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Dimethylphenylphosphonit
phosphonite · Dimethoxyphenylphosphane · PHENYLDIMETHOXYPHOSPHINE · DIMETHOXYPHENYLPHOSPHINE · Dimethylphenylphosphonit · imethoxy(phenyl)phosphane · DIMETHYL PHENYLPHOSPHONITE · Dimethyl phenylphosphinite
Identifikatoren & physikalische Daten
| CAS No. | 2946-61-4 |
|---|---|
| Summenformel | C8H11O2P |
| Durchschnittliche Molmasse | 170,15 g/mol |
| Monoisotopische Masse | 170,04966622 g/mol |
| SMILES | COP(OC)c1ccccc1 |
| InChIKey | LMZLQYYLELWCCW-UHFFFAOYSA-N |
| PubChem CID | 76277 |
| EC No. | 220-960-6 |
| DTXSID | DTXSID60183666 |
| Lokaler Name | Dimethylphenylphosphonit |
Chemische & physikalische Eigenschaften
| XLogP | 1,6 |
|---|---|
| Polarare Oberfläche (TPSA) | 18,5 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 2 |
| Frei drehbare Bindungen | 3 |
| Schwere Atome | 11 |
| Formalladung | 0 |
| Komplexität | 98,3 |
| Stoffklassen | Other Classes -> Phosphite Compounds |
| SpringerMaterials Properties | 31P nuclear magnetic resonance spectrum |
| Physical Description | Colorless liquid[Alfa Aesar MSDS] |
| Siedepunkt | 77-79°C 7mm |
| Dichte | 1.072 g/mL at 25 °C (lit.) |
| Brechungsindex | n20/D 1.529(lit.) |
| Flammpunkt | >230 °F |
| Lagerbedingungen | 2-8°C |
| Aggregatzustand | liquid |
| Wichte | 1.072 |
| Farbe | colorless |
| Löslichkeit | Miscible with alcohol. Immiscible with water. |
| BRN | 1073018 |
| InChI | InChI=1S/C8H11O2P/c1-9-11(10-2)8-6-4-3-5-7-8/h3-7H,1-2H3 |
| InChIKey | LMZLQYYLELWCCW-UHFFFAOYSA-N |
| SMILES | C1=CC=C(P(OC)OC)C=C1 |
| CAS Datenbank | 2946-61-4(CAS DataBase Reference) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH314 (90.9%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 44 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Gefahrenübersicht | A skin and strong eye irritant[Alfa Aesar MSDS] See Trimethyl phosphite and Benzyl diethyl phosphite. |
| Hazard Classes and Categories | Skin Corr. 1B (90.9%) |
| Wassergefährdungsklasse (WGK) | 3 |
| UN-Transportnummer | UN 1760 8/PG 2 |
| Zollcode | 2931.90.6000 |
| R-Sätze (R) | 34 |
| Gefahrensymbole | C |
| Sicherheitshinweise (S) | 26-36/37/39-45 |
| Gefahrenklasse | 8Eye Dam. 1Skin Corr. 1B |
| Verpackungsgruppe | II |
| Lagerklasse | 8A - Combustible corrosive hazardous materials |
Anwendungen & Verwendung
Verwenden
Dimethyl phenylphosphonite is used in the preparation of phenyl-phosphonic acid dimethyl ester. It is used as a precursor for the preparation of dinitrosyltris(dimethyl phenylphosphonite)manganese(I) tetrafluoroborate.