HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Triphenylsilan
DK914 · DK021 · DKSI076 · NSC 12565 · Triphenysilane · triphenyl-silan · TRIPHENYLSILANE · Tri(phenyl)silicon
Identifikatoren & physikalische Daten
| CAS No. | 789-25-3 |
|---|---|
| Summenformel | C18H16Si |
| Durchschnittliche Molmasse | 260,4 g/mol |
| Monoisotopische Masse | 260,10212705 g/mol |
| SMILES | c1ccc([SiH](c2ccccc2)c2ccccc2)cc1 |
| InChIKey | AKQNYQDSIDKVJZ-UHFFFAOYSA-N |
| PubChem CID | 69922 |
| EC No. | 212-333-0 |
| DTXSID | DTXSID10883583 |
| Lokaler Name | Triphenylsilan |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 3 |
| Schwere Atome | 19 |
| Formalladung | 0 |
| Komplexität | 202 |
| Physical Description | Colorless solid[Aldrich MSDS] |
| Schmelzpunkt | 43-45 °C (lit.) |
| Siedepunkt | 152 °C/2 mmHg (lit.) |
| Brechungsindex | 1.6160 |
| Flammpunkt | 169 °F |
| Lagerbedingungen | Inert atmosphere,2-8°C |
| Löslichkeit | sol most organic solvents.REACTS |
| Aggregatzustand | Powder |
| Farbe | off-white |
| BRN | 978182 |
| InChI | 1S/C18H16Si/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15,19H |
| InChIKey | AKQNYQDSIDKVJZ-UHFFFAOYSA-N |
| SMILES | c1ccc(cc1)[SiH](c2ccccc2)c3ccccc3 |
| CAS Datenbank | 789-25-3(CAS DataBase Reference) |
| NIST chemische Informationen | Silane, triphenyl-(789-25-3) |
| EPA chemische Informationen | Silane, triphenyl- (789-25-3) |
Sicherheit & Vorschriften
| GHS-Einstufung | WarningH315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]H335 (95.6%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposureRespiratory tract irritation]P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website. |
|---|---|
| Regulatorische Informationen | Chemical: Silane, triphenyl-Triphenylsilane: Does not have an individual approval but may be used under an appropriate group standard |
| Gefahrenübersicht | CombustibleMay decompose in moist air or waterAn irritant[Aldrich MSDS] |
| Hazard Classes and Categories | Skin Irrit. 2 (100%)Eye Irrit. 2A (100%)STOT SE 3 (95.6%) |
| Wassergefährdungsklasse (WGK) | 1 |
| TSCA-Inventar-Status | TSCA listed |
| Zollcode | 29310095 |
| R-Sätze (R) | 36/37/38 |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26-37 |
| Lagerklasse | 11 - Combustible Solids |
| Gefahrenklasse | Eye Irrit. 2Skin Irrit. 2 |
Herstellung & Synthese
synthetische
Triphenylsilane can be synthesized by reducing phenylsilane (PhSiH3) with a reducing agent such as lithium aluminum hydride (LiAlH4). The overall reaction equation is as follows:3 PhSiH3 + 2 LiAlH4 → C18H16Si + 2 LiH + 2 AlH3This reaction is typically carried out in anhydrous conditions and under inert gas atmosphere.