Tricyclohexylphosphin

Tricyclohexylphosphine

HCID 75806CAS 2622-14-2

Grundinformationen

Standard-SMILES
C1CCC(P(C2CCCCC2)C2CCCCC2)CC1
InChIKey
WLPUWLXVBWGYMZ-UHFFFAOYSA-N
Summenformel
C18H33P
Durchschnittliche Molmasse
280,4 g/mol
Monoisotopische Masse
280,23198769

Namen und Bezeichner

Bevorzugter Name
Tricyclohexylphosphine
IUPAC
tricyclohexylphosphane
Lokaler Name
Tricyclohexylphosphin
Englischer Name
Tricyclohexyl phosphine
Summenformel
C18H33P
Molmasse
280.43

Namen und Synonyme

TricyclohexylphosphinePhosphine, tricyclohexyl-EINECS 220-069-2NSC 158657DTXSID9062562Phosphine, tricyclohexylRefChem:191427DTXCID8037469220-069-2WLPUWLXVBWGYMZ-UHFFFAOYSA-N2622-14-2TRICYCLOHEXYL PHOSPHINE
Weitere Namen anzeigen
TCHPP(4-MeOC6H4)3TricycLProtein TCHPtricyclohexylphospine
TricyclohexylphosphanePCy3Tricyclohexyl-phosphaneMFCD00003853tris(cyclohexyl)phosphineP(Cy)3Cy3PP(cHex)3

Datenbank-Bezeichner

CAS
2622-14-2
PubChem CID
75806
DTXSID
DTXSID9062562
UNII
34HJS55VCG
EC Number
220-069-2
Nikkaji
J87.295D

Eigenschaften

Berechnete Struktureigenschaften

XLogP
5,4
Polarare Oberfläche (TPSA)
0 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
0
Frei drehbare Bindungen
3
Schwere Atome
19

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Classes -> Phosphorus Compounds
Physical DescriptionCrystalline powder or chunks; [Sigma-Aldrich MSDS]

Physikochemische Eigenschaften

Schmelzpunkt
81 · 81-83 °C (lit.)
Siedepunkt
383.4 · 383.4±9.0 °C | Condition: Press: 760 Torr
Dichte
0.909 g/mL · 0.909 g/mL at 25 °C
Flammpunkt
48 °F · 48 °F
storage temp.
2 · Inert atmosphere,2-8°C
Löslichkeit
Chloroform (Slightly), DMSO (Slightly, Heated, Sonicaetd), Ethyl Acetate (Slightly)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H251 (18.7%): Self-heating; may catch fire [Danger Self-heating substances and mixtures]

P235, P261, P264, P264+P265, P270, P271, P273, P280, P301+P316, P301+P317, P302+P352, P304+P340, P305+P351+P338, P319, P321, P330, P332+P317, P337+P317, P362+P364, P391, P403+P233, P405, P407, P410, P413, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 91 reports by companies from 14 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Hazards SummaryA skin and strong eye irritant; [Sigma-Aldrich MSDS] See Triphenylphosphine.
Hazard Classes and CategoriesSelf-heat. 1 (18.7%)

Sicherheitsdaten

wgk
3
tsca
TSCA listed
ridadr
UN 2056 3/PG 2
hs_code
29319090
risk_code
36/37/38-22-37/38-36-19-11-67-65-63-48/20-40
hazard_code
Xi,Xn,F

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationPhosphine, tricyclohexyl-: ACTIVE
Anwendungen · 1 Eintrag

VerwendenTricyclohexyl Phosphine is a ligand catalyst used primarily in organometallic chemistry. Ligand used in the Pd-catalyzed coupling of malononitrile with aryl halides. suzuki reaction: Bulky phosphine ligand used with a Pd(0)-triolefinic macrocycle catalyst for Suzuki coupling of aryl bromides and chlorides. This ligand is applied with Ni as a key intermediate in the formation of cylcopentane compounds. As a reagent, Tricyclohexylphosphine is used for a range of metal-catalyzed organic transformations. Crabtree's catalyst is an organoiridium compound containing tricyclohexyl phosphine used for hydrogenation of mono-, di-, tri-, and tetra- substituted substrates and hydrogen transfer reactions. Grubbs' catalysts consists of transition metal ruthenium and tricylohexyl phosphine utilized in olefin metathesis in synthetic organic chemistry.

Anbieter50 Anbieter

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