Chlordiphenylphosphin

Chlorodiphenylphosphine

HCID 66180CAS 1079-66-9
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Grundinformationen

Standard-SMILES
ClP(c1ccccc1)c1ccccc1
InChIKey
XGRJZXREYAXTGV-UHFFFAOYSA-N
Summenformel
C12H10ClP
Durchschnittliche Molmasse
220,63 g/mol
Monoisotopische Masse
220,02086463

Namen und Bezeichner

Bevorzugter Name
Chlorodiphenylphosphine
IUPAC
chloro(diphenyl)phosphane
Lokaler Name
Chlordiphenylphosphin
Englischer Name
Chlorodiphenylphosphine
Summenformel
C12H10ClP
Molmasse
220.63

Namen und Synonyme

Chlorodiphenylphosphine1079-66-9DiphenylchlorophosphineDiphenylphosphinous chloridePhosphinous chloride, diphenyl-chloro(diphenyl)phosphaneP-ChlorodiphenylphosphinechlorodiphenylphosphaneDiphenylphosphine chloridePhosphine, chlorodiphenyl-C12H10ClPMFCD00000529
Weitere Namen anzeigen
DPPCPH2PCLDiphenylphosphorus chlorideAURORA KA-132295% (C6H5)2PClChlordiphenylphosphin
ClPPh2PPh2ClDiphenyl(chloro)phosphinePhosphinous chloride, P,P-diphenyl-WO975PJK1YNSC-60407diphenyl chlorophosphinediphenyl phosphine chloride

Datenbank-Bezeichner

CAS
1079-66-9
PubChem CID
66180
DTXSID
DTXSID7038789
UNII
WO975PJK1Y
EC Number
214-093-2
Nikkaji
J24.880K

Eigenschaften

Berechnete Struktureigenschaften

XLogP
3,8
Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
2
Schwere Atome
14

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Classes -> Phosphorus Compounds
SpringerMaterials PropertiesNuclear quadrupole resonance spectroscopy
Physical DescriptionYellow liquid; [Merck Index] Yellow liquid with an acrid odor; [Alfa Aesar MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
14 · 14-16°C
Siedepunkt
320 °C · 320 °C(lit.)
Dichte
1.229 g/mL · 1.229 g/mL at 25 °C(lit.)
Dampfdichte
7.8 · 7.8 (vs air)
Dampfdruck
1.3 hPa · 1.3 hPa (20 °C)
Brechungsindex
20 · n20/D 1.636(lit.)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 0.5% (1 of 212) of reports.

Danger

H290 (67%): May be corrosive to metals [Warning Corrosive to Metals]

P234, P260, P264, P264+P265, P270, P273, P280, P301+P317, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P390, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 212 reports by companies from 19 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Phosphinous chloride, diphenyl-

Status: Active Update: 07-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/24379

Chlorodiphenylphosphine: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 Eintrag

Reacts violently with water; Causes burns and lachrymation; [Merck Index] Reacts violently with water; Causes burns and lachrymation; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Triphenylphosphine oxide.

Hazard Classes and CategoriesMet. Corr. 1 (67%)

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.

Sicherheitsdaten

F
1-9-19
wgk
2
tsca
TSCA listed
ridadr
UN 3265 8/PG 2
hs_code
29310095
risk_code
14-34-29-36

Chemie und Industrie

Verwendung und Herstellung

UsesUsed as a reagent in organic chemistry; [Merck Index] Used as an intermediate; [ExPub: ECHA REACH Registrations]
General Manufacturing InformationPhosphinous chloride, P,P-diphenyl-: ACTIVE
Anwendungen · 1 Eintrag

VerwendenChlorodiphenylphosphine is used to introduce the diphenylphosphinyl moiety by aryl ortho-lithiation. It is also used as an intermediate to make antioxidants, flame retardants, stabilizers, catalysts, photoinitiators, and optical brighteners. Used as a halogenation reagent for the conversion of alcohols into halides, in the preparation of solid-phase reagent for the conversion of alcohols to alkyl halides.

Vor- und nachgelagerte Produkte

Anbieter50 Anbieter

国药集团化学试剂有限公司86-21-63210123 · [email protected]
梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
艾特（浙江）供应链管理有限公司15553101207 18615619105

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