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Phenylquecksilberhydroxid

Phenylmercuric hydroxide

HCID 7512
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Grundinformationen

CAS
100-57-2
Standard-SMILES
O.[Hg][c]1ccccc1
InChIKey
MSYUMXXVCSLXMR-UHFFFAOYSA-N
Summenformel
C6H7HgO
Durchschnittliche Molmasse
295,71 g/mol
Monoisotopische Masse
297,020333

Überblick

Phenylmercuric hydroxide appears as a fine white to cream crystalline solid. Toxic by ingestion, inhalation or skin absorption. Denser than water.

Namen und Bezeichner

Bevorzugter Name
Phenylmercuric hydroxide
IUPAC
phenylmercury;hydrate
Lokaler Name
Phenylquecksilberhydroxid
Englischer Name
Hydroxyphenylmercury
Summenformel
C6H6HgO
Molmasse
294.7

Namen und Synonyme

PHENYLMERCURIC HYDROXIDEHydroxyphenylmercury100-57-2Phenylmercury hydroxideMersolite 1Mercury, hydroxyphenyl-Phenyl hydroxymercuryCaswell No. 657CNSC 4773EINECS 202-866-7UN1894EPA Pesticide Chemical Code 066011
Weitere Namen anzeigen
mersolite1phenylhydroxymercuryhydroxyphenyl-mercurphenylmercury hydrate(HYDROXYMERCURI)BENZENEHydroxyphenylmercury(II)PHENYL MERCURIC HYDROXIDE
BRN 0636144Y38LBL8A8GDTXSID8059213NSC-4773Mercury, hydroxyphenylRefChem:861760DTXCID9032454202-866-7

Datenbank-Bezeichner

CAS
100-57-2
PubChem CID
7512
DTXSID
DTXSID8059213
EC Number
202-866-7

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
1 Ų
H-Brücken-Donoren
1
H-Brücken-Akzeptoren
1
Frei drehbare Bindungen
1
Schwere Atome
8
Formalladung
0
Komplexität
50,5

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Organic Compounds
Vapor Pressure0.0000832 [mmHg]
Physical Description · 2 Einträge

Phenylmercuric hydroxide appears as a fine white to cream crystalline solid. Toxic by ingestion, inhalation or skin absorption. Denser than water.

White to cream-colored solid; [Hawley] Sparingly soluble in water; [Ullmann]

Physikochemische Eigenschaften

Schmelzpunkt
235.5 °C · 235.5°C
Siedepunkt
126.5 °C · 126.5°C
storage temp.
30 °C · Store below +30°C.
Löslichkeit
50 g/l · 50g/l
Aggregatzustand
solid
Farbe
White
Wasserlöslichkeit
50 g/L · 50g/L
Stabilität
Stable. Incompatible with strong acids, strong oxidizing agents.
InChI
1S/C6H5.Hg.H2O/c1-2-4-6-5-3-1;;/h1-5H;;1H2

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P260, P264, P270, P273, P280, P301+P316, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P319, P321, P330, P363, P391, P405, and P501 (click each P-code to see the statement)

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P264, P270, P273, P280, P301+P316, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P319, P321, P330, P363, P391, P405, and P501 (click each P-code to see the statement)

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Mercury, hydroxyphenyl-

Phenylmercury hydroxide: HSNO Approval: HSR004634 Approved with controls

DOT LabelPoison
Fire Hazards · 2 Einträge

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2 Einträge

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.

Hazards SummaryCauses burns; [eChemPortal: ESIS] May be fatal by inhalation, skin absorption, or ingestion; May cause irritation; Targets nerves; [MSDSonline] See Mercury, aryl compounds and linked occupational diseases.
DOT ID and Guide1894 151

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used to make phenylmercuric salts and organic mercury derivatives; Also used as a fungicide, germicide, and to denature alcohol; [Hawley] Banned in the EU for use as pesticide for plant protection; Severely restricted for use as other pesticide including biocide; [eChemPortal: ESIS] Used to make fungicides and disinfectants; Used as a preservative in cosmetics--German laws permit a concentration of 0.007%; [Ullmann]

Using Disinfectants or Biocides [Category: Clean]

General Manufacturing InformationMercury, hydroxyphenyl-: ACTIVE

Anbieter7 Anbieter

武汉易泰科技有限公司上海分公司18930552037 · [email protected]
南通合润生物科技有限公司18362409333 · [email protected]
天津荣燊化工有限公司18317763565; 18317763565 · [email protected]
泰安市嘉叶生物科技有限公司15318151873;13127280945 · [email protected]
爆牛贸易重庆有限公司+86-023-6139-8061 +86-86-13650506873 · [email protected]
上海宝杨宝欣生物科技有限公司021-56698539 19921169802 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-15350571055 · [email protected]

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InChIKey
MSYUMXXVCSLXMR-UHFFFAOYSA-N
EPA chemische Informationen
Phenylmercuric hydroxide (100-57-2)
Reactive Group
Bases, Strong
Reactivity Profile · 1 Eintrag

Bases or alkalis are chemically similar to sodium hydroxide (NaOH) or sodium oxide (Na2O). They neutralize acids exothermically to form salts plus water. When soluble in water they give solutions having a pH greater than 7.0. Mixing these materials with water can generate troublesome amounts of heat as the base is dissolved or diluted. Bases react with certain metals (such as aluminum and zinc) to form oxides or hydroxides of the metal and generate gaseous hydrogen. Bases may initiate polymerization reactions in polymerizable organic compounds, especially epoxides). They may generate flammable and/or toxic gases with ammonium salts, nitrides, halogenated organics, various metals, peroxides, and hydroperoxides. Materials of this group often serve as catalysts.

DOT Hazard Classification · 6 Einträge

Phenylmercuric hydroxide

Severe marine pollutant

Phenylmercuric hydroxide

UN1894

Div 6.1 Poisonous materials (49 eCFR § 173.132)

PG II: the degree of danger presented by the material is medium

Air and Water ReactionsSlightly soluble in water.
Hazard Classes and Categories · 3 Einträge

Acute Tox. 3 (100%)

Acute toxicity - category 3

Acute Tox. 3 *

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Accidental Release Measures · 2 Einträge

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

First Aid · 2 Einträge

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

General First Aid:

Exposure Control and Personal Protection· Wear positive pressure self-contained breathing apparatus (SCBA).
Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Isolation and Evacuation · 2 Einträge

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

Immediate precautionary measure

Threshold Limit Values (TLV)0.1 [mg/m3], as Hg
Permissible Exposure Limit (PEL)0.1 [mg/m3], as Hg
Personal Protective Equipment (PPE)Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Emergency Response Planning GuidelinesSmall Fire
Immediately Dangerous to Life or Health (IDLH)10.0 [mg/m3], as Hg

Toxikologische Informationen

Adverse EffectsNeurotoxin - Sensorimotor

Sicherheitsdaten

wgk
WGK 3 highly water endangering
tsca
TSCA listed
ridadr
UN 1894
hs_code
2852 10 00
RTECS-Nr.
OW4940000
risk_code
26/27/28-33-50/53-48/24/25-34-25
hazard_code
T+,N,T
safety_code
13-28-36-45-60-61-37-24/25-23
hazard_class
6.1
packing_group
II
Speicherklasse
6.1B - Non-combustible, acute toxic Cat. 1 and 2very toxic hazardous materials
Hazard Classifications
Acute Tox. 3 OralAquatic Acute 1Aquatic Chronic 1Eye Dam. 1Skin Corr. 1BSTOT RE 1