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Tributylphosphit
Tributyl phsophite · TRI-N-BUTYL PHOSPHITE · jp304 · Syn-O-Ad P-312 · Tributylfosfit · Tributoxyphosphine · Tributyl phosphite · TributylPhosphite>Phosphorus derivative
Identifikatoren & physikalische Daten
| CAS No. | 102-85-2 |
|---|---|
| Summenformel | C12H27O3P |
| Durchschnittliche Molmasse | 250,31 g/mol |
| Monoisotopische Masse | 250,16978135 g/mol |
| SMILES | CCCCOP(OCCCC)OCCCC |
| InChIKey | XTTGYFREQJCEML-UHFFFAOYSA-N |
| PubChem CID | 7623 |
| EC No. | 203-061-3 |
| DTXSID | DTXSID7051474 |
| Lokaler Name | Tributylphosphit |
Chemische & physikalische Eigenschaften
| XLogP | 3,8 |
|---|---|
| Polarare Oberfläche (TPSA) | 27,7 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 3 |
| Frei drehbare Bindungen | 12 |
| Schwere Atome | 16 |
| Formalladung | 0 |
| Komplexität | 110 |
| Stoffklassen | Other Classes -> Phosphite Compounds |
| SpringerMaterials Properties | Chemical diffusion |
| Exact Mass | 250.16978172 Da |
| Molecular Weight | 250.31 g/mol |
| Monoisotopic Mass | 250.16978172 Da |
| Physical Description | Clear colorless liquid with a mild odor[Acros Organics MSDS] |
| Compound Is Canonicalized | Yes |
| Schmelzpunkt | -80 °C |
| Siedepunkt | 125 °C |
| Dichte | 0.925 g/mL at 25 °C(lit.) |
| Dampfdruck | 3.2Pa at 20℃ |
| Brechungsindex | n20/D 1.431(lit.) |
| Flammpunkt | 197 °F |
| Löslichkeit | Chloroform (Sparingly), Methanol (Slightly)Not miscible or difficult to mix in water. |
| Aggregatzustand | liquid |
| Wichte | 0.925 |
| Farbe | colorless |
| BRN | 1703866 |
| InChI | 1S/C12H27O3P/c1-4-7-10-13-16(14-11-8-5-2)15-12-9-6-3/h4-12H2,1-3H3 |
| InChIKey | XTTGYFREQJCEML-UHFFFAOYSA-N |
| SMILES | CCCCOP(OCCCC)OCCCC |
| CAS Datenbank | 102-85-2(CAS DataBase Reference) |
| EPA chemische Informationen | Tributyl phosphite (102-85-2) |
Sicherheit & Vorschriften
| GHS-Einstufung | This chemical does not meet GHS hazard criteria for 0.1% (1 of 725) of reports.WarningH315 (33%): Causes skin irritation [Warning Skin corrosion/irritation]P264, P264+P265, P273, P280, P302+P352, P305+P351+P338, P321, P332+P317, P337+P317, P362+P364, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 725 reports by companies from 11 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Phosphorous acid, tributyl esterPhosphorous acid, tributyl ester is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Phosphorous acid, tributyl ester are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 17-04-2019 https://echa.europa.eu/registration-dossier/-/registered-dossier/28208Phosphorous acid, tributyl ester: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| Gefahrenübersicht | A moderate eye and severe skin irritant[RTECS] A skin and eye irritantHarmful by inhalation and skin absorption[Acros Organics MSDS] See Triethyl phosphite and Dibutyl hydrogen phosphite. |
| Hazard Classes and Categories | Skin Irrit. 2 (33%) |
| Toxicity Data | LC (rat) > 220 ppm/6hr |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 3265 8/PG 3 |
| Zollcode | 29209085 |
| RTECS-Nr. | TH0875000 |
| R-Sätze (R) | 21-34 |
| Toxizität | LD50 oral in rat: 3gm/kg |
| Gefahrensymbole | C |
| Sicherheitshinweise (S) | 26-36/37/39-45 |
| Lagerklasse | 8A - Combustible corrosive hazardous materials |
| Gefahrenklasse | Acute Tox. 4 DermalSkin Corr. 1B |
Anwendungen & Verwendung
Verwenden
Tributyl phosphite may be employed as model lubricant additive and its surface chemistry on Fe3O4 in ultrahigh vacuum is investigated.