HuagongsheHuagongshe Chemie-Druckbericht · Nur für Forschungszwecke
Magnesium, chloroethyl-
ethylmagnesium chloride solution · Chlorethylmagnesium · chloroethylmagnesium · chloroethyl-magnesiu · Ethylchloromagnesium · EthylMagnesiuM Chlorid · ETHYLMAGNESIUM CHLORIDE · Magnesium, chloroethyl-
Identifikatoren & physikalische Daten
| CAS No. | 2386-64-3 |
|---|---|
| Summenformel | C2.H5.Cl.Mg |
| Durchschnittliche Molmasse | 88,82 g/mol |
| SMILES | [CH2-]C.[Cl-].[Mg+2] |
| InChIKey | ZWNJJACKPNTXHY-UHFFFAOYSA-M |
| PubChem CID | 75432 |
| ChEBI | CHEBI:51239 |
| EC No. | 219-206-9 |
| DTXSID | DTXSID40883839 |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 0 |
| Schwere Atome | 4 |
| Formalladung | 0 |
| Komplexität | 6 |
| Dichte | 0.978 @25 °C1.00 g/mL at 20 °C |
| Siedepunkt | 66℃ |
| Flammpunkt | 1 °F |
| Lagerbedingungen | water-free area |
| Aggregatzustand | Solution |
| Farbe | Yellow to dark brown |
| Löslichkeit | reacts |
| BRN | 3647886 |
| InChI | InChI=1S/C2H5.ClH.Mg/c1-2/h1H2,2H3/q+1/p-1 |
| InChIKey | ZWNJJACKPNTXHY-UHFFFAOYSA-M |
| SMILES | C(C)[Mg]Cl |
| CAS Datenbank | 2386-64-3(CAS DataBase Reference) |
| EPA chemische Informationen | Magnesium, chloroethyl- (2386-64-3) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH225 (60.4%): Highly Flammable liquid and vapor [Danger Flammable liquids]P210, P223, P231+P232, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 111 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | REACH registered substance: Chloroethylmagnesium (EC: 219-206-9)Magnesium, chloroethyl-: Does not have an individual approval but may be used under an appropriate group standard |
| Hazard Classes and Categories | Flam. Liq. 2 (60.4%) |
| Protective Action Criteria (PAC) | 1.2 [mg/m3]13 [mg/m3]79 [mg/m3] |
| F | 1-3-10 |
| Wassergefährdungsklasse (WGK) | 1 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 3399 4.3/PG 1 |
| Zollcode | 29319090 |
| R-Sätze (R) | 12-14-20/21/22-34-40-14/15-11-22-19-67-37 |
| Gefahrensymbole | F+,C,F |
| Sicherheitshinweise (S) | 26-30-36/37/39-43-45-7/8-33-16-6A-43A-24/25 |
| Gefahrenklasse | 4.3Acute Tox. 4 OralEye Dam. 1Flam. Liq. 2Skin Corr. 1BSTOT SE 3Water-react 1 |
| Verpackungsgruppe | II |
| Lagerklasse | 4.3 - Hazardous materials which set free flammable gases upon contact with water |
Anwendungen & Verwendung
Verwenden
Ethylmagnesium chloride solution can be used: In Cp2ZrCl2 catalyzed ethylcarboxylation of alkenes using carbon dioxide to corresponding carboxylic acids. In the preparation of cyclobutylmagnesium carbenoids by reacting with 1-chlorocyclobutyl p-tolyl sulfoxides.