HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Benzo[f]chinolin
BENZO[F]QUINOLINE · Benzoquinoline · NSC 9850 · NAPHTHOPYRIDINE · azaphenanthrene · 1-AZAPHENANTHRENE · 5,6-BENZOQUINOLINE · b-naphthoquinoline
![Molekülstruktur von Benzo[f]chinolin](/img/chemical/6796.png)
Identifikatoren & physikalische Daten
| CAS No. | 85-02-9 |
|---|---|
| Summenformel | C13H9N |
| Durchschnittliche Molmasse | 179,22 g/mol |
| Monoisotopische Masse | 179,07349929 g/mol |
| SMILES | c1ccc2c(c1)ccc1ncccc12 |
| InChIKey | HCAUQPZEWLULFJ-UHFFFAOYSA-N |
| PubChem CID | 6796 |
| ChEMBL | CHEMBL1565107 |
| EC No. | 201-582-0 |
| DTXSID | DTXSID2024585 |
| Lokaler Name | Benzo[f]chinolin |
Chemische & physikalische Eigenschaften
| XLogP | 3,5 |
|---|---|
| Polarare Oberfläche (TPSA) | 12,9 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 1 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 14 |
| Formalladung | 0 |
| Komplexität | 201 |
| Stoffklassen | Nitrogen Compounds -> Quinolines |
| SpringerMaterials Properties | Angular frequency |
| LogP (Verteilungskoeffizient) | 3.25 |
| Löslichkeit | less than 0.1 mg/mL at 66 °F (NTP, 1992)Insoluble in water |
| Flammpunkt | 330.8 °F (NTP, 1992)166 °C |
| Siedepunkt | 662 °F at 721 mmHg (NTP, 1992)349 °C (721 mmHg) |
| Schmelzpunkt | 199 to 201 °F (NTP, 1992)89-91 °C |
| Dampfdruck | 5.5 mmHg at 66 °F (NTP, 1992)0.000056 [mmHg] |
| Physical Description | Benzo[f]quinoline appears as yellow crystals or white powder. Characteristic irritating odor. (NTP, 1992)Solid[Merck Index] Yellow or white solid with a characteristic irritating odor[CAMEO] |
| Collision Cross Section | 134.7 Ų [M+H]+ [CCS Type: DTBuffer gas: N2Ionization: APCI+Dataset: TOXCASTSource Identifier: DTXSID2024585] |
| Dichte | 1.1255 (rough estimate) |
| Brechungsindex | 1.7270 (estimate) |
| Lagerbedingungen | Keep in dark place,Sealed in dry,Room Temperature |
| Aggregatzustand | Crystalline |
| pKa (Säurekonstante) | pK1: 5.00(+1) (25°C) |
| Farbe | Leaflets from H2O or pet ether |
| Merck | 14,1105 |
| Henry-Konstante | 5.7×101 mol/(m3Pa) at 25℃, Duchowicz et al. (2020) |
| CAS Datenbank | 85-02-9(CAS DataBase Reference) |
| EPA chemische Informationen | Benzo[f]quinoline (85-02-9) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH301 (97.5%): Toxic if swallowed [Danger Acute toxicity, oral]P264, P264+P265, P270, P280, P301+P316, P305+P354+P338, P317, P321, P330, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 40 reports by companies from 2 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Not Classified |
|---|---|
| Regulatorische Informationen | Chemical: Benzo[f]quinoline |
| Brandgefahren | This compound is combustible. (NTP, 1992) |
| Gesundheitsgefahren | SYMPTOMS: Symptoms of exposure to this compound include severe local damage to the skin and mucous membranes indicated by discoloration, severe irritation, redness, swelling and the formation of blisters and bumps. It may also cause visual disturbances, eye irritation, conjunctivitis, light-sensitivity, tearing and burning sensations. Chronic exposure may cause necrosis and corneal injury. |
| Gefahrenübersicht | Causes severe irritation and local injury to skin and mucous membranesEye contact may cause severe visual disturbances, lachrymation, conjunctivitis, burning sensation, and corneal injury[NTP] An irritant that may cause serious eye injuryToxic by ingestion[Sigma-Aldrich MSDS] See Quinoline and Naphthalene. |
| Reaktive Gruppe | Amines, Phosphines, and Pyridines |
| Reactivity Profile | BENZO[F]QUINOLINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides. |
| Air and Water Reactions | Sensitive to prolonged exposure to air. Insoluble in water. |
| Hazard Classes and Categories | Acute Tox. 3 (97.5%)Hazardous to the aquatic environment (Acute) - Category 2 |
| Brandbekämpfung | Fires involving this compound should be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992) |
| Erste Hilfe | EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. |
| Freisetung ohne Brand | SMALL SPILLS AND LEAKAGE: Should a spill occur while you are handling this chemical, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with 60-70% ethanol and transfer the dampened material to a suitable container. Use absorbent paper dampened with 60-70% ethanol to pick up any remaining material. Seal the absorbent paper, and any of your clothes, which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with 60-70% ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. |
| Personal Protective Equipment (PPE) | MINIMUM PROTECTIVE CLOTHING: If Tyvek-type disposable protective clothing is not worn during handling of this chemical, wear disposable Tyvek-type sleeves taped to your gloves. |
| Unerwünschte Wirkungen | Lacrimator (Lachrymator) - A substance that irritates the eyes and induces the flow of tears. |
| Zollcode | 29334990 |
| RTECS-Nr. | DK1428000 |
| R-Sätze (R) | 40-36/37/38 |
| Toxizität | mma-sat 50 mg/plate 50NNAZ 7,73,83 |
| Gefahrensymbole | Xn |
| Sicherheitshinweise (S) | 45-36/37/39-26 |
Anwendungen & Verwendung
Verwenden
As a reagent for the determination of cadmium which is pptd as (C13H9N)2H2(CdI4) from dil nitric or sulfuric acid solution in the presence of potassium iodide.