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2-Iodbenzoylchlorid
SKL1215 · 2-iodo-benzoylchlorid · O-IODOBENZOYL CHLORIDE · 2-IODOBENZOYL CHLORIDE · 2-IodobenzoylChloride>Benzoyl chloride, 2-iodo- · 2-Iodobenzoylchloride,97% · 2-Iodobenzoic acid chloride · 9-(phenylmethyl)phenanthrene
Identifikatoren & physikalische Daten
| CAS No. | 609-67-6 |
|---|---|
| Summenformel | C7H4ClIO |
| Durchschnittliche Molmasse | 266,46 g/mol |
| Monoisotopische Masse | 265,89954043 g/mol |
| SMILES | O=C(Cl)c1ccccc1I |
| InChIKey | MVIVDSWUOGNODP-UHFFFAOYSA-N |
| PubChem CID | 69112 |
| EC No. | 210-196-1 |
| DTXSID | DTXSID4060573 |
| Lokaler Name | 2-Iodbenzoylchlorid |
Chemische & physikalische Eigenschaften
| XLogP | 3,4 |
|---|---|
| Polarare Oberfläche (TPSA) | 17,1 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 1 |
| Frei drehbare Bindungen | 1 |
| Schwere Atome | 10 |
| Formalladung | 0 |
| Komplexität | 138 |
| Stoffklassen | Toxic Gases & Vapors -> Acid Halides |
| Physical Description | Off-white solidmp = 27-32 deg C[Alfa Aesar MSDS] |
| Schmelzpunkt | 27-31 °C(lit.) |
| Siedepunkt | 105-106 °C1 mm Hg(lit.) |
| Dichte | 1.932 |
| Flammpunkt | >110°C |
| Lagerbedingungen | Keep in dark place,Inert atmosphere,2-8°C |
| Löslichkeit | soluble in TolueneReacts with water. |
| Aggregatzustand | powder to lump |
| Farbe | White to Light yellow to Dark green |
| BRN | 2042672 |
| InChI | 1S/C7H4ClIO/c8-7(10)5-3-1-2-4-6(5)9/h1-4H |
| InChIKey | MVIVDSWUOGNODP-UHFFFAOYSA-N |
| SMILES | ClC(=O)c1ccccc1I |
| CAS Datenbank | 609-67-6(CAS DataBase Reference) |
| EPA chemische Informationen | Benzoyl chloride, 2-iodo- (609-67-6) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 46 reports by companies from 4 notifications to the ECHA C&L Inventory. |
|---|---|
| Regulatorische Informationen | 2-Iodobenzoyl chloride: Does not have an individual approval but may be used under an appropriate group standard |
| Gefahrenübersicht | Reacts with waterCauses burnsInhalation may cause corrosive injuries to upper respiratory tract and lungs[Alfa Aesar MSDS] See Benzoyl chloride. |
| Hazard Classes and Categories | Skin Corr. 1B (100%) |
| Unerwünschte Wirkungen | Dermatotoxin - Skin burns. |
| F | 21-19 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 3261 8/PG 2 |
| Zollcode | 29163990 |
| R-Sätze (R) | 34 |
| Gefahrensymbole | C |
| Sicherheitshinweise (S) | 26-36/37/39-45 |
| Gefahrenklasse | 8Eye Dam. 1Skin Corr. 1B |
| Verpackungsgruppe | II |
| Lagerklasse | 8A - Combustible corrosive hazardous materials |
Anwendungen & Verwendung
Verwenden
2-Iodobenzoyl chloride has been used in palladium-catalyzed synthesis of carbomethoxy functional group-induced isoindolin-1-ones, preparation of starting materials required for the synthesis of novel cyclic derivatives of pentavalent iodine, benziodazole oxides.