| GHS-Einstufung | WarningH302+H312+H332 (97.2%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oralacute toxicity, dermalacute toxicity, inhalation]H302 (97.2%): Harmful if swallowed [Warning Acute toxicity, oral]H312 (97.2%): Harmful in contact with skin [Warning Acute toxicity, dermal]H332 (97.2%): Harmful if inhaled [Warning Acute toxicity, inhalation]H411 (97.2%): Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]P261, P264, P270, P271, P273, P280, P301+P317, P302+P352, P304+P340, P317, P321, P330, P362+P364, P391, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 107 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
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| Regulatorische Informationen | Status: Cease Manufacture Update: 05-09-2012 https://echa.europa.eu/registration-dossier/-/registered-dossier/10048 |
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| DOT-Kennzeichnung | Poison |
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| Brandgefahren | This compound is probably combustible. (NTP, 1992) |
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| Gesundheitsgefahren | SYMPTOMS: Similar chemicals cause methemoglobinemia resulting in cyanosis. This type of compound may cause irritation of the eyes, skin, mucous membranes and upper respiratory tract.ACUTE/CHRONIC HAZARDS: This type of compound may be fatal if inhaled, swallowed or absorbed through the skin. Vapor or mist may be irritating to the eyes, skin, mucous membranes and upper respiratory tract. When heated to decomposition this type of compound may emit toxic fumes of carbon monoxide, carbon dioxide and oxides of nitrogen. (NTP, 1992) |
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| Reaktive Gruppe | Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic |
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| Reactivity Profile | 1,4-DIMETHYL-2-NITROBENZENE is incompatible with strong oxidizers and strong bases (NTP, 1992). |
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| Air and Water Reactions | Insoluble in water. |
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| Hazard Classes and Categories | Acute Tox. 4 (97.2%)Aquatic Chronic 2 (97.2%) |
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| Brandbekämpfung | Fires involving this compound can be controlled using a dry chemical, carbon dioxide, or Halon extinguisher. (NTP, 1992) |
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| Erste Hilfe | EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.SKIN: IMMEDIATELY flood affected skin with water while removing and isolating all contaminated clothing. Gently wash all affected skin areas thoroughly with soap and water. If symptoms such as redness or irritation develop, IMMEDIATELY call a physician and be prepared to transport the victim to a hospital for treatment.INHALATION: IMMEDIATELY leave the contaminated areatake deep breaths of fresh air. If symptoms (such as wheezing, coughing, shortness of breath, or burning in the mouth, throat, or chest) develop, call a physician and be prepared to transport the victim to a hospital. Provide proper respiratory protection to rescuers entering an unknown atmosphere. Whenever possible, Self-Contained Breathing Apparatus (SCBA) should be usedif not available, use a level of protection greater than or equal to that advised under Protective Clothing.INGESTION: DO NOT INDUCE VOMITING. If the victim is conscious and not convulsing, give 1 or 2 glasses of water to dilute the chemical and IMMEDIATELY call a hospital or poison control center. Be prepared to transport the victim to a hospital if advised by a physician. If the victim is convulsing or unconscious, do not give anything by mouth, ensure that the victim's airway is open and lay the victim on his/her side with the head lower than the body. DO NOT INDUCE VOMITING. IMMEDIATELY transport the victim to a hospital. (NTP, 1992) |
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| Freisetung ohne Brand | SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.STORAGE PRECAUTIONS: You should store this material under ambient temperatures. STORE AWAY FROM SOURCES OF IGNITION. (NTP, 1992) |
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| Isolation and Evacuation | Excerpt from ERG Guide 152 [Substances - Toxic (Combustible)]:IMMEDIATE PRECAUTIONARY MEASURE: Isolate spill or leak area in all directions for at least 50 meters (150 feet) for liquids and at least 25 meters (75 feet) for solids.SPILL: Increase the immediate precautionary measure distance, in the downwind direction, as necessary.FIRE: If tank, rail tank car or highway tank is involved in a fire, ISOLATE for 800 meters (1/2 mile) in all directionsalso, consider initial evacuation for 800 meters (1/2 mile) in all directions. (ERG, 2024) |
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| Personal Protective Equipment (PPE) | RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992) |
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| TSCA-Inventar-Status | TSCA listed |
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| UN-Transportnummer | 1665 |
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| Zollcode | 29042090 |
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| RTECS-Nr. | ZE4686600 |
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| R-Sätze (R) | 36/37-39/23/24/25 |
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| Toxizität | LD50 orl-rat: 2440 mg/kg 85JCAE -,420,86 |
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| Sicherheitshinweise (S) | 26-36/37/39-24/25 |
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| Gefahrenklasse | 6.1 |
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| Verpackungsgruppe | II |
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