Grundinformationen
- Standard-SMILES
C[SiH](C)Cl- InChIKey
YGHUUVGIRWMJGE-UHFFFAOYSA-N- Summenformel
- C2H7ClSi
- Durchschnittliche Molmasse
- 94,61 g/mol
- Monoisotopische Masse
- 94,00055443
Überblick
Dimethylchlorosilane appears as a colorless fuming liquid with a pungent, burning odor. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.
Namen und Bezeichner
- Bevorzugter Name
- Chlorodimethylsilane
- IUPAC
- chloro(dimethyl)silane
- Lokaler Name
- Chlordimethylsilan
- Englischer Name
- Chlorodimethylsilane
- Summenformel
- C2H7ClSi
- Molmasse
- 94.62
Namen und Synonyme
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Datenbank-Bezeichner
- CAS
1066-35-9- PubChem CID
- 66108
- DTXSID
DTXSID0027355- EC Number
- 213-912-0
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 0
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 4
- Formalladung
- 0
- Komplexität
- 13,5
Experimentelle und physikochemische Eigenschaften
Physical Description
Dimethylchlorosilane appears as a colorless fuming liquid with a pungent, burning odor. Extremely corrosive to skin and respiratory tissues, both as a liquid and vapor. Vapors are heavier than air.
Liquid
Colorless fuming liquid with a pungent, burning odor; Bp = 35 deg C; [CAMEO]
Physikochemische Eigenschaften
- Schmelzpunkt
- 111 °C · −111 °C(lit.)
- Siedepunkt
- 34.7 °C · 34.7 °C(lit.)
- Dichte
- 0.852 g/mL · 0.852 g/mL at 25 °C(lit.)
- Dampfdichte
- 4 · 4 (vs air)
- Dampfdruck
- 8.56 psi · 8.56 psi ( 20 °C)
- Brechungsindex
- 20 · n20/D 1.383(lit.)
- Flammpunkt
- 20 °F · −20 °F
- storage temp.
- 2 · 2-8°C
- Löslichkeit
- Miscible with organic solvents.
- Aggregatzustand
- Liquid
- Farbe
- Clear colorless
- Wichte
- 0.868 · 0.868
- Explosionsgrenze
- 3 · 3.0-20.0%(V)
- Wasserlöslichkeit
- reacts
- BRN
- 1633434 · 1633434
- InChI
- 1S/C2H7ClSi/c1-4(2)3/h4H,1-2H3
- InChIKey
- YGHUUVGIRWMJGE-UHFFFAOYSA-N
- SMILES
- C[SiH](C)Cl
- CAS Datenbank
- 1066 · 1066-35-9(CAS DataBase Reference)
- NIST chemische Informationen
- Silane, chlorodimethyl-(1066-35-9)
- EPA chemische Informationen
- Silane, chlorodimethyl- (1066-35-9)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 0.2% (4 of 2413) of reports.
Danger
H224 (98.8%): Extremely flammable liquid and vapor [Danger Flammable liquids]
P210, P231+P232, P233, P240, P241, P242, P243, P260, P261, P264, P271, P280, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P321, P363, P370+P378, P402+P404, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 2413 reports by companies from 13 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory Information
Chemical: Silane, chlorodimethyl-
Silane, chlorodimethyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, chlorodimethyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 12-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/14141
Chlorodimethylsilane: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
Reacts violently with water evolving heat and hydrogen chloride gas; Liquid and vapor highly corrosive to skin and respiratory tissue; [CAMEO] Reacts with water producing flammable gases that may ignite spontaneously; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Sigma-Aldrich MSDS]
Reactivity Profile
Chlorosilanes, such as DIMETHYLCHLOROSILANE, are compounds in which silicon is bonded to from one to four chlorine atoms with other bonds to hydrogen and/or alkyl groups. Chlorosilanes react with water, moist air, or steam to produce heat and toxic, corrosive fumes of hydrogen chloride. They may also produce flammable gaseous H2. They can serve as chlorination agents. Chlorosilanes react vigorously with both organic and inorganic acids and with bases to generate toxic or flammable gases.
Sicherheit und Schutzausrüstung
Exposure Control and Personal Protection
TIH (Toxic Inhalation Hazard) - Term used to describe gases and volatile liquids that are toxic when inhaled. Some are TIH materials themselves, e.g., chlorine, and some release TIH gases when spilled in water, e.g., chlorosilanes. [ERG 2016].
Protective Action Criteria (PAC)
1.8 [ppm]
22 [ppm]
100 [ppm]
AEGLs Table
AEGL 1: Notable discomfort, irritation, or certain asymptomatic non-sensory effects. However, the effects are not disabling and are transient and reversible upon cessation of exposure (Unit: ppm)
1.8
1.8
1.8
1.8
1.8
Toxikologische Informationen
Sicherheitsdaten
- F
- 10-21
- wgk
- 1
- tsca
- TSCA listed
- ridadr
- UN 2988 4.3/PG 1
- hs_code
- 29310095
- risk_code
- 11-34-12-35-20-14/15
- hazard_code
- F,C,F+
- safety_code
- 16-26-36/37/39-45-9-43
- hazard_class
- 3
- packing_group
- I
- Speicherklasse
- 4.3 - Hazardous materials which set free flammable gases upon contact with water
- Hazard Classifications
- Acute Tox. 3 InhalationFlam. Liq. 1Skin Corr. 1AWater-react 3
Chemie und Industrie
Verwendung und Herstellung
General Manufacturing Information
All Other Basic Inorganic Chemical Manufacturing
Silane, chlorodimethyl-: ACTIVE
Anwendungen
VerwendenChlorodimethylsilane is used to prepare vinyldimethylsilanols for palladium-catalyzed cross-coupling with aryl iodides. Chlorodimethylsilane in combination with a tertiary amine such as triethylamine is another useful reagent for the synthesis of hydrodimethylsilyl ethers, especially for large scale preparations.
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