Tris(4-chlorphenyl)phosphin

Tris(4-chlorophenyl)phosphine

HCID 70874CAS 1159-54-2

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Grundinformationen

Standard-SMILES: Clc1ccc(P(c2ccc(Cl)cc2)c2ccc(Cl)cc2)cc1
InChIKey: IQKSLJOIKWOGIZ-UHFFFAOYSA-N
Summenformel: C18H12Cl3P
Durchschnittliche Molmasse: 365,6 g/mol
Monoisotopische Masse: 363,97422

Namen und Bezeichner

Bevorzugter Name: Tris(4-chlorophenyl)phosphine
IUPAC: tris(4-chlorophenyl)phosphane
Lokaler Name: Tris(4-chlorphenyl)phosphin
Englischer Name: Tris(4-chlorophenyl)phosphine
Summenformel: C18H12Cl3P
Molmasse: 365.62

Namen und Synonyme

Tris(4-chlorophenyl)phosphine1159-54-2Phosphine, tris(4-chlorophenyl)-Tris(p-chlorophenyl)phosphinetri(p-Chlorophenyl)phosphinetri-(4-Chlorophenyl)phosphinePhosphine, tris(p-chlorophenyl)-EINECS 214-596-7DTXSID30151216Phosphine, tris[4-chlorophenyl]-NSC 136459RefChem:192104

Weitere Namen anzeigen

Tri(p-chlorophenTris(4-chlorophenyl)TRI(4-CHLOROPHENYL)PHOSPHINERIS(4-CHLOROPHENYL)PHOSPHINETris(p-chlorophenyl)phosphane

DTXCID9073707214-596-7IQKSLJOIKWOGIZ-UHFFFAOYSA-Ntris(4-chlorophenyl)phosphaneMFCD00013639NSC136459DWG5LE6Q8XNSC-136459

Datenbank-Bezeichner

CAS: 1159-54-2
PubChem CID: 70874
DTXSID: DTXSID30151216
UNII: DWG5LE6Q8X
EC Number: 214-596-7
Nikkaji: J203.418B

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 6,5
Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 0
Frei drehbare Bindungen: 3
Schwere Atome: 22
Formalladung: 0
Komplexität: 275

Physikochemische Eigenschaften

Schmelzpunkt: 100 · 100-103 °C (lit.)
Siedepunkt: 427.6 · 427.6±40.0 °C(Predicted)
storage temp.: Inert atmosphere,Room Temperature
Aggregatzustand: crystal
Farbe: white
BRN: 751458 · 751458
InChI: 1S/C18H12Cl3P/c19-13-1-7-16(8-2-13)22(17-9-3-14(20)4-10-17)18-11-5-15(21)6-12-18/h1-12H
InChIKey: IQKSLJOIKWOGIZ-UHFFFAOYSA-N
SMILES: Clc1ccc(cc1)P(c2ccc(Cl)cc2)c3ccc(Cl)cc3
CAS Datenbank: 1159 · 1159-54-2(CAS DataBase Reference)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.8%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 46 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.8%)

Sicherheitsdaten

wgk: 3
tsca: No
ridadr: 3278
hs_code: 29310099
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-37/39
packing_group: III
Speicherklasse: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Anwendungen · 1 Eintrag

VerwendenCatalyst for:Preparation of chromans and (E,E)-1,3-dienes via reaction of γ-substituted allenoates with aldehydesSolvent-free Heck reactionsCocatalyst in:Regioselective carbomagnesiation of terminal alkynes and enynes with alkyl Grignard reagentsRhodium-catalyzed coordination-assisted regioselective alkenylation of aromatic C-H bonds with terminal silylacetylenesRhodium-catalyzed hydrogenation reactionsPlatinum-catalyzed allylation reactions