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Trimethoxyvinylsilan

Vinyltrimethoxysilane

HCID 76004
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Grundinformationen

CAS
2768-02-7
Standard-SMILES
C=C[Si](OC)(OC)OC
InChIKey
NKSJNEHGWDZZQF-UHFFFAOYSA-N
Summenformel
C5H12O3Si
Durchschnittliche Molmasse
148,23 g/mol
Monoisotopische Masse
148,05557077

Namen und Bezeichner

Bevorzugter Name
Vinyltrimethoxysilane
IUPAC
ethenyl(trimethoxy)silane
Lokaler Name
Trimethoxyvinylsilan
Englischer Name
Vinyltrimethoxysilane
Summenformel
C5H12O3Si
Molmasse
148.23

Namen und Synonyme

Vinyltrimethoxysilane2768-02-7TrimethoxyvinylsilaneSilane, ethenyltrimethoxy-Ethenyltrimethoxysilane(Trimethoxysilyl)etheneSilane, trimethoxyvinyl-Vinyl trimethoxy silaneDTXSID20292400ZIU135UESA 171 (Silane derivative)DYNASYLAN SILFIN
Weitere Namen anzeigen
VTMSa171VTMOethenyltrimethoxy-Silanekbm1003vts-mCo-Formula CFS-027Vinymethyltrimethoxysilane
KBM 1003SZ 6300DTXCID509240A 171V 4917Y 4302RefChem:901966220-449-8

Datenbank-Bezeichner

CAS
2768-02-7
PubChem CID
76004
DTXSID
DTXSID2029240
UNII
0ZIU135UES
EC Number
220-449-8、688-602-5
Nikkaji
J54.326H

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

Polarare Oberfläche (TPSA)
27,7 Ų
H-Brücken-Donoren
0
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
4
Schwere Atome
9
Formalladung
0
Komplexität
81,9

Experimentelle und physikochemische Eigenschaften

Chemical ClassesOther Classes -> Other Organic Compounds
SpringerMaterials PropertiesViscosity
Density · 2 Einträge

1.13 @25 °C

Specific Density: 0.94 (water = 1)

SolubilityWater Solubility: 1,000,000 mg/L at 20°C (modeled data).
Flash Point25.5°C
Boiling Point · 2 Einträge

123 °C @760 [mm Hg]

123°C at 1013 hPa (converted to 101.3 kPa) (760 mm Hg)

Melting Point−97°C
Vapor Pressure11.9 hPa (converted to 1.19 kPa) at 20°C
Food Contact Substances · 2 Einträge

FCS -> FDA Cumulative Estimated Daily Intake (CEDI)

FCS -> FDA Inventory of Effective Food Contact Substance (FCS) Notifications

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 6 Einträge

Warning

H317: May cause an allergic skin reaction [Warning Sensitization, Skin]

P261, P272, P280, P302+P352, P321, P333+P317, P362+P364, and P501 (click each P-code to see the statement)

This chemical does not meet GHS hazard criteria for 7.7% (104 of 1358) of reports.

Danger

H226 (55%): Flammable liquid and vapor [Warning Flammable liquids]

Gefahrenhinweise

Regulatory Information · 3 Einträge

Chemical: Silane, ethenyltrimethoxy-

Status: Active Update: 05-04-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14728

Trimethoxyvinylsilane: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationEvaluation - Chemicals that are unlikely to require further regulation to manage risks to environment
Hazards Summary · 1 Eintrag

Dermal LD50 (rabbit) = 3.36 mL/kg; Oral LD50 (rat) = 7.34 mL/kg; [ChemIDplus] A mild skin and eye irritant; Causes somnolence, ataxia, and dermatitis in dermal lethal-dose studies of rabbits; Causes changes in fluid intake, hematuria, and weight loss in 9-day intermittent inhalation study of rats (750 ppm/6hr/day); [RTECS] Sensitive to moisture; A skin irritant; May cause serious eye injury; Harmful by inhalation; [Alfa Aesar MSDS]

Hazard Classes and Categories · 6 Einträge

Flam. Liq. 3 (55%)

Not Classified

Skin sensitisation - category 1B

Flammable liquids - Category 2

Skin sensitization - Category 1B

Skin Sens. 1B

Sicherheit und Schutzausrüstung

Chemie und Industrie

Verwendung und Herstellung

Uses · 1 Eintrag

The typical concentration of VTMS in industrial products is from 1 to 2%. VTMS undergoes reactions, resulting in minimal or no residual chemical in the final products. It serves as a coupling agent for plastics and wire and cable pipes, acts as a moisture scavenger in sealants, and functions as a co-monomer in latex dispersions to enhance adhesion on inorganic surfaces. VTMS is managed within closed systems (hard piped) in manufacturing environments, and it is not used in consumer products.

Household ProductsInformation on 20 consumer products that contain Trimethoxyvinylsilane in the following categories is provided:
General Manufacturing InformationSilane, ethenyltrimethoxy-: ACTIVE
Anwendungen · 1 Eintrag

VerwendenVTMS may be used to provide superhydrophobicity to different materials like TiO2, talc, kaolin, magnesium oxide nanoparticles, ammonium phosphate and PEDOT. It modifies the surface by capping the material and creates a protective layer that is water resistant and can be used in major coating industries.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Methanol

Nachgelagerte Produkte

Vinyl-tris-(2-methoxyethoxy)-silan6-Methoxy-2-vinylnaphthalene3-Phenylpropene-3-olBenzoic acid, 3-ethenyl-, methyl ester

Zugehörige Reaktionen

27
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 91516
HRID 91516als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
Reaktionsgleichung von HRID 93023
HRID 93023als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
Reaktionsgleichung von HRID 197285
HRID 197285als EduktTraining data from https://doi.org/10.1039/C8SC04228D (6/10)
Reaktionsgleichung von HRID 209127
HRID 209127als ProduktTraining data from https://doi.org/10.1039/C8SC04228D (6/10)
Reaktionsgleichung von HRID 229892
HRID 229892als Eduktuspto-grants-2009_07
Reaktionsgleichung von HRID 229893
HRID 229893als Eduktuspto-grants-2009_07
Reaktionsgleichung von HRID 229894
HRID 229894als Eduktuspto-grants-2009_07
Reaktionsgleichung von HRID 352642
HRID 352642als Eduktuspto-grants-2004_06
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Physical Description · 2 Einträge

Light yellow liquid; [Aldrich MSDS] Colorless liquid with a fruity odor; [Alfa Aesar MSDS]

Liquid (at standard temperature and pressure)

Stability/Shelf LifeHydrolytically unstable; at pH = 7 (20°C–25°C) half-life <0.2 h
Autoignition Temperature224°C

Physikochemische Eigenschaften

Schmelzpunkt
-70 °C · <-70°C
Siedepunkt
123 °C · 123 °C (lit.)
Dichte
0.968 g/mL · 0.968 g/mL at 25 °C (lit.)
Dampfdruck
88 hPa · 88 hPa (55 °C)
Brechungsindex
20 · n20/D 1.392(lit.)
Flammpunkt
73 °F · 73 °F
storage temp.
30 °C · Store below +30°C.
Aggregatzustand
liquid
Farbe
Colorless to Almost colorless
Wichte
0.97 · 0.970
Geruch (Odor)
Fruity odor
Explosionsgrenze
1.1 % · 1.1%(V)
Wasserlöslichkeit
slightly soluble
BRN
1099136 · 1099136
InChI
1S/C5H12O3Si/c1-5-9(6-2,7-3)8-4/h5H,1H2,2-4H3
InChIKey
NKSJNEHGWDZZQF-UHFFFAOYSA-N
SMILES
CO[Si](OC)(OC)C=C
LogP
-2 · -2--0.82 at 20℃
CAS Datenbank
2768 · 2768-02-7(CAS DataBase Reference)
NIST chemische Informationen
Vinyltrimethoxysilane(2768-02-7)
EPA chemische Informationen
Vinyltrimethoxysilane (2768-02-7)
Protective Action Criteria (PAC) · 3 Einträge

10 [ppm]

20 [ppm]

120 [ppm]

Other Standards Regulations and Guidelines · 1 Eintrag

The subchronic (14-week), whole-body inhalation study (6 h/day, 5 days/week) in F344 rats was used as the critical study for the derivation of the Workplace Environmental Exposure Level (WEEL). The No-Observed-Adverse-Effect Concentration (NOAEC) of 100 ppm (605 mg/m3) was used as the point of departure (PoD). Adjustment factors for subchronic to chronic extrapolation and intra-individual variability were applied to the NOAEC to develop the health-based WEEL value of 10 ppm as the 8-hour time-weighted average (TWA).

Toxikologische Informationen

Toxicity Summary · 1 Eintrag

Experimental animal studies have shown that VTMS exhibits low acute toxicity when exposed via oral, dermal, and inhalation routes. It is not a dermal or eye irritant. A weight of evidence assessment of four dermal sensitization studies in guinea pigs indicates that VTMS is not a dermal sensitizer. However, one additional study yielded positive results, leading ECHA to classify VTMS as Category 1B, indicating it may cause an allergic skin reaction. VTMS is not considered genotoxic based on in vitro and in vivo studies. Various experimental animal studies have demonstrated that VTMS does not have reproductive or developmental effects. Short-term oral administration of VTMS for 28 days in rats resulted in treatment-related effects in the urinary bladder and kidney. In a 14-week inhalation study in rats, VTMS exposure was linked to histopathological changes in the kidney and urinary bladder. However, an expert panel review concluded that these observations were adaptive responses to physical or chemical irritant(s) in the urine. The NOAEC of 100 ppm (605 mg/m³) from the 14-week inhalation study was used as the point of departure for deriving the health-based WEEL.

Medical SurveillanceThree producers of VTMS provided information to confirm that there have been no cases of skin sensitization among workers during more than 40 years of manufacture.
Toxicity DataLC50 (rat) = 2,773 ppm

Sicherheitsdaten

F
10-21
wgk
1
tsca
TSCA listed
ridadr
UN 1993 3/PG 2
hs_code
29310095
RTECS-Nr.
VV6770000
risk_code
10-36/37/38-20
Toxizität
LD50 orally in Rabbit: 7120 mg/kg LD50 dermal Rabbit 3259 mg/kg
hazard_code
Xi
safety_code
26-36/37/39-37/39-16
hazard_class
3
packing_group
III
Speicherklasse
3 - Flammable liquids
Hazard Classifications
Acute Tox. 4 InhalationFlam. Liq. 2Skin Sens. 1B
Selbstentzündungstemperatur
235 °C
2-(Trimethoxysilyl)ethanthiol
N-VINYLSUCCINIMIDE
6-vinyl-2,3-dihydrobenzo[b][1,4]dioxine
1-(thiophen-2-yl)prop-2-en-1-ol
3-Vinylbenzonitrile