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o-Phenylenphosphorochloridit
o-Phenylene chlorophosphite · 2-chlorobenzo[d][1,3,2]dioxaphosphole · CATECHYL PHOSPHORUS CHLORIDE · O-PHENYLENE PHOSPHOROCHLORIDITE · 2-benzodioxaphosphole,2-chloro-3 · Pyrocatechol phosphoryl chloride · 1,2-Phenylene phosphorochloridite · 2-CHLORO-1,3,2-BENZODIOXAPHOSPHOLE
Identifikatoren & physikalische Daten
| CAS No. | 1641-40-3 |
|---|---|
| Summenformel | C6H4ClO2P |
| Durchschnittliche Molmasse | 174,52 g/mol |
| Monoisotopische Masse | 173,96374368 g/mol |
| SMILES | ClP1Oc2ccccc2O1 |
| InChIKey | YUJYEGDMJZHLMY-UHFFFAOYSA-N |
| PubChem CID | 74232 |
| EC No. | 216-690-3 |
| DTXSID | DTXSID3061843 |
| Lokaler Name | o-Phenylenphosphorochloridit |
Chemische & physikalische Eigenschaften
| XLogP | 2,5 |
|---|---|
| Polarare Oberfläche (TPSA) | 18,5 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 10 |
| Formalladung | 0 |
| Komplexität | 119 |
| SpringerMaterials Properties | Schoenflies notation |
| Schmelzpunkt | 30-35 °C(lit.) |
| Siedepunkt | 80 °C20 mm Hg(lit.) |
| Dichte | 1.466 g/mL at 25 °C(lit.) |
| Brechungsindex | n20/D 1.571(lit.) |
| Flammpunkt | >230 °F |
| Lagerbedingungen | 0-6°C |
| Löslichkeit | Benzene (Slightly), Chloroform (Slightly) |
| Aggregatzustand | solid |
| BRN | 135455 |
| Stabilität | Moisture Sensitive |
| InChI | 1S/C6H4ClO2P/c7-10-8-5-3-1-2-4-6(5)9-10/h1-4H |
| InChIKey | YUJYEGDMJZHLMY-UHFFFAOYSA-N |
| SMILES | ClP1Oc2ccccc2O1 |
| CAS Datenbank | 1641-40-3(CAS DataBase Reference) |
| EPA chemische Informationen | 1,3,2-Benzodioxaphosphole, 2-chloro- (1641-40-3) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 43 reports by companies from 2 notifications to the ECHA C&L Inventory. |
|---|---|
| Regulatorische Informationen | Chemical: 1,3,2-Benzodioxaphosphole, 2-chloro- |
| Weitere Sicherheitsinformationen | Evaluation - Chemicals not considered for in depth evaluation - Not commercially active in Australia |
| Hazard Classes and Categories | Skin Corr. 1B (100%) |
| F | 10-21 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 3261 8/PG 2 |
| R-Sätze (R) | 34 |
| Gefahrensymbole | C |
| Sicherheitshinweise (S) | 26-36/37/39-45 |
| Gefahrenklasse | 8Skin Corr. 1B |
| Verpackungsgruppe | II |
| Lagerklasse | 8A - Combustible corrosive hazardous materials |
Anwendungen & Verwendung
Verwenden
Highly reactive cyclic phosphitylating reagent which provides fast coupling rates, and hydrolytic cleavage occurs more readily than with acyclic analogs