N-Methylcyclohexylamine (HCID 7514)

Überblick

Methyl cyclohexylamine appears as a water-white liquid. Slightly soluble in water and floats on water. A strong irritant to skin and eyes. Corrosive. Used as a solvent.

Namen und Bezeichner

Bevorzugter Name: N-Methylcyclohexylamine
IUPAC: N-methylcyclohexanamine
Lokaler Name: Cyclohexyl(methyl)amin
Englischer Name: N-Methylcyclohexylamine
Summenformel: C7H15N
Molmasse: 113.2

Namen und Synonyme

N-METHYLCYCLOHEXYLAMINEN-Methylcyclohexanamine100-60-7MethylcyclohexylamineCyclohexanamine, N-methyl-CyclohexylmethylamineCyclohexyl(methyl)amineNSC 434UNII-YH8PF4C1OWYH8PF4C1OWEINECS 202-869-3BRN 1523664

Weitere Namen anzeigen

1-MethylcyclohexylamineAKOS BBS-00004304TIMTEC-BB SBB004314N-METHYCYCLOHEXYLAMINEMETHYLAMINOCYCLOHEXANEBromhexine Impurity 35N-CYCLOHEXYLMETHYLAMINE

N-MetyhcyclohexylamineAI3-16733NSC-434DTXSID3059216CHEBI:590184-12-00-00017 (Beilstein Handbook Reference)methyl cyclohexylamineRefChem:163815

Datenbank-Bezeichner

CAS: 100-60-7
PubChem CID: 7514
DTXSID: DTXSID3059216
ChEBI: CHEBI:59018
UNII: YH8PF4C1OW
EC Number: 202-869-3
Nikkaji: J23.469I

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 1,6
Polarare Oberfläche (TPSA): 12 Å²
H-Brücken-Donoren: 1
H-Brücken-Akzeptoren: 1
Frei drehbare Bindungen: 1
Schwere Atome: 8
Formalladung: 0
Komplexität: 55,4

Experimentelle und physikochemische Eigenschaften

SpringerMaterials PropertiesOptical coefficient

Physical DescriptionMethyl cyclohexylamine appears as a water-white liquid. Slightly soluble in water and floats on water. A strong irritant to skin and eyes. Corrosive. Used as a solvent.

Physikochemische Eigenschaften

Schmelzpunkt: -9 · -9--7 °C (lit.)
Siedepunkt: 149 °C · 149 °C (lit.)
Dichte: 0.868 g/mL · 0.868 g/mL at 25 °C (lit.)
Dampfdichte: 4 · 4 (vs air)
Dampfdruck: 11 mm · 11 mm Hg ( 40 °C)
Brechungsindex: 20 · n20/D 1.456(lit.)
Flammpunkt: 85 °F · 85 °F
storage temp.: Keep in dark place,Inert atmosphere,Room temperature
Löslichkeit: 54 g/l · 54g/l
Aggregatzustand: Liquid
pka: 11.03 · 11.03±0.20(Predicted)
Wichte: 0.855 · 0.855 (20/4℃)
Farbe: Clear colorless to yellow
PH: 12 · 12 (10g/l, H2O, 20℃)
Explosionsgrenze: 2.2 · 2.2-10.5%(V)
Wasserlöslichkeit: 5.4 g/100 · 5.4 g/100 mL (20 ºC)
BRN: 1523664 · 1523664
Dielectric constant: 3.64 · 3.6400000000000001
InChI: 1S/C7H15N/c1-8-7-5-3-2-4-6-7/h7-8H,2-6H2,1H3
InChIKey: XTUVJUMINZSXGF-UHFFFAOYSA-N
SMILES: CNC1CCCCC1
CAS Datenbank: 100 · 100-60-7(CAS DataBase Reference)
NIST chemische Informationen: Cyclohexanamine, N-methyl-(100-60-7)
EPA chemische Informationen: Cyclohexanamine, N-methyl- (100-60-7)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H226 (99.5%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P234, P240, P241, P242, P243, P260, P261, P262, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P362+P364, P363, P370+P378, P390, P403+P233, P403+P235, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 218 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Cyclohexanamine, N-methyl-

Status: Active Update: 13-01-2016 https://echa.europa.eu/registration-dossier/-/registered-dossier/17035

Cyclohexyl(methyl)amine: Does not have an individual approval but may be used under an appropriate group standard

DOT LabelFlammable Liquid Corrosive

Fire HazardsExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Health HazardsExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Reactive GroupAmines, Phosphines, and Pyridines

Reactivity AlertsHighly Flammable

Sicherheit und Schutzausrüstung

Fire FightingExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

First AidExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Nonfire Spill ResponseExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Isolation and EvacuationExcerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Personal Protective Equipment (PPE)Excerpt from ERG Guide 132 [Flammable Liquids - Corrosive]:

Toxikologische Informationen

EPA Provisional Peer-Reviewed Toxicity Values · 3 Einträge

n-Methylcyclohexylamine

PDF Document

2011

Sicherheitsdaten

wgk: 1
tsca: TSCA listed
ridadr: UN 2734 8/PG 2
hs_code: 29213099
RTECS-Nr.: GX1529000
risk_code: 10-21/22-35-20/21/22
hazard_code: C
hazard_note: Corrosive
safety_code: 16-26-36/37/39-45
hazard_class: 8
packing_group: II
Speicherklasse: 3 - Flammable liquids
Hazard Classifications: Acute Tox. 3 DermalAcute Tox. 4 OralAquatic Chronic 3Eye Dam. 1Flam. Liq. 3Met. Corr. 1Skin Corr. 1A

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationCyclohexanamine, N-methyl-: ACTIVE

Anwendungen

VerwendenIntermediate, solvent, acid acceptor.

VerwendenN-Methylcyclohexylamine is used as a component of vulcanization accelerators, but the market size is relatively small.

Darstellung · 1 Eintrag

synthetischeN-Methylcyclohexylamine can be prepared by a procedure similar to that used for cyclohexylamine, i.e., by hydrogenation of methylaniline over a supported nickel catalyst or from cyclohexanone and methylamine under hydrogenation conditions. Cyclohexylamine reacts with methanol over copper, zinc, or copper – calcium catalysts.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Quecksilberdichlorid Aluminium Cyclohexylamin Cyclohexanon Methanimidamide, N,N'-dicyclohexyl-N,N-Dimethylcyclohexanamin Guanidine,N,N',N''-tricyclohexyl-tert-Butyl N-cyclohexylcarbaMate Cyclohexylisocyanid (Chlormethyl)triethoxysilan Methylammoniumchlorid N-Methylmethanamin, gasförmig

Nachgelagerte Produkte

Bromhexinhydrochlorid 2-Amino-N-cyclohexyl-N-methylbenzylamin 4-Chloro-N-cyclohexyl-N-MethylbutyraMide, 97%

Anbieter50 Anbieter

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

郑州阿尔法化工有限公司+86-18530059196 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

南京迪恩赛尔生物科技有限公司19951952469 · [email protected]

Ergänzende Hinweise

DefinitionChEBI: A secondary aliphatic amine having methyl and cyclohexyl as the two alkyl groups.

Zugehörige Reaktionen

218

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HRID 9664als Eduktuspto-grants-2006_08

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HRID 90956als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)

HRID 91843als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)

HRID 117075als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)

HRID 117190als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)

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