Tris(diethylamino)phosphin

Hexaethylphosphorous triamide

HCID 75292CAS 2283-11-6

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Grundinformationen

Standard-SMILES: CCN(CC)P(N(CC)CC)N(CC)CC
InChIKey: FDIOSTIIZGWENY-UHFFFAOYSA-N
Summenformel: C12H30N3P
Durchschnittliche Molmasse: 247,36 g/mol
Monoisotopische Masse: 247,21773459

Überblick

structure given in first source

Namen und Bezeichner

Bevorzugter Name: Hexaethylphosphorous triamide
IUPAC: N-[bis(diethylamino)phosphanyl]-N-ethylethanamine
Lokaler Name: Tris(diethylamino)phosphin
Englischer Name: Tris(diethylamino)phosphine
Summenformel: C12H30N3P
Molmasse: 247.36

Namen und Synonyme

Tris(diethylamino)phosphine2283-11-6Hexaethylphosphorous triamidePhosphorous triamide, hexaethyl-WPC83R9HNCDTXSID4062305Phosphorous triamide, N,N,N',N',N'',N''-hexaethyl-RefChem:900283DTXCID0036760218-920-8Hexaethyl phosphorous triamideN,N,N',N',N'',N''-Hexaethylphosphinetriamine

Weitere Namen anzeigen

P(N(C2H5)2)3HexaethyLphosphorous triamideHexaethylphosphinetriamineHEXAETHYLPHOSPHORUS TRIAMIDEAURORA KA-1249

N-[bis(diethylamino)phosphanyl]-N-ethylethanamineMFCD00009041Tris(N,N-diethylamino)phosphineN,N,N',N',N'',N''-hexaethylphosphorous triamideHexaethyltriamidophosphiteHexaethyltriaminophosphineTris(diethylamido)phosphinePhosphorous acid tris(diethylamide)

Datenbank-Bezeichner

CAS: 2283-11-6
PubChem CID: 75292
DTXSID: DTXSID4062305
UNII: WPC83R9HNC
EC Number: 218-920-8
Nikkaji: J21.143E

Eigenschaften

Berechnete Struktureigenschaften

XLogP: 2,8
Polarare Oberfläche (TPSA): 9,7 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 3
Frei drehbare Bindungen: 9
Schwere Atome: 16
Formalladung: 0
Komplexität: 126

Experimentelle und physikochemische Eigenschaften

SpringerMaterials Properties15N nuclear magnetic resonance spectrum

Physikochemische Eigenschaften

Schmelzpunkt: 230 · 230-232 °C
Siedepunkt: 80 · 80-90 °C10 mm Hg(lit.)
Dichte: 0.903 g/mL · 0.903 g/mL at 25 °C(lit.)
Brechungsindex: 20 · n20/D 1.475(lit.)
Flammpunkt: 58 °C · 58 °C
storage temp.: 30 °C · Store below +30°C.
pka: 9.74 · 9.74±0.70(Predicted)
Aggregatzustand: Liquid
Wichte: 0.903 · 0.903
Farbe: Clear colorless to yellow-orange
Wasserlöslichkeit: Insoluble in water.
BRN: 636187 · 636187
InChI: 1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3
InChIKey: FDIOSTIIZGWENY-UHFFFAOYSA-N
SMILES: CCN(CC)P(N(CC)CC)N(CC)CC
CAS Datenbank: 2283 · 2283-11-6(CAS DataBase Reference)
EPA chemische Informationen: Phosphorous triamide, hexaethyl- (2283-11-6)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 47 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory InformationHexaethyltriaminophosphine: Does not have an individual approval but may be used under an appropriate group standard

Hazard Classes and CategoriesFlam. Liq. 3 (100%)

Sicherheitsdaten

F: 10-23
wgk: 3
tsca: TSCA listed
ridadr: UN 1993 3/PG 3
hs_code: 29319090
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36
hazard_class: 3
packing_group: III
Speicherklasse: 3 - Flammable liquids
Hazard Classifications: Eye Irrit. 2Flam. Liq. 3Skin Irrit. 2STOT SE 3

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationPhosphorous triamide, N,N,N',N',N'',N''-hexaethyl-: ACTIVE

Anwendungen · 1 Eintrag

VerwendenTris(diethylamino)phosphine [(Et2N)3P] can be used as a reagent to synthesize: 1,1′-Dialkylisoindigo derivatives by reacting with various 1-alkylisatins via deoxygenation reaction.1-Aminomethylisatins by treating with isatin and primary and secondary amines.It can also be used in the deoxygenation of some cyclic α-diketones using fullerene C60.