3,7-Dinitroso-1,3,5,7-tetraazabi-cyclo(3.3.1)nonan
Dinitrosopentamethylenetetramine
Grundinformationen
- CAS
101-25-7- Standard-SMILES
O=NN1CN2CN(C1)CN(N=O)C2- InChIKey
MWRWFPQBGSZWNV-UHFFFAOYSA-N- Summenformel
- C5H10N6O2
- Durchschnittliche Molmasse
- 186,17 g/mol
- Monoisotopische Masse
- 186,08652358
Überblick
Flammable explosive solid.
Namen und Bezeichner
- Bevorzugter Name
- Dinitrosopentamethylenetetramine
- IUPAC
- 3,7-dinitroso-1,3,5,7-tetrazabicyclo[3.3.1]nonane
- Lokaler Name
- 3,7-Dinitroso-1,3,5,7-tetraazabi-cyclo(3.3.1)nonan
- Englischer Name
- N,N'-DINITROSOPENTAMETHYLENETETRAMINE
- Summenformel
- C5H10N6O2
- Molmasse
- 186.17
Namen und Synonyme
101-25-7DINITROSOPENTAMETHYLENETETRAMINEDipentaxMicroporDnpmtOpexMikrofor NPorophor BN,N-DinitrosopentamethylenetetramineVulcacel BNUnicel-NDUnicel NDX
Weitere Namen anzeigen
DPMTAdnpmPU 55opex80opex93PTs 55
Porofor DNO/FPorofor chkhc-18Aceto DNPT 100Vulcacel B-40DNMPTDNPTKhempor N 90N,N'-Dinitrosopentamethylenetetramine
Datenbank-Bezeichner
- CAS
101-25-7- PubChem CID
- 7549
- DTXSID
DTXSID5020526- ChEBI
CHEBI:82457- UNII
- O35M5QNM4Q
- EC Number
- 202-928-3
- Nikkaji
- J1.179G
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 0,3
- Polarare Oberfläche (TPSA)
- 71,8 Ų
- H-Brücken-Donoren
- 0
- H-Brücken-Akzeptoren
- 8
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 13
- Formalladung
- 0
- Komplexität
- 189
Experimentelle und physikochemische Eigenschaften
Chemical ClassesNitrogen Compounds -> Nitrosamines
Color/Form
LIGHT CREAM-COLORED POWDER
LIGHT-YELLOW NEEDLES
Solubility
SOL IN DIMETHYL FORMAMIDE; SOMEWHAT SOL IN PYRIDINE
SOMEWHAT SOL IN METHYL ETHYL KETONE & ACETONITRILE
SLIGHTLY SOL IN WATER (ABOUT 1%), METHANOL, ETHANOL
SLIGHTLY SOL IN BENZENE, ETHER, ACETONE
READILY SOL DIMETHYL SULFOXIDE
Physical Description
Flammable explosive solid.
Dry Powder
Cream-colored solid; [Hawley] Off-white powder; [MSDSonline]
Stability/Shelf LifeHYDROLYZES IN PRESENCE OF DILUTE HYDROCHLORIC ACID @ 100 °C
Physikochemische Eigenschaften
- Schmelzpunkt
- 207 °C · 207°C
- Siedepunkt
- 320.65 °C · 320.65°C (rough estimate)
- Dichte
Sicherheit und Regulatorisches
Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.
GHS-Klassifizierung
GHS Classification
Danger
H228 (81.6%): Flammable solid [Danger Flammable solids]
P210, P234, P235, P240, P241, P261, P264, P264+P265, P270, P271, P272, P280, P301+P317, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P330, P333+P317, P337+P317, P362+P364, P370+P378, P403, P403+P233, P405, P410, P411, P420, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 76 reports by companies from 10 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Danger
H242: Heating may cause a fire [Danger Self-reactive substances and mixtures; Organic peroxides]
Gefahrenhinweise
Regulatory Information
Chemical: 1,3,5,7-Tetraazabicyclo[3.3.1]nonane, 3,7-dinitroso-
1,3,5,7-Tetraazabicyclo[3.3.1]nonane, 3,7-dinitroso- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of 1,3,5,7-Tetraazabicyclo[3.3.1]nonane, 3,7-dinitroso- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: 3,7-dinitroso-1,3,5,7-tetraazabicyclo[3.3.1]nonane (EC: 202-928-3)
Dinitrosopentamethylenetetramine: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelFlammable Solid
Fire HazardsExcerpt from ERG Guide 149 [Substances (Self-Reactive)]:
Fire Potential...MODERATE FIRE RISK.
Health HazardsExcerpt from ERG Guide 149 [Substances (Self-Reactive)]:
Chemie und Industrie
Verwendung und Herstellung
Uses
Used as a blowing agent (rubber and plastics); [Hawley]
BLOWING AGENT FOR NATURAL & SYNTHETIC UNICELLULAR RUBBER, POLYVINYL CHLORIDE PLASTISOLS, FOR EPOXY, POLYESTER & SILICONE RESINS
U.S. Exports
(1977) No Data
(1979) No Data
U.S. Imports
(1977) No Data
(1979) No Data
U.S. Production
2023: <50,000 lb
(1977) PROBABLY GREATER THAN 2.27X10+6 GRAMS
(1979) PROBABLY GREATER THAN 2.27X10+6 GRAMS
Industry UsesPropellants, non-motive (blowing agents)
Methods of ManufacturingADDITION OF ACID (EG, HYDROCHLORIC) TO A COLD, MIXED SOLUTION OF HEXAMETHYLENETETRAMINE AND SODIUM NITRITE
Formulations/Preparations...AVAILABLE IN US AS FREE-FLOWING POWD IN GRADES CONTAINING 99%, 93%, 80% & 42% ACTIVE INGREDIENT. INERT COMPONENTS OF BLENDED PRODUCTS ARE INORGANIC DILUENTS (EG, SILICA, CLAY), PROCESSING AIDS &/OR STABILIZERS...
General Manufacturing Information
Synthetic Rubber Manufacturing
1,3,5,7-Tetraazabicyclo[3.3.1]nonane, 3,7-dinitroso-: ACTIVE
/DINITROSOPENTAMETHYLENETETRAMINE/...PRODUCED IN JAPAN HAS FOLLOWING SPECIFICATIONS: PURITY, GREATER THAN 98%; WATER, LESS THAN 0.1%, DECOMP TEMP, 200-205 °C; QUANTITY OF GAS GENERATED (0 °C, 1 ATMOSPHERE), 240 ML/G.
...USED AS NITROGEN-RELEASING CHEM BLOWING AGENT FOR PREPN OF NATURAL & SYNTH UNICELLULAR RUBBER, WHICH IS USED MAINLY IN CARPET UNDERLAY, AUTOMOBILE & BUILDING WEATHER STRIPPING, THERMAL INSULATION MATERIAL, SHOE LININGS, CUSHIONING & FLOTATION PRODUCTS.
...EFFECTIVE BLOWING AGENT FOR EXPANSION OF POLYVINYL CHLORIDE PLASTISOLS & EPOXY, POLYESTER & SILICONE RESINS.
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