Octahydro-2,4-methano-2H-indeno-(1,2-b:5,6-b')bis-oxiren

Dicyclopentadiene dioxide

HCID 6673CAS 81-21-0

Grundinformationen

Standard-SMILES
C1C2OC2C2C1C1CC2C2OC12
InChIKey
BQQUFAMSJAKLNB-UHFFFAOYSA-N
Summenformel
C10H12O2
Durchschnittliche Molmasse
164,2 g/mol
Monoisotopische Masse
164,08372962

Namen und Bezeichner

Bevorzugter Name
Dicyclopentadiene dioxide
IUPAC
4,10-dioxapentacyclo[6.3.1.02,7.03,5.09,11]dodecane
Lokaler Name
Octahydro-2,4-methano-2H-indeno-(1,2-b:5,6-b')bis-oxiren
Englischer Name
Dicyclopentadiene diepoxide
Summenformel
C10H12O2
Molmasse
164.2

Namen und Synonyme

Dicyclopentadiene diepoxideDICYCLOPENTADIENE DIOXIDEHSDB 5240Dicyclopentadiene dioxide (VAN)DTXSID4020452EINECS 201-334-11,2:5,6-Diepoxyhexahydro-4,7-methanoindanAI3-260462,4-Methano-2H-indeno(1,2-b:5,6-b')bisoxirene, octahydro-2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-Dicyclopentadiene dioxide, 70% exo isomers, 30% endo isomersDTXCID00452
Weitere Namen anzeigen
BICYCLOPENTADIENE DIEPOXIDE2,4-Methano-2H-indeno1,2-b:5,6-bbisoxirene, octahydro-ep207unox207unox207xepoxide207unoxepoxide207bicyclopentadienedioxideBicyelopentadiene dioxide
NSC-24262NSC-30544NSC-34460NSC-54738NSC-56357UNII-4UQK50194RRefChem:1332582,4-METHANO-2H-INDENO(1,2-B:5,6-B')BISOXIRENE, OCTAHYDRO-, (1A.ALPHA.,1B.BETA.,2.BETA.,2A.ALPHA.,3A.ALPHA.,4.BETA.,4A.BETA.,5A.ALPHA.)-

Datenbank-Bezeichner

CAS
81-21-0
PubChem CID
6673
DTXSID
DTXSID4020452
ChEMBL
CHEMBL3184982
EC Number
201-334-1
Nikkaji
J192.584I

Eigenschaften

Berechnete Struktureigenschaften

XLogP
0,8
Polarare Oberfläche (TPSA)
25,1 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
0
Schwere Atome
12

Experimentelle und physikochemische Eigenschaften

PolymersPlastics & Rubber -> Epoxides
OdorMILD TERPENE LIKE ODOR MAY BE MASKED BY MORE POWERFUL & DISTINCTIVE HYDROCARBON ODOR OF DICYCLOPENTADIENE.
Density1.331 @ 25 °C
Color/FormWHITE CRYSTALLINE POWDER
Solubility · 5 Einträge

SOL IN BENZENE

1.4% IN WATER

18.6% IN METHANOL

44.7% IN ACETONE

18.7% IN ETHER

Melting Point180-184 °C

Physikochemische Eigenschaften

Schmelzpunkt
185 · 185-189 °C(lit.)
Siedepunkt
120 °C · 120°C 10mm
Dichte
1 · 1,331 g/cm3
Brechungsindex
1.546 · 1.5460 (estimate)
Flammpunkt
120 °C/10mm · 120°C/10mm subl.
storage temp.
2 · 2-8°C

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P264, P264+P265, P270, P280, P301+P316, P305+P351+P338, P321, P330, P337+P317, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: 2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-

2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

Hazards SummaryMild irritant on rabbit skin; Methemoglobinemia, CNS effects, and proteinuria reported in inhalation studies of rats; [RTECS] Emergency treatment: irritants; [HSDB] An eye irritant; [MSDSonline]
TSCA RequirementsSection 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329.
Hazard Classes and CategoriesAcute Tox. 3 (100%)

Toxikologische Informationen

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect
Human Toxicity ExcerptsNo cases of dermatitis or sensitization have been reported /in man/.
Non-Human Toxicity Excerpts · 2 Einträge

CMPD IS MODERATELY TOXIC FOLLOWING ORAL OR IP ENTRY INTO BODY & PRACTICALLY NONTOXIC ON PERCUTANEOUS ABSORPTION. ... THE LETHAL RANGE WHEN GIVEN ORALLY TO RATS AS 50 TO 140 MG/KG, AND 11 TO 53 MG/KG INTRAPERITONEALLY. ... RABBITS TOLERATED 1 G/KG PERCUTANEOUSLY WITHOUT EFFECT. IN INHALATION EXPERIMENTS A DOSE OF 1 G/CU M FOR 1 HR WAS MODERATELY TOXIC, AND 10 G/CU M FOR 1 HR WAS LETHAL TO 5 OF 6 TEST ANIMALS. SATURATED VAPORS WERE NONLETHAL TO RATS IN 8 HR EXPOSURE. ... MILDLY IRRITATING BUT NO CORNEAL INJURY IN RABBITS WITH TEST QUANT OF 0.05 G. 40% SOLN WAS LEAST CONCN TO CAUSE BARELY DETECTABLE INJURY. ... SKIN IRRITATION. UNDIL MATERIAL CAUSED REDNESS OF SHORT DURATION.

DICYCLOPENTADIENE DIOXIDE DID NOT SHOW ANY ALLERGENIC PROPERTIES WHEN APPLIED IN 10-50% SOLN TO SKIN OF GUINEA PIGS FOR 5-15 DAYS.

Regulatorische Informationen

TSCA RequirementsSection 8(a) of TSCA requires manufacturers of this chemical substance to report preliminary assessment information concerned with production, use, and exposure to EPA as cited in the preamble of the 51 FR 41329.

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
UN 2811 6.1/PG 3
hs_code
29109000
RTECS-Nr.
PB9625200
risk_code
22-36

Chemie und Industrie

Verwendung und Herstellung

Uses · 5 Einträge

Used as an intermediate for epoxy resins, plasticizers, and protective coatings; as a rubber additive; and for high temperature and high performance adhesives; [HSDB]

Working with Glues and Adhesives [Category: Other]

INTERMEDIATE FOR EPOXY RESINS, PLASTICIZERS, PROTECTIVE COATINGS

RUBBER ADDITIVE, EG, FOR CRACK PREVENTION & ADHESION

For high temp & high performance system, adhesives

U.S. Production · 2 Einträge

(1979) PROBABLY GREATER THAN 2.72X10+6 G

(1980) PROBABLY GREATER THAN 2.72X10+6 G

Methods of ManufacturingPROBABLY BY DIELS-ALDER CONDENSATION OF CYCLOPENTADIENE FOLLOWED BY EPOXIDATION.
General Manufacturing Information · 2 Einträge

2,4-Methano-2H-indeno[1,2-b:5,6-b']bisoxirene, octahydro-: ACTIVE

AVAIL IN EXPTL QUANT, THIS DIFUNCTIONAL EPOXIDE IS SUGGESTED FOR USE AS PRIMARY BUILDING BLOCK FOR EPOXY RESIN SYSTEM. IT HAS ALSO BEEN SUGGESTED IN MODIFICATION OF ALKYD RESINS, AS PLASTICIZER, & AS CHEMICAL INTERMEDIATE.

Anwendungen · 1 Eintrag

VerwendenDicyclopentadiene diepoxide acts as an intermediate for epoxy resins, plasticizers and protective coatings. It finds application as a rubber additive and adhesives, which is used at high temperature. Further, it is used in the preparation of endo-3-hydroxy-exo-9-oxa-exo-tetracyclo[5.3.1.02,6.08,10]undecane using lithium aluminum hydride as a reagent.

Anbieter50 Anbieter

郑州阿尔法化工有限公司+86-18530059196 · [email protected]
衢州润东化工有限公司0570-8789886 18892685668 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]

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