Grundinformationen
- Standard-SMILES
c1ccc(B(c2ccccc2)c2ccccc2)cc1- InChIKey
MXSVLWZRHLXFKH-UHFFFAOYSA-N- Summenformel
- C18H15B
- Durchschnittliche Molmasse
- 242,1 g/mol
- Monoisotopische Masse
- 242,12668088
Namen und Bezeichner
- Bevorzugter Name
- Triphenylborane
- IUPAC
- triphenylborane
- Lokaler Name
- Triphenylboran
- Englischer Name
- Triphenylborane
- Summenformel
- C18H15B
- Molmasse
- 242.12
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
960-71-4- PubChem CID
- 70400
- DTXSID
DTXSID6027345- ChEMBL
CHEMBL1876579- UNII
- 6282553L0G
- EC Number
- 213-504-2
- Nikkaji
- J121.102A
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 0 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 0
- Frei drehbare Bindungen
- 3
- Schwere Atome
- 19
- Formalladung
- 0
- Komplexität
- 202
Experimentelle und physikochemische Eigenschaften
Physikochemische Eigenschaften
- Schmelzpunkt
- 145 °C · 145 °C (lit.)
- Siedepunkt
- 203 °C/15 · 203 °C/15 mmHg (lit.)
- Dichte
- 0.898 g/mL · 0.898 g/mL at 25 °C
- Flammpunkt
- 1 °F · 1 °F
- storage temp.
- 2 · Storage temp. 2-8°C
- Aggregatzustand
- Powder
- Farbe
- off-white
- Wasserlöslichkeit
- Soluble in aromatic solvents. Insoluble in water.
- BRN
- 1961313 · 1961313
- InChI
- 1S/C18H15B/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
- InChIKey
- MXSVLWZRHLXFKH-UHFFFAOYSA-N
- SMILES
- c1ccc(cc1)B(c2ccccc2)c3ccccc3
- CAS Datenbank
- 960 · 960-71-4(CAS DataBase Reference)
- EPA chemische Informationen
- Borane, triphenyl- (960-71-4)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H228 (100%): Flammable solid [Danger Flammable solids]
P210, P240, P241, P280, and P370+P378 (click each P-code to see the statement)
Aggregated GHS information provided per 45 reports by companies from 4 notifications to the ECHA C&L Inventory.
Gefahrenhinweise
Regulatory Information
Chemical: Borane, triphenyl-
Borane, triphenyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Borane, triphenyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Borane, triphenyl-: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
Rapidly hydrolyzes; Shipped as the sodium hydroxide adduct in aqueous solution; Corrosive to skin and severely irritating to eyes in rabbits; Not a skin sensitizer in guinea pigs; [EPA ChAMP: Screening Level Hazard Characterization: Triphenylboron Category - 2009] Reproductive toxicity observed in oral study of rats at 10 mg/kg/day; One female failed to conceive, 5 of 9 mated females delivered, and the mean number of pups per litter was significantly reduced; Initial histopathology revealed adverse effects to semen; [EPA - TSCATS] Decomposed by water; A severe eye irritant that may cause eye injury; [Alfa Aesar MSDS] See Tri-n-butylborane.
Sicherheit und Schutzausrüstung
Protective Action Criteria (PAC)
0.59 [mg/m3]
6.5 [mg/m3]
39 [mg/m3]
Toxikologische Informationen
Adverse Effects
Reproductive Toxin - A chemical that is toxic to the reproductive system, including defects in the progeny and injury to male or female reproductive function. Reproductive toxicity includes developmental effects. See Guidelines for Reproductive Toxicity Risk Assessment.
Sicherheitsdaten
- F
- 10-23
- wgk
- 3
- tsca
- TSCA listed
- ridadr
- UN 1993 3/PG 2
- RTECS-Nr.
- ED2367500
- risk_code
- 11-36/37/38-22-19-40-36/37
- hazard_code
- F,Xn
- safety_code
- 16-26-33-36-24/25-22-36/37
- hazard_class
- 4.1
- packing_group
- III
- Speicherklasse
- 3 - Flammable liquids
- Hazard Classifications
- Acute Tox. 4 OralCarc. 2Eye Irrit. 2Flam. Liq. 2STOT SE 3
Chemie und Industrie
Verwendung und Herstellung
Uses
A monofunctional Lewis acid; Not currently commercially marketed; Possible applications include olefin polymerization, agrochemicals, metal scavenging, and consumer products (i.e. fuel additives and flame retardants); [EPA ChAMP: Screening Level Hazard Characterization: Triphenylboron Category - 2009]
Anwendungen
VerwendenTRIPHENYLBORANE is a type of Lewis acid used as catalyst and intermediate.
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