Chlordimethylsilan

Chlorodimethylsilane

HCID 66108CAS 1066-35-9

Grundinformationen

Standard-SMILES
C[SiH](C)Cl
InChIKey
YGHUUVGIRWMJGE-UHFFFAOYSA-N
Summenformel
C2H7ClSi
Durchschnittliche Molmasse
94,61 g/mol
Monoisotopische Masse
94,00055443

Überblick

Dimethylchlorosilane appears as a colorless fuming liquid with a pungent, burning odor. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.

Namen und Bezeichner

Bevorzugter Name
Chlorodimethylsilane
IUPAC
chloro(dimethyl)silane
Lokaler Name
Chlordimethylsilan
Englischer Name
Chlorodimethylsilane
Summenformel
C2H7ClSi
Molmasse
94.62

Namen und Synonyme

dimethylsilyl chloridedimethylmonochlorosilaneRefChem:575834DTXCID807355213-912-01066-35-9ChlorodimethylhydrosilaneChlorodimethylsilaneDimethylchlorohydrosilaneDimethylchlorosilaneDimethylhydrosilyl chlorideDTXSID0027355
Weitere Namen anzeigen
DMCSDMSCCD5470CFS-359orodimethyL
Silane, chlorodimethyl-XR7E4F5838chloro(dimethyl)silaneDimethylsilylchloridechiorodimethylsilaneHSiMe2ClMe2SiHClSiHMe2Cl

Datenbank-Bezeichner

CAS
1066-35-9
PubChem CID
66108
DTXSID
DTXSID0027355
EC Number
213-912-0

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
0
Schwere Atome
4

Experimentelle und physikochemische Eigenschaften

Chemical ClassesToxic Gases & Vapors -> Chlorosilanes
SpringerMaterials Properties29Si nuclear magnetic resonance spectrum
Density0.852 @25 °C
Boiling Point34.6 °C @760 [mm Hg]
Melting Point-111 °C
Vapor Pressure442.6 [mmHg]

Physikochemische Eigenschaften

Schmelzpunkt
111 °C · −111 °C(lit.)
Siedepunkt
34.7 °C · 34.7 °C(lit.)
Dichte
0.852 g/mL · 0.852 g/mL at 25 °C(lit.)
Dampfdichte
4 · 4 (vs air)
Dampfdruck
8.56 psi · 8.56 psi ( 20 °C)
Brechungsindex
20 · n20/D 1.383(lit.)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 0.2% (4 of 2413) of reports.

Danger

H224 (98.8%): Extremely flammable liquid and vapor [Danger Flammable liquids]

P210, P231+P232, P233, P240, P241, P242, P243, P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 2413 reports by companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 4 Einträge

Chemical: Silane, chlorodimethyl-

Silane, chlorodimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, chlorodimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 12-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/14141

Chlorodimethylsilane: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelFlammable Liquid Corrosive
Fire HazardsExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Health HazardsExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Hazards Summary · 1 Eintrag

Reacts violently with water evolving heat and hydrogen chloride gas; Liquid and vapor highly corrosive to skin and respiratory tissue; [CAMEO] Reacts with water producing flammable gases that may ignite spontaneously; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS]

Reactive GroupChlorosilanes

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
First AidExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Exposure Control and Personal Protection · 1 Eintrag

TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].

Nonfire Spill ResponseExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Isolation and EvacuationExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:
Protective Action Criteria (PAC) · 3 Einträge

1.8 [ppm]

22 [ppm]

100 [ppm]

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.

Sicherheitsdaten

F
10-21
wgk
1
tsca
TSCA listed
ridadr
UN 2988 4.3/PG 1
hs_code
29310095
risk_code
11-34-12-35-20-14/15

Chemie und Industrie

Verwendung und Herstellung

UsesToxic Gas from Spilling Chemical in Water [Category: Other]
U.S. Production2023: 2,500,000 - <4,000,000 lb
Industry UsesMonomers
General Manufacturing Information · 2 Einträge

All Other Basic Inorganic Chemical Manufacturing

Silane, chlorodimethyl-: ACTIVE

Anwendungen · 1 Eintrag

VerwendenChlorodimethylsilane is used to prepare vinyldimethylsilanols for palladium-catalyzed cross-coupling with aryl iodides. Chlorodimethylsilane in combination with a tertiary amine such as triethylamine is another useful reagent for the synthesis of hydrodimethylsilyl ethers, especially for large scale preparations.

Anbieter50 Anbieter

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
Shandong chuangyingchemical Co., Ltd.18853181302 · [email protected]
湖北科孚乐材料科技有限公司027-84459282 13720265353 · [email protected]
南通润丰石油化工有限公司66017690 19952660367 · [email protected]

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