to identify the solvent being used. Solvent is added to lessen explosion hazard.1-hydroxy-1'-hydroperoxy dicyclohexyl peroxide is an odorless thick white liquid. Sinks in water. (USCG, 1999)Odorless thick white liquid or paste[CAMEO] Moist white solid[MSDSonline]
Selbstentzündungstemperatur	757 °F (USCG, 1999)
LogP (Verteilungskoeffizient)	1.2 at 29℃
EPA chemische Informationen	Cyclohexanone, peroxide (12262-58-7)

Sicherheit & Vorschriften

GHS-Einstufung	DangerH240: Heating may cause an explosion [Danger Self-reactive substances and mixturesOrganic peroxides]P210, P234, P235, P240, P260, P264, P270, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P363, P370+P372+P380+P373, P403, P405, P410, P411, P420, and P501 (click each P-code to see the statement)
Regulatorische Informationen	Chemical: Cyclohexanol, 1-[(1-hydroperoxycyclohexyl)dioxy]-Chemical: Cyclohexanone, peroxideCyclohexanone, peroxide is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cyclohexanone, peroxide are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)REACH registered substance: Cyclohexanone, peroxide (EC: 235-527-7)Cyclohexanone peroxide, 30-60%, 30-60% dibutyl phthalate, 10-30% ethyl acetate: Does not have an individual approval but may be used under an appropriate group standardCyclohexanone peroxide, >25% in a non hazardous diluent: Does not have an individual approval but may be used under an appropriate group standard
DOT-Kennzeichnung	Organic Peroxide
Brandgefahren	Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Behavior in Fire: May explode (USCG, 1999)
Brandpotenzial	DANGEROUS /FIRE HAZARD/ BY CHEM REACTION WITH REDUCING AGENTS OR EXPOSURE TO HEAT. THEY ARE POWERFUL OXIDIZERS. /PEROXIDES, ORG/ALTHOUGH FLASHPOINTS OF MOST ORG PEROXIDES ARE NOT EXCEPTIONALLY LOW, WHEN IGNITED THEY BURN MORE FURIOUSLY THAN CORRESPONDING FLAMMABLE LIQ NOT CONTAINING THE PEROXY LINKAGE. ORG PEROXIDES CONTAIN SUFFICIENT AVAILABLE OXYGEN TO SUPPORT THEIR OWN COMBUSTION IN...ABSENCE OF ATMOSPHERIC OXYGEN. /PEROXIDES, ORG/
Gesundheitsgefahren	Excerpt from ERG Guide 145 [Organic Peroxides (Heat and Contamination Sensitive)]:Irritates eyes and skin on contact. Ingestion causes irritation of mouth and stomach. (USCG, 1999)
Gefahrenübersicht	Water is added to paste to decrease explosion hazard