Grundinformationen
- Standard-SMILES
c1ccc(Pc2ccccc2)cc1- InChIKey
GPAYUJZHTULNBE-UHFFFAOYSA-N- Summenformel
- C12H11P
- Durchschnittliche Molmasse
- 186,19 g/mol
- Monoisotopische Masse
- 186,05983698
Namen und Bezeichner
- Bevorzugter Name
- Diphenylphosphine
- IUPAC
- diphenylphosphane
- Lokaler Name
- Diphenylphosphin
- Englischer Name
- Diphenylphosphine
- Summenformel
- C12H11P
- Molmasse
- 186.19
Namen und Synonyme
Diphenylphosphine829-85-6Phosphine, diphenyl-F9B5T7O7ZYEINECS 212-591-4NSC-152123DIPHENYLPHOSPHINE [MI]DTXSID50232076NSC 152123RefChem:588939DTXCID50154567212-591-4
Weitere Namen anzeigen
Diphenylphosphin98% Ph2PHAURORA KA-1107Diphenyl phospinePHOSPHINE, DIPHENYLDPP/DIPHENYLPHOSPHIN
diphenylphosphaneHPPH2PH2PHMFCD00003040C12H11PUNII-F9B5T7O7ZYdiphenylphospinediphenyl-phosphane
Datenbank-Bezeichner
- CAS
829-85-6- PubChem CID
- 70017
- DTXSID
DTXSID50232076- UNII
- F9B5T7O7ZY
- EC Number
- 212-591-4
- Nikkaji
- J99.507J
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 3
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 0
- Frei drehbare Bindungen
- 2
- Schwere Atome
- 13
- Formalladung
- 0
- Komplexität
- 116
Experimentelle und physikochemische Eigenschaften
Chemical ClassesOther Classes -> Phosphorus Compounds
SpringerMaterials Properties31P nuclear magnetic resonance spectrum
Physical DescriptionClear liquid with strong unpleasant odor; [Merck Index] Clear light yellow liquid; [Sigma-Aldrich MSDS]
Physikochemische Eigenschaften
- Schmelzpunkt
- -14.5 °C · -14.5 °C
- Siedepunkt
- 280 °C · 280 °C(lit.)
- Dichte
- 1.07 g/mL · 1.07 g/mL at 25 °C(lit.)
- Dampfdruck
- 2 mm · 2 mm Hg ( 110 °C)
- Brechungsindex
- 20 · n20/D 1.625(lit.)
- Flammpunkt
- -18 °C · -18°C (Hexane)
- storage temp.
- 2 · 2-8°C
- Löslichkeit
- Chloroform
- pka
- 0.03 · diphenylphosphine is weakly basic. The pKa of the protonated derivative is 0.03.
- Aggregatzustand
- liquid
- Farbe
- colorless
- Wichte
- 0.68 · 0.68
- Wasserlöslichkeit
- Miscible with ethanol, ether, benzene, concentrated hydrochloric acid. Immiscible with water.
- BRN
- 742504 · 742504
- InChIKey
- GPAYUJZHTULNBE-UHFFFAOYSA-N
- CAS Datenbank
- 829 · 829-85-6(CAS DataBase Reference)
- NIST chemische Informationen
- Phosphine, diphenyl-(829-85-6)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H250 (100%): Catches fire spontaneously if exposed to air [Danger Pyrophoric liquids]
P210, P222, P231, P233, P261, P264, P264+P265, P271, P280, P302+P335+P334, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 50 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory InformationStatus: Active Update: 15-03-2021 https://echa.europa.eu/registration-dossier/-/registered-dossier/28173
Hazards SummaryPyrophoric and irritating; [Merck Index] Pyrophoric; Reacts violently with water; A skin and strong eye irritant; [Sigma-Aldrich MSDS] See Triphenylphosphine and Phenylphosphine.
Hazard Classes and CategoriesPyr. Liq. 1 (100%)
Sicherheitsdaten
- F
- 8-10-13-23
- wgk
- 3
- ridadr
- UN 2845 4.2/PG 1
- hs_code
- 29319090
- risk_code
- 17-36/37/38
- hazard_code
- F,Xi
- safety_code
- 26-36
- hazard_class
- 4.2
- packing_group
- I
Chemie und Industrie
Verwendung und Herstellung
UsesUsed as a reagent in synthetic organic chemistry; [Merck Index]
Anwendungen
VerwendenDiphenylphosphine is used in the synthesis of aminophosphines for application as catalysts. It is also used in the preparation of chiral palladacycles with N-heterocyclic carbene ligands as catalysts.
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