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1,8-Naphthylendiamin
Naphthalene-1,8-diamine · 1,8-NAPHTHALENEDIAMINE · 1,8-Diaminonaphthalene,99% · 1,8-DiaminonaphthaL · 8-Diaminonaphthalene · 1,8-Diaminonaphthale · 1,8-Naphthylendiamin · 1,8-DIAMINONAPHTHALONE
Identifikatoren & physikalische Daten
| CAS No. | 479-27-6 |
|---|---|
| Summenformel | C10H10N2 |
| Durchschnittliche Molmasse | 158,2 g/mol |
| Monoisotopische Masse | 158,08439832 g/mol |
| SMILES | Nc1cccc2cccc(N)c12 |
| InChIKey | YFOOEYJGMMJJLS-UHFFFAOYSA-N |
| PubChem CID | 68067 |
| ChEMBL | CHEMBL595537 |
| EC No. | 207-529-8 |
| DTXSID | DTXSID6044432 |
| Lokaler Name | 1,8-Naphthylendiamin |
Chemische & physikalische Eigenschaften
| XLogP | 2,1 |
|---|---|
| Polarare Oberfläche (TPSA) | 52 |
| H-Brücken-Donoren | 2 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 12 |
| Formalladung | 0 |
| Komplexität | 142 |
| Polymers | Nitrogen Compounds -> Amines, Polyaromatic |
| SpringerMaterials Properties | 13C nuclear magnetic resonance spectrum |
| LogP (Verteilungskoeffizient) | 1.78 |
| Dampfdruck | 0.0000293 [mmHg]0.011Pa at 25℃ |
| Physical Description | Solid[Merck Index] Light brown crystalline solid[Sigma-Aldrich MSDS] |
| Schmelzpunkt | 60-65 °C (lit.) |
| Siedepunkt | 205 °C/12 mmHg (lit.) |
| Dichte | 1.1265 |
| Brechungsindex | 1.6829 |
| Flammpunkt | 205°C/12mm |
| Lagerbedingungen | Store below +30°C. |
| Löslichkeit | methanol: solubleslightly soluble |
| Aggregatzustand | Chunks or Crystalline Mass |
| pKa (Säurekonstante) | 4.46±0.10(Predicted) |
| Farbe | Grayish-red to gray or dark brown |
| Merck | 14,6372 |
| BRN | 742841 |
| Stabilität | Air Sensitive |
| InChI | 1S/C10H10N2/c11-8-5-1-3-7-4-2-6-9(12)10(7)8/h1-6H,11-12H2 |
| InChIKey | YFOOEYJGMMJJLS-UHFFFAOYSA-N |
| SMILES | Nc1cccc2cccc(N)c12 |
| LogP (Verteilungskoeffizient) | 1.335 |
| CAS Datenbank | 479-27-6(CAS DataBase Reference) |
| NIST chemische Informationen | 1,8-Naphthalenediamine(479-27-6) |
| EPA chemische Informationen | 1,8-Naphthalenediamine (479-27-6) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH302 (99.4%): Harmful if swallowed [Warning Acute toxicity, oral]P203, P261, P264, P270, P272, P273, P280, P301+P317, P302+P352, P318, P321, P330, P333+P317, P362+P364, P391, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 172 reports by companies from 15 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: 1,8-NaphthalenediamineStatus: Active Update: 02-02-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/212851,8-Naphthalenediamine: Does not have an individual approval but may be used under an appropriate group standard |
| Gefahrenübersicht | May cause skin sensitizationHarmful by ingestion[ECHA REACH Registrations] May cause irritation and skin sensitizationSuspected carcinogen[Sigma-Aldrich MSDS] See p-Phenylenediamine and o-Phenylenediamine. See 1,5-Naphthalenediamine. |
| Hazard Classes and Categories | Acute Tox. 4 (99.4%) |
| Unerwünschte Wirkungen | Skin Sensitizer - An agent that can induce an allergic reaction in the skin. |
| F | 8 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | 2811 |
| Zollcode | 29215940 |
| R-Sätze (R) | 22-40-43-36/37/38 |
| Toxizität | LD50 orally in Rabbit: 800 mg/kg |
| Gefahrensymbole | Xn,Xi |
| hazard_note | Irritant |
| Sicherheitshinweise (S) | 36/37-36/37/39-26-24-36 |
| Lagerklasse | 11 - Combustible Solids |
| Gefahrenklasse | Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Carc. 2Skin Sens. 1 |
Anwendungen & Verwendung
Verwenden
1,8-Diaminonaphthalene is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. 1,8-Naphthalenediamine has minor use as an antioxidant for lubricating oils and as an analytical reagent for the detection of selenium and nitrites.